不同维度的NiCoP对析氢反应的影响

doi:10.12422/j.issn.1006-396X.2023.02.009

石油化工高等学校学报 ›› 2023, Vol. 36 ›› Issue (2): 70-77.DOI: 10.12422/j.issn.1006-396X.2023.02.009

不同维度的NiCoP对析氢反应的影响

李东¹(), 王昆彦¹^,², 王育乔¹()

^1.东南大学化学化工学院，江苏南京 211189
^2.金陵科技学院材料工程学院，江苏南京 211169

收稿日期:2022-05-06 修回日期:2022-06-11 出版日期:2023-04-25 发布日期:2023-05-06
通讯作者: 王育乔
作者简介:李东（1997⁃），男，硕士研究生，从事纳米光电材料方面的研究；E⁃mail：1024736601@qq.com。
基金资助:
国家自然科学基金项目(61774033)

Effects of NiCoP with Different Dimension on Hydrogen Evolution Reaction

Dong Li¹(), Kunyan Wang¹^,², Yuqiao Wang¹()

^1.School of Chemistry and Chemical Engineering，Southeast University，Nanjing Jiangsu 211189，China
^2.School of Materials Engineering，Jinling Institute of Technology，Nanjing Jiangsu 211169，China

Received:2022-05-06 Revised:2022-06-11 Published:2023-04-25 Online:2023-05-06
Contact: Yuqiao Wang

摘要/Abstract

摘要：

形貌调控是提升电催化析氢反应性能的重要途径。通过理论计算和实验验证相结合的方法，研究了不同维度的NiCoP对析氢反应的影响；构建了一维纳米线（NW?NiCoP）和二维纳米片（NS?NiCoP）的结构模型。结果表明，NW?NiCoP在费米能级附近具有更高的态密度，有利于电荷高效传输，而NS?NiCoP则具有更高的氢吸附能，有利于进行Volmer反应。采用水热和磷化两步法分别制备了NW?NiCoP、NS?NiCoP和三维杂化纳米片线（NSW?NiCoP）；对不同维度的NiCoP进行了电化学测试。结果表明，在电流密度为-10 mA/cm²时，NSW?NiCoP的过电位为45 mV。

关键词: NiCoP, 形貌调控, 不同维度, 析氢反应

Abstract:

Morphology regulation is an important way to improve the performance of electrocatalytic hydrogen evolution reaction. This paper investigated the effect of NiCoP with different dimension on the hydrogen evolution reaction by combining theoretical calculation and experimental analysis methods and constructed structural models of 1D nanowires (NW?NiCoP) and 2D nanosheets (NS?NiCoP).Simulation results show that NW?NiCoP exhibits higher electronic density of electronic states near the Fermi level, which is beneficial to efficient charge transfer. NS?NiCoP features higher hydrogen adsorption energy, which is favorable for the Volmer reaction.NW?NiCoP,NS?NiCoP,and 3D nanosheet?wires (NSW?NiCoP) were prepared by hydrothermal and phosphating processes. Electrochemical tests on NiCoP with different dimension indicate that the overpotential is 45 mV for NSW?NiCoP at -10 mA/cm².

Key words: NiCoP, Morphology regulation, Different dimension, Hydrogen evolution reaction

中图分类号:

TQ151

李东, 王昆彦, 王育乔. 不同维度的NiCoP对析氢反应的影响[J]. 石油化工高等学校学报, 2023, 36(2): 70-77.

Dong Li, Kunyan Wang, Yuqiao Wang. Effects of NiCoP with Different Dimension on Hydrogen Evolution Reaction[J]. Journal of Petrochemical Universities, 2023, 36(2): 70-77.

图/表 13

图1 不同维度NiCoP的制备流程图

Fig.1 Preparation flow chart of NiCoP with different dimension

图2 NS?NiCoP、NW?NiCoP优化后的理论模型及DOS和吸附能

Fig.2 Theoretical model after optimization， density of states and adsorption energy of NS?NiCoP and NW?NiCoP

图3 不同维度NiCoP的XRD曲线

Fig.3 XRD patterns of NiCoP with different dimension

图4 不同维度NiCoP的SEM和TEM图

Fig.4 SEM and TEM images of NiCoP with different dimension

图5 NSW?NiCoP的XPS谱图

Fig.5 XPS profile of NSW?NiCoP

图6 NF及不同维度NiCoP的LSV和Tafel曲线

Fig.6 LSV and Tafel curves of NF and NiCoP with different dimension

表1 不同文献报道的催化剂的HER性能

Table 1 HER activity with other reported catalysts

催化剂	过电位/mV	参考文献
NiCoP	108	[17]
NiCoP	34	[18]
Ni₂P	98	[19]
Co⁃Fe⁃P	86	[7]
MoP	86	[20]
NSW⁃NiCoP	45	本研究

图7 不同扫描速率下Ni及不同维度NiCoP的CV曲线

Fig.7 The CV curves of NiCoP with different dimension at different sweep velocities

图8 不同维度NiCoP的Cdl曲线

Fig.8 The Cdl curve of NiCoP with different dimension

图9 不同维度NiCoP的ECSA

Fig.9 The ECSA of NiCoP with different dimension

图10 NF及不同维度NiCoP的电荷转移阻抗

Fig.10 Charge transfer impedance of NF and NiCoP with different dimension

表2 EIS的模拟数据

Table 2 The simulated data from EIS

催化剂	R_s/Ω	R_ct/Ω	催化剂	R_s/Ω	R_ct/Ω
NSW⁃NiCoP	1.38	3.17	NS⁃NiCoP	1.67	3.87
NW⁃NiCoP	2.06	3.30	NF	1.51	6.76

