Research Progress on the Influence of Metal Nanomaterials on Hydrate Formation

doi:10.12422/j.issn.1672-6952.2023.03.005

Abstract

Abstract:

Metal nanomaterials with high thermal conductivity are ideal promoters for enhanced gas hydrate formation, including metal?based nanoparticles, metal oxides, and metalloid oxides. In this paper, the effects of different kinds of metal nanomaterials on the formation of gas hydrates were reviewed, and the effects of parameters such as the induction time and gas consumption of enhanced hydrate formation were introduced from the three aspects of additive concentration, particle size and surface properties. The results show that the heat transfer effect of metal?based nanoparticles is better, and some metal oxides and metalloid oxides will exhibit an inhibitory effect; the appropriate addition concentration and particle size have an important impact on the formation of hydrates. In addition, the combination of metal nanomaterials and chemical reagents can significantly improve the dispersion stability of nanoparticles, thereby promoting the efficient generation of hydrates.

Key words: Metal nanomaterials, Hydrate, High thermal conductivity, Induction time, Gas consumption

摘要：

拥有高导热性的金属纳米材料是强化气体水合物生成的理想促进剂，金属纳米材料包括金属基纳米颗粒、金属氧化物和类金属氧化物。针对不同种类金属纳米材料促进气体水合物生成的影响进行了综述，分别从金属纳米材料的浓度、粒径以及表面性质三个方面对水合物生成的诱导时间和气体消耗量等参数的影响进行了介绍。结果表明，金属基纳米颗粒的传热效果较好，部分金属氧化物和类金属氧化物对气体水合物的生成具有抑制作用；添加适量的金属纳米材料的浓度和粒径对水合物的生成有重要的影响；此外，金属纳米材料与化学试剂复配可明显提升纳米颗粒的分散稳定性，进而促进水合物的高效生成。

关键词: 金属纳米材料, 水合物, 高导热性, 诱导时间, 气体消耗量

CLC Number:

TE09

Chang Sun, Weiwei Jian, Sai Ye, Shuai Wang. Research Progress on the Influence of Metal Nanomaterials on Hydrate Formation[J]. Journal of Liaoning Petrochemical University, 2023, 43(3): 28-33.

孙畅, 建伟伟, 叶赛, 王帅. 金属纳米材料影响水合物生成的研究进展[J]. 辽宁石油化工大学学报, 2023, 43(3): 28-33.

Figures/Tables 4

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促进剂	水合介质	w(促进剂)/%	诱导时间下降率/%	气体消耗量增加率/%
Al₂O₃	CH₄	0.3	72.0	52.7
CuO	CH₄	0.3	64.0	33.0
SiO₂	CH₄	0.3	74.0	59.0
Al₂O₃	CO₂	0.3	66.2	30.0
CuO	CO₂	0.3	64.6	24.7
SiO₂	CO₂	0.3	70.8	32.8

促进剂	水合介质	w(促进剂)/%	诱导时间下降率/%	气体消耗量增加率/%
Al₂O₃	CH₄	0.3	72.0	52.7
CuO	CH₄	0.3	64.0	33.0
SiO₂	CH₄	0.3	74.0	59.0
Al₂O₃	CO₂	0.3	66.2	30.0
CuO	CO₂	0.3	64.6	24.7
SiO₂	CO₂	0.3	70.8	32.8

粒径/nm	w（Al₂O₃）/%	诱导时间/min	气体消耗量/mol
10.0	0.1	14.5	0.212
30.0	0.1	5.5	0.334
50.0	0.1	20.0	0.324
10.0	1.0	16.9	0.216
30.0	1.0	7.0	0.320
50.0	1.0	22.8	0.315

粒径/nm	w（Al₂O₃）/%	诱导时间/min	气体消耗量/mol
10.0	0.1	14.5	0.212
30.0	0.1	5.5	0.334
50.0	0.1	20.0	0.324
10.0	1.0	16.9	0.216
30.0	1.0	7.0	0.320
50.0	1.0	22.8	0.315

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