石油化工高等学校学报

石油化工高等学校学报 ›› 2016, Vol. 29 ›› Issue (2): 18-22.DOI: 10.3969/j.issn.1006-396X.2016.02.004

• 石油化工 • 上一篇    下一篇

粘结组分对脱硫剂脱硫性能及机械强度的影响

陈逸斐1,2,冀德坤1,丁福臣1,2,迟姚玲1,易玉峰1   

  1. (1.北京石油化工学院化学工程学院,北京102617;2.北京化工大学化学工程学院,北京100029
  • 收稿日期:2015-12-18 修回日期:2016-03-20 出版日期:2016-04-25 发布日期:2016-05-06
  • 通讯作者: 冀德坤(1971-),男,博士,讲师,从事汽油改质技术方向研究;E-mail:jidekun@bipt.edu.cn。
  • 作者简介:陈逸斐(1990-),女,硕士研究生,从事油品脱硫研究;E-mail:chenyifei0024@163.com。
  • 基金资助:
    北京市教委资助项目(15032221001/004)。

 

Effects of Binder Component to Adsorptive Desulfurization Catalyst for FCC Gasoline on Desulfurization Performance and Mechanical Strength

 

Chen Yifei1,2, Ji Dekun1, Ding Fuchen1,2,Chi Yaoling1, Yi Yufeng1

  

  1.  

    1.School of Chemical Engineering Beijing Institute of Petrochemical Technology, Beijing 102617, China;

    2.School of Chemical Engineering Beijing University of Chemical Technology, Beijing 100029,China

  • Received:2015-12-18 Revised:2016-03-20 Published:2016-04-25 Online:2016-05-06

摘要: 以Al2O3、HNO3 等为粘结组分,ZnO 为储硫物质,Ni为活性成分,采用等体积浸渍法制备了Ni/ZnO
吸附脱硫剂。通过改变制备时粘结组分中的拟薄水铝石和硅藻土的质量比、硝酸用量、拟薄水铝石与硅藻土的总加
入量和载体混捏时间,考察了粘结组分对吸附脱硫剂活性及机械强度的影响。结果表明,随胶溶剂硝酸、拟薄水铝
石和硅藻土的总加入量增多,吸附脱硫剂脱硫性能提高,随载体中拟薄水铝石与硅藻土加入质量之比增大,吸附脱
硫剂脱硫性能先提高后降低存在最优值,随载体混捏时间增长吸附脱硫剂脱硫性能先提高后趋于稳定;随载体中拟
薄水铝石与硅藻土加入质量之比提高,加入胶溶剂硝酸减少,拟薄水铝石与硅藻土的总加入量增大,吸附脱硫剂机
械强度提高。

关键词: 脱硫剂, 粘结组分, 机械强度, FCC汽油

Abstract:  

Using Al2O3, HNO3 and other components as binder component, Ni as active component, ZnO as sulfur storage material, the adsorptive desulfurization catalyst was prepared by equal volume impregnation method. The effects of the Al/Si mass ratio, kneading time of the supporter, adding quality percentage of nitric acid and binder component on catalysts desulfurization performance and mechanical strength were investigated. The results showed that the catalysts desulfurization performancewas improved when the adding quality of nitric acid, pseudo boehmite and kieselguhr was increased. The desulfurization performance was increased and then decreased with increasing of Al/Si mass ratio, increased and then kept stable with increasing of kneading time. The catalysts mechanical strength was improved when the Al/Si mass ratio increased, the adding quantity of nitric acid decreased, pseudo boehmite and kieselguhr increased and the kneading time increased.

Key words:  

引用本文

陈逸斐,冀德坤,丁福臣,迟姚玲,易玉峰. 粘结组分对脱硫剂脱硫性能及机械强度的影响[J]. 石油化工高等学校学报, 2016, 29(2): 18-22.

Chen Yifei Ji Dekun, Ding Fuchen,Chi Yaoling, Yi Yufeng.  

Effects of Binder Component to Adsorptive Desulfurization Catalyst for FCC Gasoline on Desulfurization Performance and Mechanical Strength

[J]. Journal of Petrochemical Universities, 2016, 29(2): 18-22.

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