相转化法制备疏松纳滤膜研究进展

doi:10.3969/j.issn.1006-396X.2022.01.007

石油化工高等学校学报 ›› 2022, Vol. 35 ›› Issue (1): 41-47.DOI: 10.3969/j.issn.1006-396X.2022.01.007

相转化法制备疏松纳滤膜研究进展

孙二强¹(), 姜永健², 张环宇³, 王昭旭¹, 赵凤阳¹(), 雷良才¹

^1.辽宁石油化工大学石油化工学院，辽宁抚顺 113001
^2.辽宁石油化工大学理学院，辽宁抚顺 113001
^3.西安航天动力技术研究所，陕西西安 710025

收稿日期:2020-09-28 修回日期:2020-11-28 出版日期:2022-02-25 发布日期:2022-04-14
通讯作者: 赵凤阳
作者简介:孙二强（1995⁃），男，硕士研究生，从事高性能吸附分离材料方面研究；E⁃mail：1559667016@qq.com。
基金资助:
国家自然科学基金青年基金项目(21808096);辽宁省科技厅博士启动项目(20170520259);辽宁省教育厅科研项目(L2017LQN003);辽宁石油化工大学引进人才科研启动基金资助(2016XJJ?071)

Research Progress of Loose Nanofiltration Membrane Prepared Via Phase Inversion Method

Erqiang Sun¹(), Yongjian Jiang², Huanyu Zhang³, Zhaoxu Wang¹, Fengyang Zhao¹(), Liangcai Lei¹

^1.School of Petrochemical and Engineering，Liaoning Petrochemical University，Fushun Liaoning 113001，China
^2.College of Science，Liaoning Petrochemical University，Fushun Liaoning 113001，China
^3.Xi'an Institute of Aerospace Propulsion Technology，Xi'an Shaanxi 710025，China

Received:2020-09-28 Revised:2020-11-28 Published:2022-02-25 Online:2022-04-14
Contact: Fengyang Zhao

摘要/Abstract

摘要：

随着纺织产业的兴起，印染废水的治理问题已成为行内关注的热点，其关键是如何高效分离有机染料和无机盐。疏松纳滤膜因其疏松的膜结构，在实现高染料截留率的同时具有良好的盐渗透性，在印染废水的治理方面具有独特优势。针对印染废水的治理问题，着重综述了近年来采用相转化法制备疏松纳滤膜的研究进展，研究了纳米材料改性对所制备疏松纳滤膜性能的影响,并对其存在的问题进行深入分析，以及对未来采用相转化法制备疏松纳滤膜的研究方向进行了展望。

关键词: 印染废水, 相转化, 疏松纳滤膜, 纳米材料

Abstract:

With the rise of the textile industry, the treatment of printing and dyeing wastewater has grown up to be a hot spot in the industry. The key is how to efficiently separate organic dyes and inorganic salts. Due to its loose membrane structure, the loose nanofiltration membrane has a high dye rejection rate and good salt permeability, which has unique advantages in the treatment of printing and dyeing wastewater. Article focuses on the research progress in the preparation of loose nanofiltration membranes by phase inversion. The effect of nanomaterial modification the performance of the prepared loose nanofiltration membranes. The existing problems are analyzed, and the future research direction of using phase inversion method to make loose nanofiltration membrane is prospected.

Key words: Printing and dyeing wastewater, Phase inversion, Loose nanofiltration membrane, Nanomaterial

中图分类号:

TQ028.8

孙二强, 姜永健, 张环宇, 王昭旭, 赵凤阳, 雷良才. 相转化法制备疏松纳滤膜研究进展[J]. 石油化工高等学校学报, 2022, 35(1): 41-47.

Erqiang Sun, Yongjian Jiang, Huanyu Zhang, Zhaoxu Wang, Fengyang Zhao, Liangcai Lei. Research Progress of Loose Nanofiltration Membrane Prepared Via Phase Inversion Method[J]. Journal of Petrochemical Universities, 2022, 35(1): 41-47.

