Metal corrosion is an irreversible destructive behavior, therefore, the research of anticorrosive coatings has become a vital research topic in various fields. With the development of recent years, the single protective form of anti?corrosion coating is no longer sought after, the advent of barrier/self-healing coatings has added a significant complement to anti?corrosion coatings and has become one of the most widely studied topic today. Subsequently，new anti-corrosion forms such as ion exchange, hydrophobicity and intelligent self-warning have appeared on the market. Dual/multi-functional anti?corrosion coatings that integrate self-healing, barrier properties, hydrophobic properties and intelligent self-warning properties have also become research topics in recent years. In this paper, the research progress of barrier/self-healing bifunctional anti?corrosion coatings, other dual-function anti-corrosion coatings (ion exchange/self-healing coatings, hydrophobic/self-healing, self-warning/self-healing) and multi-functional anti-corrosion coatings are reviewed, and the future development direction of more intelligent and green dual/multi-functional coatings is prospected.

Deep and ultra-deep carbonate oil and gas reservoirs, with their vast reserves and immense potential, have emerged as critical strategic assets in global energy supply. However, the complex challenges posed by high-temperature, high-pressure environments, intricate pore-throat structures, and the coexistence of macro-pores, dissolution cavities, and fractures make traditional exploration and production technologies insufficient to manage such complexity. As exploration and development progress, precise reservoir characterization and seepage behavior research face significant hurdles, including advanced modeling, complex seepage experiments, and accurate description of reservoir properties. Therefore, this review offers an in-depth analysis of the latest developments and key challenges in the characterization and seepage behavior of deep and ultra-deep carbonate reservoirs. It provides a comprehensive summary of cutting?edge methods for detailed microstructural reservoir characterization and multi?attribute seismic interpretation techniques enhanced by artificial intelligence. The paper also explores the application and success of multi?scale characterization approaches in complex reservoirs,while outlining the primary technical strategies and emerging trends in reservoir identification and description. Additionally,the article emphasizes recent advancements in understanding seepage characteristics under high-temperature and high?pressure conditions in deep carbonate reservoirs, focusing on multi-scale seepage theory and gas-water two?phase flow mechanisms. By examining experimental data and theoretical models from both domestic and international research, the review highlights current challenges and future directions in seepage studies, providing valuable insights for the development and efficient exploitation of deep and ultra?deep oil and gas reservoirs.

Using sodium lignosulfonate and copper chloride dihydrate as raw materials, and activated carbon modified materials under different synthetic conditions were prepared by calcination under N₂ atmosphere by impregnation and activation. The structure and surface morphology of the prepared materials were studied by X-ray diffraction (XRD), infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and other testing methods. Taking K₂Cr₂O₇ solution with mass concentration of 20 mg/L as the research object, the Cr(Ⅵ) content in the solution was detected by Diphenyl carbamide chromogenic method, and the adsorption capacity of the prepared activated carbon modified materials was calculated. According to the experimental results, when the proportion of copper is 20% and the calcination temperature is 700 ℃, the adsorption performance of the material is the best, and the adsorption capacity is 72.2 mg/g. The adsorption process conforms to the Langmuir monolayer adsorption and Pseudo-second-order kinetics.

There are several sets of formation pressure systems in Y structure of block X in Bohai Sea. Shahejie Formation and its upper strata are sedimentary undercompacted layers. dc index method is adopted to monitor formation pressure. The Mesozoic buried-hills are widely distributed in medium acid volcanic rocks, which are non-sedimentary underpressure layers. The formation pressure monitoring method of Sigma index is used to monitor the formation pressure. The real drilling shows that the formation pressure monitoring method of dc index has good applicability in the formation profile pressure monitoring dominated by sand and mudstone. The formation pressure monitoring method of Sigma index has a good application effect in the non-sand mudstone formation profile pressure monitoring, and the combined application of the two provides effective technical support for the smooth drilling. The application of Sigma index formation pressure monitoring method in deep and ultra?deep layers effectively improves the accuracy of the deep and ultra?deep layer pressure monitoring technology while drilling. The practical application shows that the results of formation pressure monitoring while drilling are in good conformity with the measured formation pressure results, and the formation pressure monitoring method of Sigma index has the value of popularization and application in deep and ultra-deep formation.

Microbial dewaxing of crude oil is an efficient and simple method. In order to further improve the paraffin degradation rate of microorganisms, two strains L and K were used to form paraffin degradation mixed bacteria, and their degradation conditions were optimized. The factors affecting the degradation of mixed bacteria (culture temperature, initial pH value of culture medium, salt concentration, and V（L strain ）/V（K strain）) were determined by orthogonal experiment and single factor experiment. Box-Behnken method was used to design four?factor three?level experiment and response surface optimization, and a mathematical model was established to explore the best conditions for the degradation of paraffin by mixed bacteria. The experimental results showed that the influence of four single factors is as follows: V（L strain）/V（K strain）>culture temperature>salt concentration>initial pH value of culture medium. Their primary term, secondary term and individual interaction term had significant influence on the paraffin degradation rate. The optimal experimental operating conditions for the mixed bacteria to degrade paraffin were determined as follows: culture temperature 37.2 ℃, initial pH value of culture medium 7.3, salt concentration of culture medium 1.2%, ratio of mixed bacteria V（L strain）/V（K strain）=1.0∶1.6, and paraffin degradation rate 58.67%. The mixed bacteria were used to act on crude oil under the optimized conditions, and the biodegradation rate was 41.38%,have good application prospects.

Poly (butyleneadipate-co-terephthalate) (PBAT) was used to toughen poly (lactic acid) (PLA), and a fully biodegradable high impact PLA/PBAT composite was prepared. To improve the interface compatibility between PBAT and PLA, PBAT grafted glycidyl methacrylate (GMA)(PBAT-GMA) compatibilizer was prepared by the melt grafting method. The effect of the mass fraction of compatibilizer on the properties of PLA/PBAT composite was studied. The results show that with the increase of PBAT-GMA mass fraction, the impact strength of the composites is significantly improved. When the PBAT?GMA mass fraction is 30%, the impact strength of the composites reaches 64.8 kJ/m², and the elongation at break is 289.9%; the compatibilizing mechanism is the epoxy groups on PBAT?GMA can react with the end groups of PLA, which effectively improves the interfacial compatibility between PLA and PBAT.

