关键词: 杯芳烃 , 水溶性 , 合成 , 偶氮 , 还原 , 杯芳烃铵盐酸盐

Abstract: Calix ［4］ arene was synthesized by dealkylation reaction using ptertbutylcalix ［4］ arene and phenol as raw material in the presence of anhydrous AlCl3. Then 5,11,17,23four sulfo phenyl)azo calix ［4］ arene was synthesized by coupling reaction using calix ［4］ arene and pamino benzene sulfonic acid as raw materials. In the presence of tinhydrochloric acid, 5,11,17,23four sulfo phenyl)azo calix ［4］ arene was reduced to 5,11,17,23four aminocalix ［4］ arene hydrochloride. The synthesized compounds were characterized by thermal analysis, infrared spectrum analysis and UV spectra of the synthesized compounds. By using the method of synthesis of calix ［4］ arene ammonium hydrochloride yield is high, cost is greatly reduced.

Key words: Calixarene,    , Watersoluble,    , Synthesis,    , Azo,    , Reduction,   , Calixarene amine hydrochloride