参考文献 50

1	Lin J，Ye W，Baltaru M C，et al.Tight ultrafiltration membranes for enhanced separation of dyes and Na₂SO₄ during textile wastewater treatment［J］.Journal of Membrane Science，2016，514：217⁃228.
2	Tavangar T，Jalali K，Mohammad A A S，et al.Toward real textile wastewater treatment：Membrane fouling control and effective fractionation of dyes/inorganic salts using a hybrid electrocoagulation⁃nanofiltration process［J］.Separation and Purification Technology，2019，216：115⁃125．
3	Gao Y S，Mi Y F，Zhao F Y，et al.Zwitterions functionalized multi⁃walled carbon nanotubes/polyamide hybrid nanofiltration membranes for monovalent/divalent salts separation［J］.Separation and Purification Technology，2018，206：59⁃68．
4	Shang W，Sun F，Jia W，et al.High⁃performance nanofiltration membrane structured with enhanced stripe nano⁃morphology［J］.Journal of Membrane Science，2020，600：117852．
5	Qi Y，Zhu L，Shen X，et al.Polythyleneimine⁃modified original positive charged nanofiltration membrane：Removal of heavy metal ions and dyes［J］.Separation and Purification Technology，2019，222：117⁃124．
6	Shan L，Liang Y，Prozorovska L，et al.Multifold enhancement of loose⁃nanofiltration membrane performance by intercalation of surfactant assemblies［J］.Environmental Science & Technology Letters，2018，5（11）：668⁃674．
7	Liu S B，Wang Z，Song P.Free radical graft copolymerization strategy to prepare catechin modified chitosan loose nanofiltration （NF） membrane for dye desalination［J］.ACS Sustainable Chemistry & Engineering，2018，6（3）：4253⁃4263.
8	Trivedi J S，Bera A，Jewrajka S K，et al.Alkyl amine functional dextran macromonomer‐based thin film composite loose nanofiltration membranes for separation of charged and neutral solutes［J］.Journal of Applied Polymer Science，2017，134（37）：45301．
9	Hendrix K，Vaneynde M，Koeckelberghs G，et al.Synthesis of modified poly（ether ether ketone） polymer for the preparation of ultrafiltration and nanofiltration membranes via phase inversion［J］.Journal of Membrane Science，2013，447：96⁃106.
10	张瑛洁，郎野.相转化法制备碳捕集用聚偏氟乙烯膜及其改性的研究进展［J］.水处理技术，2015，41（8）：5⁃10．
	Zhang Y J，Lang Y.Research progress of preparation of PVDF film by phase inversion method and its modification for carbon capture［J］.Technology of Water Treatment，2015，41（8）：5⁃10．
11	Figueiredo A S，Sánchez⁃Loredo M G，Maurício A，et al.Tailoring of structures and permeation properties of asymmetric nanocomposite cellulose acetate/silver membranes［J］.Journal of Applied Polymer Science，2015，132（21）：41796.
12	Brami M V，Oren Y，Linder C，et al.Nanofiltration properties of asymmetric membranes prepared by phase inversion of sulfonated nitro⁃polyphenylsulfone［J］.Polymer，2017，111：137⁃147.
13	陈慧娟，纪晓声，陈霄翔，等.纤维素/壳聚糖共混纳滤膜的制备及其染料脱盐性能研究［J］.膜科学与技术，2018，38（4）：27⁃32．
	Chen H J，Ji X S，Chen X X，et al.Preparation of CEL/CS blend nanofiltration membranes for dyes desalination［J］.Membranes Science and Technology，2018，38（4）：27⁃32．
14	李祥，张忠国，任晓晶，等.纳滤膜材料研究进展［J］.化工进展，2014，33（5）：1210⁃1218．
	Li X，Zhang Z G，Ren X J，et al.Progress in nanofiltration membrane materials［J］.Chemical Industry and Engineering Progress，2014，33（5）：1210⁃1218．
15	Peng B L，Dhar N，Liu H L，et al.Chemistry and applications of nanocrystalline cellulose and its derivatives：A nanotechnology perspective［J］.Canadian Journal of Chemical Engineering，2011，89（5）：1191⁃1206.
16	Lessan F，Karimi M，Arami M.Tailoring the hierarchical porous structure within polyethersulfone/cellulose nanosheets mixed matrix membrane to achieve efficient dye/salt mixture fractionation［J］.Journal of Polymer Research，2016，23（9）：171．
17	Jia J，Cheng G J，Wu A H，et al.Novel imprinted polyethyleneimine nano⁃fluorescent probes with controllable selectivity for recognizing and adsorbing metal ions［J］.RSC Advances，2017，7（57）：36048⁃36055.
18	Zhu J Y，Zhang Y T，Tian M M，et al.Fabrication of a mixed matrix membrane with in situ synthesized quaternized polyethylenimine nanoparticles for dye purification and reusel［J］.Acs Sustainable Chemistry & Engineering，2015，3（4）：690⁃701．
19	赵凤阳，姜永健，刘涛，等.纳滤膜新型材料的研究［J］.化学进展，2018，30（7）：1013⁃1027．
	Zhao F Y，Jiang Y J，Liu T，et al.Nanofiltration membrane base on novel materials［J］.Progress in Chemistry，2018，30（7）：1013⁃1027．
20	王帅，王振，邱俊杰，等.零维、一维、二维无机纳米材料催化还原CO₂研究进展［J］.功能材料，2018，49（12）：12071⁃12078．
	Wang S，Wang Z，Qiu J J，et al.Research progress of 0D，1D and 2D inorganic nanomaterials as catalysts for the reduction of carbon dioxide［J］.Journal of Functional Materials，2018，49（12）：12071⁃12078．
21	陈平，高肖汉，翟玉春.SiO₂负载磷钨酸催化苯甲醚与乙酸酐反应［J］.石油化工高等学校学报，2011，24（4）：29⁃33．
	Chen P，Gao X H，Zhai Y C.Reaction of anisole with acetic anhydride over SiO₂ support phosphotungstic acid［J］.Journal of Pertochemical Universities，2011，24（4）：29⁃33．
22	Xing L X，Guo N N，Zhang Y T，et al.A negatively charged loose nanofiltration membrane by blending with poly （sodium 4⁃styrene sulfonate） grafted SiO₂ via SI⁃ATRP for dye purification［J］.Separation and Purification Technology，2015，146：50⁃59．
23	Yu L，Zhang Y T，Wang Y M，et al.High flux，positively charged loose nanofiltration membrane by blending with poly （ionic liquid） brushes grafted silica spheres［J］.Journal of Hazardous Material，2015，287：373⁃383．
24	梁旭，秦利娟，张亚涛，等.二氧化硅接枝聚合磷酸胆碱/聚醚砜复合膜的制备及性能［J］.高等学校化学学报，2018，39（3）：598⁃606．
	Liang X，Qin L J，Zhang Y T，et al. Preparatin and properties of Ploy⁃2⁃methacryloyloxyethyl phosphorylcholine grafted silica/polethersulfone composite membrane［J］.Chemical Journal of Chinese Universities，2018，39（3）：598⁃606．