The environmental contamination caused by tetracycline hydrochloride (TC) has aroused widespread concern, photocatalytic degradation of TC has become an effective method. CeO₂ was prepared by coprecipitation method, and solvothermal synthesis of CeO₂@UiO-66 composite catalysts. The prepared catalysts were characterized by FT-IR, XRD, SEM and EDS respectively, and the effects of the amount of CeO₂, catalyst mass concentration and H₂O₂ mass fraction on the photocatalytic degradation of TC were also investigated. The results showed that CeO₂@UiO?66 was successfully synthesized. When the amount of CeO₂ substance is 25 mmol, the mass concentration of TC solution is 20 mg/L, the mass concentration of catalyst is 0.2 g/L, and the mass fraction of H₂O₂ is 2%, CeO₂@UiO?66 photocatalytic effect is the best, and the TC degradation rate reaches over 98% when irradiated by UV lamp for 70 min. The free radical trapping experiments showed that holes and ·OH were the main contributors in the photocatalytic process. In addition, after six cycles, the degradation rate of TC composite photocatalyst can still maintain above 85%, which indicates its good stability.

Co@CNT/CN nanocomposites were obtained by a simple one-pot co?precipitation method using dicyandiamide, glucose and cobalt nitrate as raw materials. The effect of carbon nanotubes (CNTs) on the catalytic activity of Co was investigated by X-ray diffraction (XRD) and electrochemical tests. The results show that Co@CNT/CN can be obtained only at the calcination temperature of 850 ℃. And after electrochemical performance test, it was found that the electrocatalytic activity of Co@CNT/CN material with carbon nanotubes was significantly higher than that of other samples, mainly because carbon nanotubes have special conductivity, but also can promote the separation of Co elemental, reduce the agglomeration phenomenon, so as to obtain higher electrocatalytic activity.

Ultra?deep wells of over 10 000 meters have been successfully drilled in China, and deeper breakthroughs has been made in drilling and completion equipment technology, which indicates that China has achieved a significant milestone in the field of oil exploration and development. It is crucial to improve drilling efficiency and ensure safety in this context. Intelligent drilling and completion technology is a core solution to the challenges faced in the industry. It offers significant advantages in improving drilling efficiency and safety. By integrating advanced automation control, real?time data monitoring, and machine learning technology, it optimizes drilling operations. This not only improves drilling efficiency but also dramatically enhances drilling and completion safety. This paper summarizes the current development status of intelligent drilling and completion equipment technology. It proposes a trinity research approach that includes automation control, real?time data monitoring, and machine learning technology. The paper focuses on analyzing the development journey and technological innovation of domestic and international innovative equipment, such as intelligent drill bits, intelligent guiding tools, intelligent drill pipes, intelligent slip sleeves, and intelligent drilling rigs. To achieve comprehensive development of intelligent drilling and completion equipment technology in the future, it is recommended to utilize artificial intelligence, intelligent optimization algorithms, and foster domestic and international cooperation.

In oil and gas extraction, coiled tubing technology has attracted much attention because of its advantages such as fast operation time, little damage to the formation low labor intensity, etc. The research of coiled tubing technology is a systematic project involving many aspects. This paper first starts the discussion from the domestic and international literature published and the main research scholars review the development process of coiled tubing technology, and summarise the relevant achievements existing in China. At present, the coiled tubing technology is in the stage of rapid development, but the research of coiled tubing in ultra-deep wells is minimal. The authors describe the relevant research carried out by the team on the downhole accessibility of coiled tubing in ultra-deep wells, the extension of the horizontal section of coiled tubing, the optimization of the construction parameters of coiled tubing operation, and the downhole safety assessment of coiled tubing operation. According to the current status of coiled tubing technology research in ultra-deep wells, it is suggested to carry out the research related to the real-time warning technology of coiled tubing fatigue life based on the digital intelligence technology, the ability of tractor?driven coiled tubing extension, and the research and development of high?temperature?resistant tools and fluids, to solve the technical difficulties of coiled tubing operation in ultra-deep wells.

The reduction of graphene oxide(GO), in?situ loading of SnSe and interface assembly were achieved simultaneously by microwave method, and the reduced graphene oxide(rGO)?supported the petal?shaped SnSe (SnSe/rGO) composite was successfully prepared. The SnSe/rGO was characterized by Raman spectroscopy, X?ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), and the effects of different rGO contents for SnSe/rGO composite on the electrocatalytic oxygen reduction reaction(ORR) were investigated. The results indicated that there was an interaction between SnSe and matrix rGO, and Sn-C and Sn-O-C bonds were used as bridges of charge transfer. The intimate interconnection between the petal?like SnSe and the rGO formed a robust three?dimensional mesh structure, which served to reinforce the overall structural integrity of the catalyst, preventing its collapse. Based on this, the optimized SnSe/10%rGO catalyst (10rGO means that the mass fraction of rGO is 10%) exhibited excellent ORR activity with a limiting current density of 3.79 mA/cm², an onset voltage （vs.RHE） of 0.85 V, and an electron transfer number of 3.10. Meanwhile, the SnSe/10%rGO catalyst performed the electrocatalysis long?term stability superior that of commercial 20%Pt/C （20%Pt means that the mass fraction of Pt is 20%） with the current density remaining 81.15% of the start value after 20 000 s of reaction. The present work offers insights into the preparation of non?precious metal cathode oxygen reduction catalytic materials for fuel cells.

To study the influence of hydrogen mixing ratio on the leakage of natural gas pipelines, a mathematical model for the leakage and diffusion of directly buried high?pressure hydrogen mixed natural gas pipelines was established based on computational fluid dynamics theory and numerical simulation method.The leakage status, volume fraction distribution of hydrogen mixed gas,and the distribution of soil pressure and gas velocity around the pipeline were analyzed under different hydrogen mixing ratios.The results show that with the increase of hydrogen mixing ratio, the explosion radius of hydrogen mixed gas in the atmosphere will gradually decrease,and the range of high?pressure area around the pipeline will gradually decrease,and the gas flow rate at the leakage port will gradually increase.When the hydrogen mixing ratio is 30%,the explosion radius in the atmosphere is reduced by 43%,and the gas flow rate at the leakage port is increased by 68%.This provides a theoretical reference for the safety and emergency repair of hydrogen?doped natural gas pipelines and has important practical significance for promoting the large?scale application of hydrogen?doped natural gas.

