苏丹高酸值原油环烷酸分离及结构分析

doi:10.3696/j.issn.1006-396X.2011.04.001

石油化工高等学校学报 ›› 2011, Vol. 24 ›› Issue (4): 1-5.DOI: 10.3696/j.issn.1006-396X.2011.04.001

• 石油化工 • 下一篇

苏丹高酸值原油环烷酸分离及结构分析

胡科,彭勃^*,林梅钦,李明远,董朝霞

中国石油大学提高采收率研究中心,北京102249

收稿日期:2011-07-02 修回日期:2011-07-26 出版日期:2011-08-25 发布日期:2011-08-25
作者简介:胡科(1986 -), 男, 湖北钟祥市, 在读硕士
基金资助:
国家高科技发展计划“ 863 ” 项目(2008AA062207)

The Naphthenic Acids Separation and Structural Analysis of Sudan Crude Oil With High Acid Valu

Enhanced Oil Recovery Research Center, China University of Petroleum, Beijing 102249, P.R.China

Received:2011-07-02 Revised:2011-07-26 Published:2011-08-25 Online:2011-08-25

摘要/Abstract

摘要： 利用复合脱酸剂分离出苏丹高酸值原油中的环烷酸,并用电喷雾傅立叶变换离子回旋共振高分辨质谱(ESI-FT-ICR MS)及红外光谱(IR)分析了所分离出的环烷酸的分子结构。结果表明,苏丹高酸值原油中环烷酸红外光谱在3500~2500,1707,1500~800cm-1处具有明显的特征吸收峰,为典型的一元羧酸(脂肪酸和环烷酸)类化合物,无二元及多元酸。质谱分析点状图表明,原油中环烷酸以一、二、三环环烷酸为主,其中二环环烷酸含量最多,而且主要是碳数为26~34的二环环烷酸。环烷酸质谱分析点状图点数多且密集,环烷酸含量较为丰富。

关键词: 环烷酸, 脱酸, 高分辨质谱, 环数, 碳数分布

Abstract: The naphthenic acids of Sudan crude oil with high acid value were separated by compounding deacidification agent.The separated naphthenic acids were analyzed by electrospray ionization Fourier transform ion cyclotron resonance high resolution mass spectrometry(ESI-FT-ICR MS)and infrared spectrum(IR).The results show that there are obvious IR characteristic bands from 3500~2500,1707,1500~800cm-1,so they are typical monocarboxylic acids compounds(fatty acid and naphthenic acid),there are no binary and multivariate acids.MS Analysis point-like figure shows that the naphthenic acids of Sudan crude oil are mainly one,two and three-ring naphthenic acids,and the most content is two-ring naphthenic acids,the majority of which have 26 to 34 carbon number.MS Analysis point-like figure has many point-counts and they
arranged closely.The naphthenic acids content is very abundant.

Key words: Naphthenic acids, , Deacidification, , ESI-FT-ICR MS, , Ring number, , Carbon number distribution

胡科,彭勃,林梅钦,李明远,董朝霞. 苏丹高酸值原油环烷酸分离及结构分析[J]. 石油化工高等学校学报, 2011, 24(4): 1-5.

HU Ke, PENG Bo, LIN Mei-qin,et al. The Naphthenic Acids Separation and Structural Analysis of Sudan Crude Oil With High Acid Valu[J]. Journal of Petrochemical Universities, 2011, 24(4): 1-5.

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苏丹高酸值原油环烷酸分离及结构分析

The Naphthenic Acids Separation and Structural Analysis of Sudan Crude Oil With High Acid Valu

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