25	Zhang Y T，Song Q Q，Liang X，et al.High⁃flux，high⁃selectivity loose nanofiltration membrane mixed with zwitterionic functionalized silica for dye/salt separation［J］.Applied Surface Science，2020，515：146005.
26	Akbari A，Homayoonfal M.Sulfonation and mixing with TiO₂ nanoparticles as two simultaneous solutions for reducing fouling of polysulfone loose nanofiltration membrane［J］.Korean Journal of Chemical Engineer，2016，33（8）：1⁃14．
27	Tavangar T，Mohammad K，Rezakazemi M，et al.Textile waste，dyes/inorganic salts separation of cerium oxide⁃loaded loose nanofiltration polyethersulfone membranes［J］.Chemical Engineering Journal，2020，385：123787．
28	Abdullayev E，Lvov Y.Halloysite clay nanotubes for controlled release of protective agents［J］.Journal of Nanoscience and Nanotechnology，2011，11（11）：10007⁃10026.
29	Lvov Y，Abdullayev E.Functional polymer⁃clay nanotube composites with sustained release of chemical agents［J］.Progress in Polymer Science，2013，38（10⁃11）：1690⁃1719.
30	Zhu J Y，Guo N N，Zhang Y T，et al.Preparation and characterization of negatively charged PES nanofiltration membrane by blending with halloysite nanotubes grafted with poly （sodium 4⁃styrenesulfonate） via surface⁃initiated ATRP［J］.Journal of Membrane Science，2014，465：91⁃99．
31	Wang Y M，Zhu J Y，Dong G Y，et al.Sulfonated halloysite nanotubes/polyethersulfone nanocomposite membrane for efficient dye purification［J］.Separation and Purification Technology，2015，150：243⁃251．
32	Ibrahim G P S，Isloor A M，Moslehyani A，et al.Bio⁃inspired，fouling resistant， tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation［J］.Journal of Water Process Engineering，2017，20：138⁃148．
33	Yu L，Zhang Y T，Zhang H Q，et al.Development of a molecular separation membrane for efficient separation of low⁃molecular⁃weight organics and salts［J］.Desalination，2015，359：176⁃185.
34	Lee J，Liu Z W，Jeong S，et al.Progress and challenges of carbon nanotube membrane in water treatment［J］.Critical Reviews in Environmental Science & Technology，2016，46（11⁃12）：999⁃1046．
35	Rahimi Z，Zinatizadeh A A，Zinadini S，et al.β⁃cyclodextrin functionalized MWCNTs as a promising antifouling agent in fabrication of composite nanofifiltration membranes［J］.Separation and Purifification Technology，2020，247：116979.
36	Mohammad P，Toraj M，Omid B，et al.Effective treatment of dye wastewater via positively charged TETA⁃MWCNT/PES hybrid nanofiltration membranes［J］.Separation & Purification Technology，2018，194：488⁃502．
37	Cohen⁃Tanugi D，Grossman J C.Water desalination across nanoporous graphene［J］.Nano Letters，2012，12（7）：3602⁃3608.
38	Huang K，Liu G P，Lou Y Y，et al.A graphene oxide membrane with highly selective molecular separation of aqueous organic solution［J］.Angewandte Chemie International Edition in English，2014，53（27）：6929⁃6932.
39	Qiu Z Y，Ji X F，He C J，et al.Fabrication of a loose nanofiltration candidate from polyacrylonitrile/graphene oxide hybrid membrane via thermally induced phase separation［J］.Journal of Hazardous Materials，2018，360：122⁃131．
40	Ji D W，Xiao C F，An S L，et al.Preparation of high⁃flux PSF/GO loose nanofiltration hollow fiber membranes with dense⁃loose structure for treating textile wastewater［J］.Chemical Engineering Journal，2019，363：33⁃42．
41	Zhu J Y，Tian M M，Hou J W，et al.Surface zwitterionic functionalized graphene oxide for a novel loose nanofiltration membrane［J］.Journal of Materials Chemistry A，2016，4（5）：1980⁃1990．
42	Cui X，Lee G H，Kim Y D，et al.Multi⁃terminal transport measurements of MoS₂ using a van der Waals heterostructure device platform［J］.Nature Nanotechnology，2015，10（6）：534⁃540.
43	Liang X，Wang P H，Wang J，et al.Zwitterionic functionalized MoS₂ nanosheets for a novel composite membrane with effective salt/dye separation performance［J］.Journal of Membrane Science，2019，573：270⁃279．
44	Liu J D，Yu L，Zhang Y T，et al.Fabrication and characterization of positively charged hybrid ultrafiltration and nanofiltration membranes via the in⁃situ exfoliation of Mg/Al hydrotalcite［J］.Desalination，2014，335（1）：78⁃86．
45	Yu L，Deng J M，Wang H X，et al.Improved salts transportation of a positively charged loose nanofiltration membrane by introduction of poly（ionic liquid） functionalized hydrotalcite nanosheets［J］.ACS Sustainable Chemistry & Engineering，2016，4（6）：3292⁃3304．
46	Wang J，Zhang Y T，Zhu J Y，et al.Zwitterionic functionalized layered double hydroxides nanosheets for a novel charged mosaic membrane with high salt permeability［J］.Journal of Membrane Science，2016，510：27⁃37．
47	Xia M S，Jiang Y S，Zhao L，et al.Wet grinding of montmorillonite and its effect on the properties of mesoporous montmorillonite［J］.Colloids & Surfaces A Physicochemical & Engineering Aspects，2010，356（1⁃3）：1⁃9.
48	Zhu J Y，Tian M M，Zhang Y T，et al.Fabrication of a novel "loose" nanofiltration membrane by facile blending with chitosan–montmorillonite nanosheets for dyes purification［J］.Chemical Engineering Journal，2015，265：184⁃193．
49	Camacho Bárbara C R，Ribeiro Rui P P L，Esteves Isabel A A C，et al.Adsorption equilibrium of carbon dioxide and nitrogen on the MIL⁃53（Al） metal organic framework［J］.Separation & Purification Technology，2015，141：150⁃159.
50	Ruan H M，Guo C M，Yu H W，et al.Fabrication of a MIL⁃53（Al） nanocomposite membrane and potential application in desalination of dye solutions［J］.Industrial & Engineering Chemistry Research，2016，55（46）：12099⁃12110．