Direct flame impingement heating technology is widely used in the field of steel heat treatment processes and is currently fueled by natural gas. Hydrogen, as a clean energy source and its high laminar flame propagation speed, combined with natural gas will improve the fuel combustion speed and reduce the emission of carbon oxides and nitrogen oxides. In this paper, a numerical model of direct flame impingement heating of steel plate was established using Fluent, and the heat transfer characteristics of direct flame impingement heating of steel strip were investigated under different hydrogen doping, Reynolds number, and factorless distance conditions. The results show that the temperature and heat flow density of the steel plate of the heated target decrease with the increase of hydrogen doping from 0 to 25% at a heating time of 10 s. The temperature of the steel plate stationary point decreases from 385.36 K to 374.31 K, and the heat flow density of the steel plate stationary point decreases from 154 828 W/m² to 137 926 W/m². With the increase of Reynolds number from 13 400 to 33 600, the steel plate stationary temperature increased from 347.04 K to 450.90 K, the pressure increased from 14.93 Pa to 136.53 Pa, but the uniformity of the temperature and pressure of the steel plate deteriorated gradually. The increase of the causeless distance from 25 to 45 made the temperature of the steel plate stationary point decreased from 442.42 K to 344.36 K, and the pressure was reduced from 106.00 Pa to 24.81 Pa and the distribution was more inhomogeneous.

Poly (arylpiperidine) anion exchange membrane (AEM) has been widely studied in anion exchange membrane fuel cells (AEMFCs) and alkaline electrolyzed water due to their excellent alkali resistance and stability. In this work, poly (triphenyl fluorene piperidine) (PTDP) AEM was prepared from 9,9?diphenylfluorene monomer with distorted large volume structure, and hydrophilic large volume cyclodextrin crosslinking agent (β?CD?Br₇) was introduced on this basis, which can control the microphase separation structure in AEMs. The prepared qPTDP?10?CD₅ AEM with 5% crosslinker content reached a high conductivity (130.2 mS/cm at 80 ℃). After the membrane was treated in 1 mol/L NaOH at 80 ℃ for 2 000 h, its conductivity retention was 94.3%, showing good stability. The H₂/O₂ fuel cell assembled with qPTDP?10?CD₅ yielded a peak power density of 1 490 mW/cm² at 80 ℃. In the durability test, the fuel cell assembled with qPTDP?10?CD₅ showed a voltage retention rate of 89.7% after 30 h, showing good cell performance.

A series of novel anion exchange membranes (AEMs) were prepared by constructing semi?interpenetrating polymer networks (sIPN) based on imidazole functional brominated polyphenyl ether (ImF?BPPO) and quaternary ammonium polyvinyl alcohol (QPVA). The effects of different contents of QPVA on the comprehensive properties of the composite membranes were systematically studied, the structure of the series composite membranes was analyzed by ¹H?NMR and FT?IR, and the morphology of composite membrane was investigated by SEM, and the ion exchange capacity, water uptake and conductivity and other properties of the composite membranes were tested. The results show that the prepared series of composite membranes have good compatibility and no obvious phase separation phenomenon. When the mass fraction of QPVA was 40%, the water uptake and swelling rate of the composite membrane were 58.2% and 24.6%, respectively. At 80 ℃, the conductivity of the composite membrane reached 67.24 mS/cm. After soaking in 6 mol/L KOH alkaline solution for 168 h, about 90% of the initial conductivity was still retained, indicating that the membrane had good conductivity and alkali resistance stability.

A base?catalyzed 1,6?conjugate addition of p?QMs for the preparation of diaryl methyl ethers (thioether) has been developed with 37% to 95% yields, which realized the solvolysis reaction between p?QMs and alcohol (thiophenol) under the catalysis of 20% NaOH. The method features easy operation, mild condition and good functional tolerance. A gram scale experiment was examined in 80% yield, which provides possibility for potential application and transformation in later stage.

Using the synergistic effect of surfactant mixture to reduce oil?water interfacial tension and crude oil viscosity is an important method to improve oil recovery in recent years.The content of each component of crude oil produced from each oil field is different, so it is necessary to screen the suitable surfactant according to the component content.In this paper, the interfacial tension and emulsifying properties of sodium dodecyl benzene sulfonate (SDBS) and lauryl glucoside (APG1214) in Liaohe crude oil were studied by rotating drop interfacial tensiometer and bottle test method. The interfacial tension was studied by changing different compounding ratios, salinity and pH value, and the viscosity of the emulsion was measured by viscometer.The results show that the interfacial tension between oil and water can be reduced and the stable heavy oil emulsion can be formed by adding proper amount of inorganic salt in combination of surfactant.

In this study, the optical properties of 3D carbon ball were theoretically investigated by using Density?Functional Theory (DFT) and wave function analysis. The electron?leaping mechanism in the Ultraviolet?visible (UV?vis) absorption spectrum was investigated. The electronic excitation properties of 3D carbon ball were investigated by Transition Density Matrix (TDM) and Charge Density Difference (CDD). Raman spectra were calculated and the vibrational modes of the 3D carbon ball were further explained. Meanwhile, the interaction between 3D carbon ball and the external environment was investigated using Electrostatic Potential (ESP), and the degree of electron delocalization of 3D carbon ball was investigated based on the magnetic induction current under the applied magnetic field.It is shown that the absorption spectra of three?dimensional carbon spheres are mainly in the ultraviolet region and that they have a strong electron delocalization capability. This study can provide a theoretical basis for the application of other 3D π?conjugated molecular structures in linear and nonlinear optics.

