石油化工高等学校学报

石油化工高等学校学报 ›› 2008, Vol. 21 ›› Issue (4): 34-37.

• 石油化工 • 上一篇    下一篇

泥煤对铬(VI)吸附动力学研究

刘峙嵘1 , 2 , 周利民1 , 王晓鹏1   

  1. (1.东华理工大学应用化学系, 江西抚州344000; 2.东华理工大学核资源与环境教育部重点实验室, 江西南昌330013)
  • 收稿日期:2007-11-03 出版日期:2008-12-20 发布日期:2017-07-05
  • 作者简介:刘峙嵘(1969 -), 男, 江西萍乡市, 副教授, 博士
  • 基金资助:
    教育部留学回国人员科研启动基金资助项目
    ([ 2006] 331);东华理工大学博士基金
    (DH B0504);核资源与环境教育部重点实验室开
    放基金(070712)

Adsorption Kinetics of Peat for Chromium(VI)

LIU Zhi-rong 1, 2, ZHOU Li-min1, WANG Xiao-peng1   

  1. (1. Department of Applied Chemistry, East China University of Technology, Fuzhou Jiangxi 344000 , P. R. China; 2. Key Laboratory of Nuclear Resources and Environment, Ministry of Education, East China Institute of Technology, Nanchang Jiangxi 330013, P. R.China)
  • Received:2007-11-03 Published:2008-12-20 Online:2017-07-05

摘要: 对泥煤吸附Cr(VI)的动力学过程进行了研究。结果表明, pH 值和初始Cr(VI)质量浓度对Cr(VI)
的吸附率有明显的影响, pH 值越小, 泥煤表面正电性越高, Cr(VI)吸附率越高;初始C r(VI)质量浓度越小, Cr(VI)
吸附率越高;初始C r(VI)质量浓度位于10 ~ 20 mg/ L , 新型L-F 动力学模型能很好地描述泥煤吸附过程;新型L -
F 动力学方程直线化截距导出的参数Co /(Co -Ce)可以反映吸附剂的吸附强弱,“ 多化一” 法推出了Cr(VI)初始浓度
与吸附常数k 拟合函数关系。

关键词: 泥煤 , 铬(VI) , 吸附 , 动力学模型

Abstract: The adsorption kinetic process for Cr(VI)on peat was studied. The results show that pH values and initial mass concentrations of Cr(VI)have great influences on adsorption of Cr(VI). Smaller pH values with higher positive charge on the surface of peat and lower initial mass concentration of Cr(VI) were favor for higher adsorption of Cr(VI). New L-F kinetic model can describe procedures of adsorption of Cr(VI)on peat excellently in the 10~20 mg/L of initial mass concentration of Cr(VI). Intercepts derived from new L-F kinetic equation, Co/(Co-Ce) reflects the adsorption strength of peat. The "more to one " means can deduce fitting function relation between initial concentration of Cr(VI) and adsorption constants

Key words: Peat , Chromium(VI) ,  Adsorption , Kinetic model

引用本文

刘峙嵘, 周利民,王晓鹏. 泥煤对铬(VI)吸附动力学研究[J]. 石油化工高等学校学报, 2008, 21(4): 34-37.

LIU Zhi-rong,ZHOU Li-min, WANG Xiao-peng. Adsorption Kinetics of Peat for Chromium(VI)[J]. Journal of Petrochemical Universities, 2008, 21(4): 34-37.

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