[1]	高倩, 程丹, 段曼华, 肖伟. 燃料电池用高性能质子交换膜研究进展[J]. 石油化工高等学校学报, 2024, 37(4): 66-75.
[2]	于喜洋, 顾贵洲, 李政. 水滑石材料处理工业废水的研究进展[J]. 石油化工高等学校学报, 2021, 34(6): 16-21.
[3]	王光鑫，李华，赵桂艳，朱雨田. 碳系导电纳米材料填充高分子导电复合材料及其研究进展[J]. 石油化工高等学校学报, 2020, 33(5): 1-7.
[4]	王萌，李保山，吴建华，方大庆，王红峰，郑天水. 双电层纳米材料的制备及在防腐涂料中的应用[J]. 石油化工高等学校学报, 2018, 31(02): 14-19.
[5]	支树洁,张冬敏,张立新. 油温回升对含蜡原油添加纳米降凝剂改性影响[J]. 石油化工高等学校学报, 2011, 24(4): 13-16.
[6]	张永利. 利用Fenton试剂处理印染废水的过程参数优化[J]. 石油化工高等学校学报, 2009, 22(2): 38-40.

相转化法制备疏松纳滤膜研究进展

Research Progress of Loose Nanofiltration Membrane Prepared Via Phase Inversion Method

HTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献 50

相关文章 6

编辑推荐

Metrics