关键词: 催化裂解 , 催化剂 , 结焦 , 重油 , 积炭率 , 关联模型

Abstract: The coking performance for the catalytic pyrolysis of heavy oil with temperature，weight ratios of catalyst －to－oil and steam－to－oil and residence time，was investigated in a confined fluidized bed reactor on catalyst CEP－1，with a special catalyst of catalytic pyrolysis process （CPP） technology．The coke content on catalyst decreases with the increase of the weight ratios of catalyst － to－oil and steam－to－oil and n（H）／n（C） of the feed，and it increases with the enhancement of reaction temperature and aromaticity of the feed．Coke yield increases with increasing reaction temperature，catalyst－to－oil weight ratio and aromaticity，while decreases with increasing steam－to－oil weight ratio and n（H）／n（C） of the feed．Both coke content and coke yield show minimum as residence time of oil gas prolongs．Both n（H）／n（C） and aromaticity of the feed can well reveal the coking tendency of a feed．On the basis of the experimental research，a correlation model of coke content and coke yield with feed property and reaction conditions was established．The parameters in the model were calculated by least square regression.

Key words: Catalytic pyrolysis , Catalyst , Coking , Heavy oil , Coke content , Correlation model