A power cycle (KC-TORC) combining a Kalina cycle and a three?stage organic Rankine is proposed to address the problems of large flue gas discharge with high temperature and low flue gas outlet temperature that is easy to cause corrosion of industrial pipelines in the industrial production process. A circulation system was constructed by using the method of thermodynamic simulation, taking industrial flue gas as the heat source and liquefied natural gas (LNG) as the cold source,and the effects of kalina cycle evaporation temperature, LNG post?pump pressure and three?stage organic Rankine cycle (ORC) turbine inlet temperature on the thermodynamic performance were analyzed by varying the flue gas outlet temperature. The results show that the maximum exergy efficiency is 62.89% at a flue gas outlet temperature of 30 ℃ and a Kalina cycle evaporation temperature of 112 ℃. The maximum thermal efficiency is 32.09% at a flue gas outlet temperature of 120 ℃ and three?stage ORC turbine inlet temperature of 160 ℃, and the net output power can be up to 2.04 MW. The annual NAV could be up to 5.773×10⁶ dollars. The KC?TORC power cycle shows good advantages in thermodynamic and economic aspects, which is important for environmental protection.

Card sleeve joints are widely used in the connection of hydraulic and pneumatic equipment such as oil and gas pipelines, and its connection reliability has an important impact on the safety of oil and gas pipelines. However, there is no report on the influence of external working conditions on the stress characteristics of the thread of card sleeve joints in oilfield ground pipelines. A three?dimensional model of the double card sleeve joint was established using SolidWorks software; The maximum equivalent stress (Von Mises stress) of the sleeve joint was numerically analyzed using ANSYS finite element software. The results indicate that within the yield limit, the greater the axial force, the better the sealing performance of the sleeve joint, while the internal pressure has little effect on the sealing of the pipe joint, and the risk of thread sticking due to excessive stress can be ignored; The influence of thread parameters on sealing performance is significant; The optimal pitch and number of threads for a sleeve joint with an outer diameter of 12 mm and an inner diameter of 9 mm are 1.5 mm and 7, respectively. The research results can provide theoretical basis and reference for the optimization of structural performance and scientific operation in the assembly process of card sleeve joints, which has important engineering significance.

At present, the demand for clean energy is constantly increasing to achieve sustainable development of human society. Among numerous new energy storage and conversion devices, proton exchange membrane fuel cells (PEMFCs) can directly convert chemical energy into electrical energy. Therefore, PEMFCs have been considered to have the merits of high efficiency, safety and wide application, etc. The proton exchange membrane is the core component of PEMFCs. However, the trade?off of proton conductivity and mechanical strength has become the primary challenge to hinder the development of proton exchange membranes. Although significant progress has been made in improving the single performance, the mutual constraints of key technical properties restrict the development of proton exchange membranes. Most importantly, the road to the commercialization of fuel cells is thus tortuous. We believe that the development of flexible proton exchange membranes is a main strategy to solve this technical challenge. Based on this, this article summarizes the recent research progress on flexible proton exchange membranes,including flexible polymer materials, structural optimization, and flexible additive design, expecting to provide inspiration for breaking through the performance bottleneck of flexible proton exchange membranes.

The study of the micro high viscosity mechanism of heavy oil is of great significance for the efficient development of Bohai heavy oil. Therefore, aiming at the typical heavy oil reservoirs in Bohai Sea, the microscopic mechanism of high viscosity of heavy oil is analyzed and studied from the aspects of viscosity?temperature relationship, crude oil composition and component polarity, heteroatom distribution and asphaltene aggregate structure. The results show that compared with N oilfield in Bohai Sea, the content of alkanes and aromatics in L oilfield in Bohai Sea is lower, and the quality score of resins and asphaltenes is higher, reaching 29.95% and 9.76% (23.25% and 6.59% in N oilfield). The quality score of heteroatoms such as O,N and S are high, and the relative molecular mass of resins and asphaltenes are also high. The polarity of each component is strong, and the dipole moments of resins and asphaltenes reach 14.01 D and 17.94 D, respectively (9.12 D and 12.25 D in N oilfield ). These will lead to stronger intermolecular forces and stronger intermolecular association between resins and asphaltenes. The smaller asphaltene molecular spacing and the denser aggregate structure,which will eventually lead to higher viscosity of crude oil.

Through molecular dynamics simulation, the torsional deformation behavior of copper nanowires in different crystal orientations (Ⅰ: x[1 0 0] y[0 1 0] z[0 0 1], Ⅱ: x[1 0 1/8] y[0 1/8 0] z[－1/8 0 1], Ⅲ: x[1 0 1/4] y[0 1/4 0] z[－1/4 0 1]), different crystal orientation ratios (α₁=1/6, α₂=1/2, α₃=5/6), and different numbers of twin interfaces (0, 2, 4) were studied, as well as the relationship between the shear stress and torsion angle of copper nanowires during torsion. The results indicate that change the orientation type contributes to enhancing the torsional mechanical properties of copper nanowires. Reducing the ratio of internal diameter to external diameter also improves the torsional mechanical properties of copper nanowires. Furthermore, decreasing the number of twin interfaces can strengthen the torsional mechanical properties of copper nanowires. The torsion process of copper nanowires can be divided into three stages: elastic, plastic and deformation failure. The research results provide a basis for investigating the torsion of high?strength copper nanomaterials.

The terrestrial gas reservoirs in the northeastern Sichuan region have reserves of over 100 billion cubic meters in the Xujiahe River. In the early stages, small?scale sand fracturing or acid fracturing were mainly used for production, but no significant breakthrough in productivity was achieved. Due to the tight and high fracture pressure of the Xujiahe reservoir, the construction displacement is limited, making it difficult to add sand and resulting in poor transformation effects. By conducting research on the guarantee technology for the operation of potential tapping wells, the Xujiahe potential tapping well wellbore treatment and fine pressure control technology have been developed, which has solved the problems of wellbore control and pressure control during construction operations caused by the coexistence of original test layers and large differences in ground pressure coefficients. The idea of tapping the potential of multiple layers in a single pipeline column has been proposed, forming a combination of large?diameter oil pipes and segmented fracturing pipelines with packers. The interactive operation of 140.0 MPa and 105.0 MPa wellheads meets the requirements of ultra?high pressure large?scale sand addition operations and later production. The application has been carried out in YB6, YL15, and YL171 wells, successfully achieving potential tapping operations in three old wells. A layer by layer fracturing of the four reservoirs was completed in the YL171 well using a single string, resulting in a production of 32 5000 cubic meters per day at a hydraulic pressure of 71.0 MPa.