图11 NSW?NiCoP的恒电压曲线及LSV曲线

Fig.11 The constant voltage curve and LSV curve of NSW?NiCoP

参考文献 20

1	宋楗，韩乔，杨占旭.NiMoP/C复合材料的制备及其电催化析氢性能［J］.石油化工高等学校学报，2022，35（1）：1⁃5.
	Song J，Han Q，Yang Z X.Preparation of NiMoP/C composite material and electrocatalytic hydrogen evolution performance［J］.Journal of Petrochemical Uneversities，2022，35（1）：1⁃5.
2	Wei G，Du K，Zhao X，et al.Cable⁃like carbon nanotubes decorated metal⁃organic framework derived ultrathin CoSe₂/CNTs nanosheets for electrocatalytic overall water splitting［J］.Chinese Chemical Letters，2020，31（10）：2641⁃2644.
3	Mahmood N，Yao Y，Zhang J W，et al.Electrocatalysts for hydrogen evolution in alkaline electrolytes：Mechanisms，challenges，and prospective solutions［J］.Advanced Science，2018，5（2）：1700464.
4	Wang P，Zhang X，Zhang J，et al.Precise tuning in platinum⁃nickel/nickel sulfide interface nanowires for synergistic hydrogen evolution catalysis［J］.Nature Communication，2017，8：14580.
5	Liu T，Liu D，Qu F，et al.Enhanced electrocatalysis for energy⁃efficient hydrogen production over CoP catalyst with nonelectroactive Zn as a promoter［J］.Advanced Energy Materials，2017，7（15）：1700020.
6	Feng J X，Tong S Y，Tong Y X，et al.Pt⁃like hydrogen evolution electrocatalysis on PANI/CoP hybrid nanowires by weakening the shackles of hydrogen ions on the surfaces of catalysts［J］.Journal of the American Chemical Society，2018，140（15）：5118⁃5126.
7	Chen J，Liu J，Xie J Q，et al.Co⁃Fe⁃P nanotubes electrocatalysts derived from metal⁃organic frameworks for efficient hydrogen evolution reaction under wide pH range［J］.Nano Energy，2019，56：225⁃233.
8	Liu J，Yuan Y，Guo X，et al.Mesocrystallizing nanograins for enhanced Li⁺ storage［J］.Advanced Energy Materials，2021，11（26）：2100503.
9	Li G，Song B，Cui X，et al.Multidimensional and binary micro CuCo₂O₄/nano NiMoO₄ for high⁃performance supercapacitors［J］.ACS Sustainable Chemistry & Engineering，2020，8（3）：1687⁃1694.
10	Lukowski M A，Daniel A S，English C R，et al.Highly active hydrogen evolution catalysis from metallic WS₂ nanosheets［J］.Energy & Environmental Science，2014，7（8）：2608⁃2613.
11	Perdew J P，Burke K，Ernzerhof M.Generalized gradient approximation made simple［J］.Physical Review Letters，1996，77：3865⁃3868.
12	Li J，Liu H X，Gou W，et al.Ethylene⁃glycol ligand environment facilitates highly efficient hydrogen evolution of Pt/CoP through proton concentration and hydrogen spillover［J］.Energy & Environmental Science，2019，12（7）：2298⁃2304.
13	Liu B，Zhao Y F，Peng H Q，et al.Nickel⁃cobalt diselenide 3D mesoporous nanosheet networks supported on Ni foam：An all⁃pH highly efficient integrated electrocatalyst for hydrogen evolution［J］.Advanced Materials，2017，29（19）：1606521.
14	Du C，Yang L，Yang F，et al.Nest⁃like NiCoP for highly efficient overall water splitting［J］.ACS Catalysis，2017，7（6）：4131⁃4137.
15	Lin Y，Pan Y，Liu S，et al.Construction of multi⁃dimensional core/shell Ni/NiCoP nano⁃heterojunction for efficient electrocatalytic water splitting［J］.Applied Catalysis B：Environmental，2019，259：118039.
16	Pan Y，Liu Y，Zhao J，et al.Monodispersed nickel phosphide nanocrystals with different phases：Synthesis，characterization and electrocatalytic properties for hydrogen evolution［J］.Journal of Materials Chemistry A，2015，3（4）：1656⁃1665.
17	Yang M，Huang Q，Luo X，et al.An electrocatalytically active pine cone like NixCoyP for high efficiency over water splitting［J］.Materials Letters，2021，303：130482.
18	Lü X，Li X，Yang C，et al.Large‐size，porous，ultrathin NiCoP nanosheets for efficient electro/photocatalytic water splitting［J］.Advanced Functional Materials，2020，30（16）：1910830.
19	Sun H M，Xu X B，Yan Z H，et al.Porous multishelled Ni₂P hollow microspheres as an active electrocatalyst for hydrogen and oxygen evolution［J］.Chemistry of Materials，2017，29（19）：8539⁃8547.
20	Zhang X，Yu X，Zhang L，et al.Molybdenum phosphide/carbon nanotube hybrids as pH⁃universal electrocatalysts for hydrogen evolution reaction［J］.Advanced Functional Materials，2018，28（16）：1706523.

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不同维度的NiCoP对析氢反应的影响

Effects of NiCoP with Different Dimension on Hydrogen Evolution Reaction

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