氧化钙对生物质在超临界水中气化制氢的影响

石油化工高等学校学报 ›› 2007, Vol. 20 ›› Issue (1): 21-23.

氧化钙对生物质在超临界水中气化制氢的影响

王景昌^{1 , 2} , 　苑塔亮¹ , 　王　琨¹ , 　刘学武¹ , 　李志义¹

1. 大连理工大学, 辽宁大连116012;
2. 大连大学, 辽宁大连116622

收稿日期:2006-04-27 出版日期:2007-03-20 发布日期:2017-06-28
作者简介:王景昌(1964 - ), 男, 黑龙江肇源县, 副教授, 在读博士
基金资助:
辽宁省教育厅科学研究计划资助(20040060 ,05L029);国家自然科学基金项目(20676022)

Effect of CaO on Hydrogen Production by Vaporization From Biomass in Supercritical Water

WA NG Jing - chang ^1,2,YUAN Ta - liang¹,WANG Kun¹, LIU Xue - w u¹, LI Zhi - y i¹

1. Dalian University o f Technology , Dalian Liaoning 116012, P. R. China ;
2. Dalian University , Dalian Liaoning 116622, P. R. China

Received:2006-04-27 Published:2007-03-20 Online:2017-06-28

摘要/Abstract

摘要： 　利用自建的一套间歇式超临界生物质气化实验装置, 在水的近临界态和超临界态, 以葡萄糖为生物质模型化合物, 以制取氢气为目的进行实验研究。选用氧化钙为二氧化碳脱除剂, 对比在添加氧化钙前后, 反应温度、停留时间和n(Ca)/n(C)等因素对实验效果的影响。得出了新的超临界生物质气化制氢最佳工艺条件:温度在480 ～ 530 ℃, 压力在临界压力以上, 葡萄糖质量分数在2. 5%～ 5. 0%, 反应停留时间在3 ～ 5 min, n(Ca)/n(C)在0. 45～ 0. 52, H2 质量分数可以达到67. 5 %.

关键词: 超临界水, 　生物质, 　葡萄糖, 　氧化钙, 　氢气

Abstract:

　 Experiments for hydro gen production w ere carried out in subcritical and supercritical water in a batch - type reactor biomass set up by our selves. Glucose was used as a model compound, and CaO was used as CO₂remover in experiments. The effects of temperature , residence time and n (Ca) /n(C) on glucose reactions with and without CaO were examined by comparison and the optimal process for hydrogen production from biomass was also suggested. Under the condition of 480 ～530 ℃, above critical pressure , 2. 5%～ 5. 0 %mass fraction of glucose , 3～ 5 min resident time , n(Ca)/n(C) of 0. 45 ～ 0. 52 , the mass fraction of hydro gen is up to 67. 5 %.

Key words: Supercritical water, , Biomass, , Glucose, , CaO, , Hydrogen

王景昌, 苑塔亮, 王　琨, 等. 氧化钙对生物质在超临界水中气化制氢的影响[J]. 石油化工高等学校学报, 2007, 20(1): 21-23.

WA NG Jing - chang,YUAN Ta - liang,WANG Kun, LIU Xue - w u, LI Zhi - y i. Effect of CaO on Hydrogen Production by Vaporization From Biomass in Supercritical Water[J]. Journal of Petrochemical Universities, 2007, 20(1): 21-23.

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