The forward and reverse transportation simulation model was established by using SPS simulation software to simulate the forward and reverse operation process of A?Sai crude oil pipeline at low throughput. The change law of the oil temperature along the pipeline during the process of forward and reverse transportation is studied. The results show that the oil temperature along the pipeline decreases gradually under the steady state of forward transportation. The oil temperature drops first and then increases at the beginning of the reverse transportation, and then drops gradually after reaching the steady state.The oil temperature at the reverse inlet station decreases first and then increases slightly, and finally tends to be stable. The lowest temperature of crude oil in the process of forward and reverse transportation is the arrival temperature when the remaining crude oil is completely pushed out of the pipeline. In addition, the influence of inverse throughput on oil temperature drop during the inverse transportation was analyzed. The higher the inverse throughput is, the higher the lowest oil temperature in the process of inverse transportation is, and the faster the stable state of inverse transportation reaches. The temperature change of forward and reverse transportation obtained by SPS simulation analysis can provide certain basis for making the forward and reverse transportation scheme of A?Sai pipeline.

The crude oil produced by oil wells contains sediment, scale and other particles, which are deposited together with the wax in the process of crude oil pipeline transportation. It leads to a decrease in pipeline throughput, and may cause pipeline blockage and affect the safety of transportation in severe cases.The yield stress test and microscopic characteristic experiments show that there is a critical scale containing ratio in wax deposits of the influence of calcium carbonate scale on the strength of wax deposits. And it is found that the wax deposits containing scale will increase the breaking force on the wax layer and the pigging efficiency of the pig through the indoor pigging experiment of polyethylene pipeline. Based on the data of pigging experiment, a prediction model of pigging efficiency was established by using the π theorem. The model was validated by indoor experiments and third?party literature experimental data.

In order to improve the compatibility between rubber powder and matrix asphalt, the rubber powder was modified by microalgae bio?oil and compounded with SBS at 5% dosage to prepare modified asphalt. The changes of rubber powder before and after modification were analyzed by infrared spectroscopy and scanning electron microscopy; the dispersion of rubber in asphalt before and after modification was analyzed by viscosity, fluorescence and phase separation tests, and the mechanical properties and aging resistance of the modified asphalt were analyzed by dynamic shear rheology analysis and multiple stress creep recovery test. It was found that the incorporation of MB increased the proportion of light components in the mixing system, promoted the solubilization development of CR in asphalt, and improved the storage stability, viscoelasticity and rutting resistance of the modified asphalt.

In earthquakes and other natural disasters, there are often large and small debris on the road, which will affect the rapid passage of emergency vehicles. Installing lifting mechanism on the vehicle chassis is an effective way to solve this problem. However, the existing lifting mechanism lifting method is relatively single, occupies a large space, and is inconvenient to install underneath the vehicle. In addition, it also faces the problem that it can not be lifted flexibly with different working conditions. In order to solve these problems, this paper designs a metamorphic lifting mechanism based on the principle of metamorphic, which has the characteristics of variable topological configuration and variable degrees of freedom, and can complete the work task in different configurations according to different working conditions. For obstacles of different sizes, the mechanism can be elevated in one or two stages to realize rapid obstacle crossing. In this paper, after establishing the virtual prototype model of the metamorphic lifting mechanism, ADAMS software is used to carry out the configuration change dynamics simulation experiment, which investigates the dynamics of the vehicle in the process of configuration change and verifies the feasibility and stability of the mechanism.

Coumarins are a key class of heterocyclic lactone compounds, which have good biological activity. 3?sulfonyl coumarin derivatives were prepared by visible light promoted reaction of benzoalkynyl esters with sodium benzenesulfonate, and their reaction mechanism was studied. The results showed that under mild reaction conditions, 3?sulfonyl coumarin derivatives can be synthesized with moderate to good yields using sodium benzenesulfite as the precursor of sulfonyl radicals and persulfate as the oxidant through a cascade radical addition cyclization strategy, providing a concise, green, and efficient synthetic route for the preparation of functionalized coumarin derivatives.

The chemical storage tank area is a place with a large number of hazard sources, and the dynamic risk of the storage tank area cannot be quantified and characterized by traditional emergency management methods. Therefore, based on PPRR theory, a quantitative evaluation model of fire emergency management ability of chemical tank farm was established, and the weight of evaluation index was determined by interval analytic hierarchy process. The improved fuzzy comprehensive evaluation method was used to quantitatively evaluate the fire emergency management ability of chemical tank farm. This model is used to evaluate the fire emergency management ability of chemical tank farm of M Petrochemical Company, and the accuracy of this model is verified. The results show that the evaluation score of fire emergency management ability of chemical tank farm of M Petrochemical Company is 3.35, which is consistent with the qualitative evaluation result, and the accuracy of this model is verified. The model can solve the problem of uncertainty of the importance degree of the indicators, and the improved fuzzy comprehensive evaluation method can point out the deficiencies and degree of chemical tank farm, which can provide a new way to perfect and improve the fire emergency management ability of the chemical tank farm.

The effects of a single emulsifier octylphenol ethoxylate 10 (OP?10) and its compounding system on emulsion stability, rheology and the effect of organic bases on the interfacial tension were investigated. The results show that the optimal binary composition is as follows: The mass fraction of OP?10 is 1% and the mass fraction of sodium oleate (YSN) is 0.6%.The optimum compounding method can produce stable emulsion with thick oil, and the viscosity can be reduced from 1 168.22 mPa?s to 57.57 mPa?s, with the viscosity reduction rate of 91.03% and the water separation rate of 21.33%. The organobase triethanolamine (TEOA) can reduce the interfacial tension of the compounded system to the 10^-2 mN/m level.

