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2005, Vol.25 No.2  Publication date:20 June 2005
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  • The Stability of SiO2 Sol
  • QIU Chun-yang,ZHANG Ke-zheng
  • 2005, 25 (2): 1-4.
  • Abstract ( ) PDF ( 274KB ) ( )   
  •  The SiO2 sol is a kind of colloid solution , with SiO2 particle dispersing in water or organic solvents , and has been widely used in the industries of the ceramics, textile , papermaking , paint, water treatment and semiconductor and so on .SiO2 sol was prepared from tetraethoxysilane(TEOS)by sol-gel method with ethanol as solvent and hydrochloric acid as catalyst .The effects of the solvent , the pH value , and additives o n the stability of SiO2 sol were studied during the so l-gel processing .The effects of these factors can be used to control the stability of the SiO2 sol .The results show the more the amount of EtOH , the mo re the stability of sol.In the absence o f additives , the stability of sol increases as the pH value is increased.As the pH value is increased , the stability of sol firstly increases, but then decreases when additives are added to the SiO2 sol.Gelation time becomes long when DMF additive is added to the SiO2 sol .If the mole ratio of TEABr and TEOS is mo re than 0 .05, TEABr makes g elation time become longer .
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  • Development of Asphalt for Flame Retardancy
  • GUO Jin -cun,LIAO Ke -jian,et al
  • 2005, 25 (2): 5-8.
  • Abstract ( ) PDF ( 261KB ) ( )   
  •  Asphalt for flame retardancy was investigated by adding flame retardant to Liaohe 70# high -quality paving asphalt . The performance of flame retardancy and synergism of DBPDO, Sb2O3 , ZnBO3 and Mg(OH)2 were examined by using the method of oxygen index and comburent flame level.The performance of smoke inhibiting on asphalt between Al(OH)3 and complexing smoke inhibitor was also studied .The results show that DBPDO, Sb2O3 , ZnBO3 and Mg(OH)2 exhibit some positive effect on asphalt flame retardancy .The flame retardancy effect of DBPDO is superior to Sb2O3 , ZnBO3 and Mg(OH)2.But it has greater smoke generation to the others .There is good synergism flame retardancy between Sb2O3 and DBPDO.Al(OH)3 and complex smoke inhibitors act as not only good flame retardant , but also good smoke inhibitor .The effect of flame retardancy and smoke inhibiting are best w hen they were added to asphalt according to certain proportion.Oxygen index of asphalt for flame retardancy reaches 36 .5 % and comburent flame level is the first grade .The amount of smoke generation is lower .
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  • Process of Walnut Oil by Microwave Ex traction
  • SHAO Hai,LI Li -hua,et al
  • 2005, 25 (2): 13-16.
  • Abstract ( ) PDF ( 272KB ) ( )   
  •         The conditions of microwave extracting walnut oil w ere discussed by using the Mars5 microwave ex traction system ,including solvent, microwave extraction temperature , extraction time and the volume of ex traction solvent .According to the results of single fraction experiments, the optimized conditions of microwave extracting walnut oil w ere obtained by orthogonal experiments: extraction temperature is 60 ℃ , extraction time is 12 minutes, 7 m L the liquid volume per gram walnut .Compared with Soxhlet method and magnetic stir ring ex traction method , the results show that the time is shorten obviously(1/ 12 of the time of magnetic mix round extraction, 1/ 20 of time of Soxhlet method), the extracting temperature is 5 ℃ low er than that of conventional method .The consumption of solvent is less than magnetic mix round ex traction and the oil yield is higher than that of conventional method. Composition of fatty acid was analyzed in walnut oil by GC.There are obvious differences of composition of fatty acid between the microwave extraction oil and the conventional ex traction oil.The mass fraction of the unsaturated fatty acid is increased from 82.94 % to 90 .25 %, while the mass fraction of linoleic acid is increased from 43.49 % to 48 .23%.
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  • Isolation Characterization and Diesel Oil Denitrogen of Quinoline -Degrading Bacterium
  • HONG Xin,YANG Xiang -hua
  • 2005, 25 (2): 32-35.
  • Abstract ( ) PDF ( 270KB ) ( )   
  •         Quinoline is poisonous organic compound and not easy to be biodegraded.Nineteen bacterial strains were screened out by enrichment culture to decompose quinoline as sole nitrogen source .By the quinoline-degrading test , HY9 is the best quinoline -degrading bacterium as experimental strain .The curves of deg ration and growth of quinoline -degrading show that the growth ofHY9 strain and degradation of quinoline are concurrent , optimal time is 50~ 70 hours , which is stable stage .Effects of glucose and the volume of initial quinoline on degradation of quinoline were studied.The optimal carbon source is glucose and volume fraction of quinoline is 1 .4 m L/ L.By orthogonal test determination, the optimal conditions are as following :temperature is 35 ℃ , pH is 7.0, time of culture is 4 days, 125 r/ min rotation speed of mechanical shaker .Temperature is the key factor for the growth of cell, then is rotation speed and pH , time o f culture is the unimportance factor .The initial test of denitrification indicates that the denitrification percent for diesel oil is only 13 %.Low denitrogen rate is probably because that the mixing of oil and water is no t perfect , efficient mixing of oil and water is important for the enhancement of denitrogen rate for diesel oil.
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  • Finite Element Analysis of Quality Factor Influencing Sheet Drawing
  • ZHU Xiang -zhe,LIN Wei
  • 2005, 25 (2): 46-49.
  • Abstract ( ) PDF ( 383KB ) ( )   
  •         In the process of drawing , the sheet often appears crinkling , bloating and ripping .The sheet drawing process includes complex physical phenomena revolved in no n -linearity of geometry , material and boundary .So it is very difficult to be solved by analytic method .Numerical simulation of sheet drawing was made by means of finite element software ANSYS/ LS -DYNA and the position of potential flaw was analyzed.Sheet drawing quality influence that resulted from punching velocity , fiction coefficient and press force w as discussed.The results show that the sheet in the adjacent area of cavity die and punch deforms firstly .The maximal value of stress and strain appears in the outboard sheet o f punch round corners .The maximal bodiness is sheet flange and the maximal attenuation is the sheet of cavity die round corners .The bigger fiction coefficient between punch and sheet is, the bigger the brim stress is.So the wrinkle isn' t easy to emerge in the rim of sheet.The effect of fiction coefficient on parietal stress is complex . Enhancing punch velocity properly can improve computing efficiency and assure computing precision.
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  • A Blind Image Watermark Algorithm Based on Wavelet Transform
  • AI Zhi -qiang,JI Yu -bo,et al
  • 2005, 25 (2): 69-73.
  • Abstract ( ) PDF ( 354KB ) ( )   
  •         As a new technique applied to protecting the copy right of digital productions, the digital watermark technique has drawn extensive attentions.The watermark technique based on wavelet transform has been an active study field .In order to ensure the concealment and robustness of watermark, a blind image algorithm on the basis of wavelet transform was proposed.Firstly ,watermark was scrambled before the algorithm w as embedded .Then watermark information and spread spectrum sequence are modulated, and combining texture concealable characteristics of human vision system with just differenthating limit, were embedded into DWT domain of carrier image .Finally , making use of autocorrelation function characteristic of spread spectrum sequence ,watermark information was detected .In the detection process, it is not requisite for initial carrier image .The experiment results demonstrate that with the algorithm embedded watermark, watermark is no t easy to be found out .I t has a fine detected watermark effect .The algorithm is robust enough for JPEG degradation compression, clipping , noise attacks and low -pass filtering .
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