Progress of Molybdate⁃Based Perovskites as Anode Materials for Solid Oxide Fuel Cells

doi:10.12422/j.issn.1672-6952.2023.01.004

Abstract

Abstract:

Solid oxide fuel cells (SOFC) as one of the energy conversion devices, have received widespread attention and importance from all walks of life because of its clean and efficient operation. Anode is an important part of SOFC. It is important to find anode materials with good fuel catalytic activity in SOFC field. In recent years, molybdat?based perovskite materials as SOFC anodes show excellent conductivity and electrochemical properties at low and medium temperatures, and have been extensively studied by many research groups. In this paper, the research progress of molybdate?base perovskite as SOFC anode is reviewed, and the effects of different doping conditions on the properties of materials are summarized from the theoretical and experimental results, so as to provide guidance for the future research of materials.

Key words: Solid oxide fuel cell, Anode, Molybdate?based perovskite, Conductivity, Electrochemical performance, Thermal expansion

摘要：

固体氧化物燃料电池(SOFC)作为一种能量转换装置，因其清洁高效的工作方式，受到了社会各界的广泛关注和重视。阳极是SOFC的重要组成部分，寻找具有良好燃料催化活性的阳极材料是SOFC领域材料研究的重点工作。近年来，钼酸盐基钙钛矿材料作为SOFC阳极，在中低温区显示了优异的电导率和电化学性能，受到了国内外众多课题组的广泛关注。综述了钼酸盐基钙钛矿作为SOFC阳极的研究进展，从理论和实验的角度总结了不同掺杂情况对材料性能的影响，为今后材料的相关研究提供指导性的意见。

关键词: 固体氧化物燃料电池, 阳极, 钼酸盐基钙钛矿, 电导率, 电化学性能, 热膨胀

CLC Number:

TQ136.1

Yufu Yang, Jiangxin Li, Pengcheng Wang, Yuankui Teng, Fangjun Jin. Progress of Molybdate⁃Based Perovskites as Anode Materials for Solid Oxide Fuel Cells[J]. Journal of Liaoning Petrochemical University, 2023, 43(1): 21-26.

杨淯夫, 李江馨, 王鹏程, 滕元魁, 金芳军. 钼酸盐基钙钛矿作为固体氧化物燃料电池阳极材料的研究进展[J]. 辽宁石油化工大学学报, 2023, 43(1): 21-26.

Figures/Tables 4

样品	空间群	电导率/ (S•cm^-1)	TEC×10⁶/K^-1	最大功率密度/ (mW•cm^-2)	界面阻抗/ (Ω•cm²)	文献
CaV_0.5Mo_0.5-_x Ti _x O_3-_δ	Pm $3 ¯$ m	1.800~2.600				[25]
CaV_1-_x Mo _x O_3-_δ	Pm $3 ¯$ m	2.400~2.800				[26]
SrMo_1-_x Cr _x O_3-_δ	Pm $3 ¯$ m	2.100~2.600	11.27~12.85	527~695		[28]
SrMo_1-_x Fe _x O_3-_δ	Pm $3 ¯$ m	2.100~2.500	12.80~13.40	87~790		[29]
SrMo _x Ni_1-_x O_3-_δ	Pm $3 ¯$ m					[30]
SrMo_1-_x Mg _x O_3-_δ	Pm $3 ¯$ m	2.800~3.200	10.64~13.94	832~887		[31]
SrMo_1-_x Ga _x O_3-_δ	Pm $3 ¯$ m	2.200~2.500	9.98~17.32	560~785	0.65~0.66	[32]

样品	空间群	电导率/ (S•cm^-1)	TEC×10⁶/K^-1	最大功率密度/ (mW•cm^-2)	界面阻抗/ (Ω•cm²)	文献
CaV_0.5Mo_0.5-_x Ti _x O_3-_δ	Pm $3 ¯$ m	1.800~2.600				[25]
CaV_1-_x Mo _x O_3-_δ	Pm $3 ¯$ m	2.400~2.800				[26]
SrMo_1-_x Cr _x O_3-_δ	Pm $3 ¯$ m	2.100~2.600	11.27~12.85	527~695		[28]
SrMo_1-_x Fe _x O_3-_δ	Pm $3 ¯$ m	2.100~2.500	12.80~13.40	87~790		[29]
SrMo _x Ni_1-_x O_3-_δ	Pm $3 ¯$ m					[30]
SrMo_1-_x Mg _x O_3-_δ	Pm $3 ¯$ m	2.800~3.200	10.64~13.94	832~887		[31]
SrMo_1-_x Ga _x O_3-_δ	Pm $3 ¯$ m	2.200~2.500	9.98~17.32	560~785	0.65~0.66	[32]

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