Two adsorbents, magnesium aluminum calcined hydrotalcite (MgAl LDO) and magnesium aluminum iron calcined hydrotalcite (MgAlFe LDO), were synthesized by coprecipitation method, and characterized by X?ray powder diffraction (XRD) analysis, scanning electron microscopy (SEM) analysis, Fourier transform infrared spectroscopy (FT?IR) analysis and BET specific surface area test analysis, etc. The adsorption performance of the two adsorbents for fluoride in wastewater was also studied. The effects of the ratio of metal substances, calcination temperature, initial mass concentration of F^-, and adsorbent dosage on the removal efficiency of fluoride in wastewater were investigated. The results showed that MgAlFe LDO had a uniform pore structure distribution, a large specific surface area, and a higher adsorption capacity for fluoride in wastewater than that of MgAl LDO. When n (Mg²⁺)/n (Al³⁺)/n (Fe³⁺)=3.0∶0.6∶0.4, the initial mass concentration of F^- was 20 mg/L, the calcination temperature was 300 ℃, and the dosage of MgAlFe LDO was 0.4 g, the removal effect of fluoride in wastewater was optimal. After 2 hours of reaction, the removal rate of fluoride in the wastewater was 98.35%.

In order to explore the preparation process of graphene?reinforced composite materials with industrial development prospects, graphene/polypropylene composite materials were prepared using the melt blending method, and the graphene reinforcement mechanism was analyzed through experimental and computational analysis. The results indicate that through melt blending, graphene can be uniformly dispersed in the matrix. The tensile strength of the composite material with a graphene mass fraction of 0.5% is 50.3 MPa. When the mass fraction of graphene is 4.0%, the elastic modulus and tensile strength of the composites are increase by 77.1% and 22.5%, respectively, compared to the polypropylene matrix alone. The uniform dispersion of graphene and the interaction between graphene and the polypropylene matrix enable effective stress transfer at the graphene/polypropylene interface.

Hydrogen is regarded as a safe and sustainable supply of clean energy, which plays a very important role in alleviating the shortage of fossil energy and environmental pollution. Electrocatalytic water splitting is one of the effective ways to produce hydrogen. MoS₂ has been widely used in electrocatalytic hydrogen evolution reaction because of its low \mathrm{\Delta } G_H. This article summarizes the methods for improving the electrocatalytic hydrogen evolution performance of MoS₂, including inducing phase transition or exposing more catalytic active sites in MoS₂ through noble metal doping, and exposing more active sites or generating sulfur vacancies in MoS₂ through transition metal and non?metal doping. Meanwhile, some suggestions have been put forward to improve the catalytic performance of MoS₂.

Traditional physical simulation method of hydraulic fracturing has certain limitations in quantitatively studying fracture morphology and dynamically monitoring fracture propagation paths. It is challenging to quantitatively evaluate the dynamic processes of fracture initiation and propagation. Therefore, there is an urgent need to develop digital and intelligent technologies to enhance the accuracy of hydraulic fracturing physical simulation methods. Systematically investigated the method principle, research status and development direction of digital core reconstruction, acoustic emission positioning and distributed optical fiber monitoring, explored the data acquisition, fracture reconstruction and data interpretation in the process of multi?method joint monitoring experiment, and clarified the sample preparation, method combination and application scope in hydraulic fracturing physical simulation. The characteristics of non?plane, asymmetrical and unbalanced initiation and propagation of true triaxial hydraulic fracturing physical simulation are pointed out and outlooks are presented with the aim of helping researchers deeply understand the dynamic process of complex fracture expansion. Digital and intelligent hydraulic fracturing physical simulation methods are the future research trend. The research results can be used as reference for the development of hydraulic fracturing physical simulation technology, experimental scheme design.

As the global energy structure transitions toward cleaner and more sustainable sources, natural gas, as a low?carbon and environmentally friendly fossil fuel, continues to see increasing consumption. However, with the ongoing expansion of natural gas pipeline networks, the growing coverage areas, and the significant increases in both transportation distances and volumes, the safe operation of pipelines is facing unprecedented challenges, with pipeline leakage emerging as a particularly critical issue. In response to the long?term monitoring needs of oil and gas pipeline leaks, based on the principle of negative pressure wave detection, a highly efficient and reliable pipeline leakage monitoring simulation system was developed using LabVIEW, a powerful graphical programming platform. This system incorporates advanced sensor networks, data communication technologies, and signal processing algorithms. It was used for the leakage monitoring of oil and gas pipelines, and its performance was verified through experiments. The results show that the system is capable of detecting pipeline leakage and rapidly locating leakage points through efficient algorithms, providing crucial information for timely repair and ensuring the safety and stability of oil and gas pipelines.

In view of the huge scale of urban underground pipe network, the traditional manual detection method can no longer meet the needs of the current projects. In this paper, the MobileNetv3?YOLOv7 network model is proposed as the algorithm for target detection of underground pipeline defects to improve the accuracy and speed of detection. First, the pipeline image dataset is preprocessed, and the input image is grayscale and resampled to balance the number of samples. Secondly, the lightweight network MobileNetv3 and YOLOv7 network frameworks are combined to increase the BiFPN feature pyramid structure to improve accuracy. Then, in terms of data processing, Mosaic data augmentation is used to improve the robustness of the model. Finally, a comparative experiment with the YOLOv7 network model is designed to verify the feasibility of the model. In this paper, the MobileNetv3?YOLOv7 network model is verified under the framework of Pytorch experiment, and the experimental results show that the model greatly reduces the amount of parameter calculation and improves the average accuracy.

Carbon fiber reinforced epoxy resin matrix composites with light weight and high strength are widely used in aerospace, transportation, energy and other fields. The composition and structure of the interface are the main factors affecting the physical and chemical properties of composites. Surface modification of carbon fiber is one of the most effective ways to enhance the interfacial properties and mechanical properties of carbon fiber composites. In recent years, it's been found that porous materials with large specific surface area and diverse structures can improve the surface energy and surface roughness of carbon fibers and improve the interfacial properties of composites. This paper briefly introduces the modification of carbon fiber with different kinds of porous materials in recent years, and summarizes the interfacial strengthening effect of carbon fiber composites, which provides reference significance for the future research of porous materials reinforced carbon fiber composites.

The influence of curing temperature on catalytic desulfurization, nitrogen and acid removal of NiW/Al₂O₃ hydrotreating catalyst during the curing tprocess was studied. The catalyst with incomplete curing was re?cured and its hydrogenation performance was studied. The structure of the vulcanized catalyst was characterized by physical adsorption (BET), X?ray diffraction (XRD) and X?ray photoelectron spectroscopy (XPS). The results showed that the sulfur content and degree of vulcanization on the catalyst increased with the increase of vulcanization temperature, and the carbon accumulation also increased, which led to the decrease of the specific surface area, pore volume and average pore size of the catalyst. After vulcanization, the active phase of the catalyst changed from low active W⁶⁺ and Ni²⁺ to high active W⁴⁺ and Ni-W-S phases. After revulcanization, the pore volume and average pore size of the catalyst decreased, while the specific surface area, sulfur and carbon contents increased. The increase in carbon deposition covered part of the active center and reduced the atomic ratio of W and Al on the catalyst surface, resulting in the aggregation of active metals in the vulcanized state and reduced the activity of the catalyst, indicating that the revulcanized catalyst was difficult to achieve complete vulcanized catalyst activity.

Offshore oilfield development faces complex geological conditions and high development costs, with limited platform lifespans and well locations. These constraints reduce the effectiveness of chemical flooding for enhancing oil recovery. Based on the geological characteristics of offshore oilfields, and drawing on the results of synergistic enhanced oil recovery (EOR) techniques combining chemical flooding and infill well patterns in Daqing, Dagang, and Shengli oilfields, this study evaluates the synergistic potential of chemical flooding agents, well pattern infill, and layer adjustment. The synergy between chemical flooding and infill well pattern optimization for enhanced oil recovery was established. Relying on numerical simulation, an optimized design for synergistic chemical flooding and infill well patterns was developed for the SZ36?1 oilfield. The effects of reservoir permeability, permeability heterogeneity, and crude oil viscosity on enhanced oil recovery potential were clarified, along with the establishment of corresponding boundaries. The study demonstrated that after the original inverted nine?spot well pattern is encrypted into an oblique inverted nine?spot well pattern, the well spacing is reduced by half. Combined with polymer flooding technology, the recovery rate can be increased by 9.8%, which is 3.4% higher than the sum of the recovery increases achieved by independent water flooding and polymer flooding. This result confirms that by utilizing the synergistic effect of chemical flooding and infill well pattern technology in offshore oilfields, the sweep efficiency of the oil displacement system can be significantly enhanced, leading to a substantial increase in recovery rates and optimization of production capacity.

Superhydrophobic materials have become one of the research hotspots in coating directions in recent years because of their special wetting properties. Due to their anti?icing, self?cleaning, drag reduction and other characteristics, it has a wide range of application prospects. In this paper, SA?SiO₂/PPSsuperhydrophobic coatings with a thickness of about 38 μm were prepared on the surface of textile cloth using nano silica (SiO₂), stearic acid (SA) and polyphenylene sulfide (PPS) as raw materials by sol?gel method. The morphology was analyzed by electron scanning microscope, and the properties of the sample coating were tested. The microcosmic properties of the coating were analyzed by molecular dynamics simulation. The results show that the water contact angle of 56%SA?SiO₂/30%PPS coating is 154.8°, which shows good self?cleaning, corrosion resistance and soaping resistance. Scanning electron microscopy (SEM) analysis shows that the material has micro and nano?scale rough structure. The surface of SiO₂ and SA molecules was connected by hydrogen bond. The molecular dynamics simulation was consistent with the experimental data, and the corrosion resistance of the coating was verified from the microscopic point of view.

The low?permeability reservoir in Qiuling Oilfield of Tuha shows that the characteristics of early water discovery and rapid rise of water cut in some wells during water injection development, and dynamic analysis shows that there are dominant channels or the possibility of fractures in the reservoir. In order to further improve the development effect and enhance oil recovery, it is necessary to verify and determine the development of micro?fractures in the reservoir at the later stage of reservoir development. In this paper, based on the description of the core of a water washing inspection well, the development and distribution of reservoir fractures are studied, and a method of identifying the fracture development horizon based on logging curves are proposed. Through the analysis of logging data of two wells and the comparison of water absorption profiles, the method is proved to be feasible and reliable, and the study provides theoretical support for improving the development effect of water drive, effective utilization and recovery of remaining oil in Qiuling Oilfield of Tuha.

In view of the influence of different factors on the leakage and diffusion of hydrogen?doped natural gas pipelines in the pipe gallery, the leakage and diffusion model of hydrogen?doped natural gas pipelines in the pipe gallery was established by numerical simulation software, and the influence of factors such as hydrogen doping ratio, pipeline pressure，leakage hole size and the model of ventilation on the gas diffusion process was studied. The results show that the hydrogen blending ratio can affect the mass transfer ability of hydrogen?doped natural gas, and the higher the hydrogen blending ratio, the faster the diffusion rate of hydrogen?doped natural gas. The pipeline pressure and leakage hole size mainly affect the leakage gas diffusion by affecting the initial kinetic energy and leakage volume of the leakage gas, and the leakage gas diffusion range becomes larger with the increase of pipeline pressure and leakage hole size. The ventilation mode plays a dominant role in the distribution of leaked gas in the pipe gallery, and the ventilation frequency is inversely proportional to the height of the leaked gas jet.

An amorphous NiP?WC composite coating was prepared on a copper substrate by chemical plating. The corrosion resistance of the coating was studied in a NaCl solution with a mass fraction of 3.5% and a 1 mol/L hydrochloric acid solution. The surface morphology, composition, and microstructure of the coating were characterized by scanning electron microscopy (SEM), Energy dispersive spectrometer （EDS）, and X?ray diffraction (XRD). The corrosion resistance of the coating was analyzed by potentiodynamic polarization and impedance spectroscopy. The results show that in a NaCl solution with a mass fraction of 3.5%, the self corrosion potential of NiP?WC coating shifted approximately 111 mV higher as compared to amorphous NiP coating, resulting in a decrease of approximately 68.8% in self corrosion current density and an increase of approximately 6.7 times in charge transfer resistance. Soaking in 1 mol/L hydrochloric acid solution, the corrosion rate of NiP?WC coating decreased by about an order of magnitude compared to NiP coating, indicating that uniformly distributed WC particles can significantly improve the corrosion resistance of amorphous NiP.

Fuel cells have attracted widespread attention owing to the merits of high efficiency, high safety and wide application, etc. Therefore, fuel cells can meet the increasing requirement for clean energy in human society. Among them, anion exchange membrane fuel cells have shown broad application prospects due to the environmental friendliness, the use of non?precious metal catalysts, high safety and stability, etc. As the core component of anion exchange membrane fuel cells, anion exchange membranes can isolate the anode from the cathode and conduct hydroxide ions. Thus, the property of anion exchange membranes plays a crucial role in the performance of anion exchange membrane fuel cells. In the development process of anion exchange membranes, the low conductivity and poor hydroxide ions conductivity stability have become the key technical challenge. The development of flexible anion exchange membranes can play a positive role in promoting the further commercialization of anion exchange membrane fuel cells. Based on this, this article reviews the recent research progress on flexible anion exchange membranes from three aspects: polymer molecular chain design, structural optimization design, and new material synthesis and the composites.

The parameters of PID controller determine the stability and speed of tension control system, so it is important to study the parameter tuning optimization of classical PID controller in winding tension control. The PID tension controller based on the modified whale algorithm is designed by combining PID and modified whale optimization algorithm with winding tension control as an entry point. The improved whale algorithm (L?WOA) is combined with PID in order to improve its convergence speed and convergence accuracy when rectifying the PID parameters. A mathematical model and a dynamic torque balance equation are developed to analyze the effect of wire speed and web diameter on web tension. The parameters are optimized using the modified whale algorithm and various other algorithms, respectively, and the results show that the PID controller optimized by the improved whale algorithm proposed in this paper has the advantages of rapid response, more steady output, sturdy anti?interference ability and better robustness when the PID controller is controlled.

The pollution of tetracycline antibiotics in the water environment is increasingly serious, and the effective removal of residual antibiotics in water is an urgent problem to be solved. The co?precipitation method was used to prepare Cu?Al layered double hydroxides biochar composites (CuAl?LDH@BC) intending to remove tetracycline hydrochloride (TCH) from water. The physicochemical properties of the CuAl?LDH@BC surface were analyzed by SEM, XRD, and FTIR, and the adsorption performance of the tetracycline hydrochloride solution was revealed. The experimental results show that the adsorption process is more consistent with the quasi?second?order kinetic model and Langmuir model, and the maximum adsorption capacity of TCH is 78.68 mg/g at 298 K, and the neutral condition CuAl?LDH@BC has the best removal effect on TCH, which has strong anti?interference ability in water environment. The mechanisms involved in the adsorption of TCH by CuAl?LDH@BC may include hydrogen bonding, surface complexation, π-π interaction, and electrostatic interaction. The results show that Cu?Al layered double hydroxides and biochar composites, as low?cost and high?efficiency adsorbents, have a broad application prospect in the adsorption of tetracycline antibiotics in water.

As a high?risk area, the fire safety has always attracted much attention. Although smoke and flame alarm have been widely used, there are still problems such as single ?point detection and easy environmental impact. In response to such problems, a multi?way flame smart video monitoring system based on the B/S architecture is designed and implemented, and it is presented in the form of a web system. In the system, an improved YOLOV5 flame detection algorithm is integrated. The Ghost convolution is used to replace in conventional convolution to achieve the lightweight of the network, and the improved attention mechanism modules and small target detection anchor frame is added to enhance small target detection ability. Finally, the flame movement information extracted from the Optical flow network and the original flame data is sent into the improved YOLOV5 flame detection algorithm to further improve the detection accuracy of the flame. A large number of on?site test proves that the system can identify and locate the flames in the plant in real time. The detecting frame rate can reach 15 ms/frame, and the detection rate reaches 100%, which has high stability. An efficient and reliable fire monitoring solution is provided for the chemical industry.

During the extraction and transportation of waxy crude oil, paraffin will deposit on the wall, forming wax deposition. In recent years, microbial wax removal and prevention technology has been widely studied for its economic and environmental advantages. Five strains of bacteria were screened from crude oil sludge, and through the determination of their paraffin degradation rate and surface hydrophobicity, the bacterium B3 was selected and identified as Bruella intermedia. The experimental results showed that bacterial B3 had the best growth activity at a temperature of 40 ℃, an initial pH of 6, and a shaking table speed of 160 r/min, and had the best degradation effect on paraffin at this time. When bacteria B3 grows and metabolizes with paraffin as a carbon source, they can produce lipopeptide biosurfactants, with an emulsification coefficient of 52.5% for liquid paraffin. After 7 days of interaction between bacteria B3 and crude oil, the wax prevention rate reached 77.2%, and the viscosity reduction rate reached 50.2% at 41 ℃. Bacterial B3 can degrade paraffin, improve crude oil fluidity, and reduce wax deposition.

Dehydration of crude oil is an important step in the production and processing of crude oil. As oil fields enter the high water cut stage of production and the addition of oil recovery additives, dehydration becomes increasingly difficult, so the use of high?frequency electric fields for electric demulsification has become an effective means of dehydration. This article investigates the mechanism of electric dehydration under high?frequency electric field through static dehydration experiments and numerical simulations of droplet electric coalescence. It is found that the electric field strength, frequency, and duration have significant impacts on dehydration efficiency when treating crude oil with electric demulsification and dehydration. In the process of electric demulsification and dehydration, there is an optimal electric field frequency. After the electric field strength increases to a certain value, continuing to increase the electric field strength will actually lead to an increase in water content. After the electric field action reaches a certain time, continuing to increase the electric field action time will result in little change in the water content of crude oil; the greater the electric field strength applied to droplets in the electric field, the more likely the droplets are to deform, and the larger the diameter of the droplets, the more likely they are to deform; compared with the power frequency electric field, droplet coalescence efficiency is higher under high?frequency electric field, and droplets are more prone to coalescence. The research results provide theoretical support for the design and parameter optimization of crude oil electric dehydration units.