Research Progress of Multi⁃Function Anti⁃Corrosion Coatings

doi:10.12422/j.issn.1672-6952.2024.05.011

Abstract

Abstract:

Metal corrosion is an irreversible destructive behavior, therefore, the research of anticorrosive coatings has become a vital research topic in various fields. With the development of recent years, the single protective form of anti?corrosion coating is no longer sought after, the advent of barrier/self-healing coatings has added a significant complement to anti?corrosion coatings and has become one of the most widely studied topic today. Subsequently，new anti-corrosion forms such as ion exchange, hydrophobicity and intelligent self-warning have appeared on the market. Dual/multi-functional anti?corrosion coatings that integrate self-healing, barrier properties, hydrophobic properties and intelligent self-warning properties have also become research topics in recent years. In this paper, the research progress of barrier/self-healing bifunctional anti?corrosion coatings, other dual-function anti-corrosion coatings (ion exchange/self-healing coatings, hydrophobic/self-healing, self-warning/self-healing) and multi-functional anti-corrosion coatings are reviewed, and the future development direction of more intelligent and green dual/multi-functional coatings is prospected.

Key words: Corrode, Coating, Self-healing, Multifunction coating

摘要：

金属腐蚀是普遍存在且无法逆转的破坏性行为，随着服役环境越来越苛刻，金属部件的腐蚀问题日益突出，特别是其耐久性已无法满足工程应用的实际要求。因此，设计兼具不同功能的长期防护涂层、提升金属部件服役的耐久性迫在眉睫。涂层的最初属性是为金属基体提供强有力的阻隔性能，随后涂层逐渐被赋予了自修复功能。在阻隔/自修复涂层的研究快速发展的基础上，又出现了离子交换、疏水性和智能自预警等具备双/多功能特点的涂层。综述了作为研究主流的阻隔/自修复双功能涂层、其他型双功能涂层（离子交换/自修复涂层、疏水/自修复、自预警/自修复）以及多功能型防腐涂层的研究进展，并展望了双/多功能涂层智能化、绿色化的发展方向。

关键词: 腐蚀, 涂层, 自修复, 多功能涂层

CLC Number:

TE91

Yaxiong SUN, Fengting CAO, Tiegang WANG, Tao LI, Yong CHEN, Jinxin CAO, Yanmei LIU, Qixiang FAN. Research Progress of Multi⁃Function Anti⁃Corrosion Coatings[J]. Journal of Liaoning Petrochemical University, 2024, 44(5): 72-81.

孙亚雄, 曹凤婷, 王铁钢, 李涛, 陈勇, 曹金鑫, 刘艳梅, 范其香. 多功能型防腐涂层的研究现状及进展[J]. 辽宁石油化工大学学报, 2024, 44(5): 72-81.

Figures/Tables 4

References 61

1	邵冬雪，吴明，谢飞，等.不锈钢在海水中腐蚀特性研究进展［J］.辽宁石油化工大学学报，2018，38（1）：26⁃30.
	SHAO D X，WU M，XIE F，et al.The research progress of corrosion properties of stainless steel in seawater［J］.Journal of Liaoning Shihua University，2018，38（1）：26⁃30.
2	梁平，郑森，梁禹财.2205双相不锈钢单相的制备及其在氢氟酸溶液中的腐蚀行为［J］.当代化工，2023，52（11）：2602⁃2605.
	LIANG P，ZHENG S，LIANG Y C.Preparation of single phase in 2205 duplex stainless steel and its corrosion behavior in hydrofluoric acid solution［J］.Contemporary Chemical Industry，2023，52（11）：2602⁃2605.
3	程振玉，王丹，谢飞，等.油水两相流体系下的CO₂腐蚀行为研究［J］.辽宁石油化工大学学报，2022，42（1）：41⁃46.
	CHENG Z Y，WANG D，XIE F，et al.Study of CO₂ corrosion behavior under oil⁃water two⁃phase flow system［J］.Journal of Liaoning Petrochemical University，2022，42（1）：41⁃46.
4	ZHANG D D，PENG F，LIU X Y.Protection of magnesium alloys：From physical barrier coating to smart self⁃healing coating［J］.Journal of Alloys and Compounds，2021，853：157010.
5	石鑫，曾文广，刘冬梅，等.抗高温高氧曼尼希碱缓蚀剂的制备与缓蚀性能［J］.油田化学，2020，37（3）：510⁃514.
	SHI X，ZENG W G，LIU D M，et al.Preparation and corrosion inhibition of Mannich Base corrosion inhibitor with high temperature and high oxygen resistance［J］.Oilfield Chemistry，2020，37（3）：510⁃514.
6	CHEN Y H，WU L，YAO W H，et al."Smart" micro/nano container⁃based self⁃healing coatings on magnesium alloys：A review［J］.Journal of Magnesium and Alloys，2023，11（7）：2230⁃2259.
7	DONG M，ZHANG H，TZOUNIS L，et al.Multifunctional epoxy nanocomposites reinforced by two⁃dimensional materials： A review［J］.Carbon，2021，185：57⁃81.
8	LIN Y N，CHEN R R，ZHANG Y J，et al.Sandwich⁃like polyvinyl alcohol （PVA） grafted graphene：A solid⁃inhibitors container for long term self⁃healing coatings［J］.Chemical Engineering Journal，2020，383：123203.
9	YE Y W，CHEN H，ZOU Y J，et al.Study on self⁃healing and corrosion resistance behaviors of functionalized carbon dot⁃intercalated graphene⁃based waterborne epoxy coating［J］.Journal of Materials Science & Technology，2021，67：226⁃236.
10	FENG C，ZHU L J，CAO K Y，et al.Difunctional Silicon dioxide combined with graphene oxide nanocomposite to enhance the anticorrosion performance of epoxy coatings［J］.ACS Omega，2022，7（28）：24134⁃24144.
11	LI H，QIANG Y J，ZHAO W J，et al.2⁃Mercaptobenzimidazole⁃inbuilt metal⁃organic⁃frameworks modified graphene oxide towards intelligent and excellent anti⁃corrosion coating［J］.Corrosion Science，2021，191：109715.
12	WAN S，CHEN H K，CAI G Y，et al.Functionalization of h⁃BN by the exfoliation and modification of carbon dots for enhancing corrosion resistance of waterborne epoxy coating［J］.Progress in Organic Coatings，2022，165：106757.
13	MATANGOUO B，DEDZO G K，DZENE L，et al.Encapsulation of butylimidazole in smectite and slow release for enhanced copper corrosion inhibition［J］.Applied Clay Science，2021，213：106266.
14	GHAZI A，GHASEMI E，MAHDAVIAN M，et al.The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating［J］.Corrosion Science，2015，94： 207⁃217.
15	LI X J，XUE Z Y，SUN W T，et al.Bio⁃inspired self⁃healing MXene/polyurethane coating with superior active/passive anticorrosion performance for Mg alloy［J］.Chemical Engineering Journal，2023，454：140187.
16	PIAO J M，WANG W，CAO L，et al.Self⁃healing performance and long⁃term corrosive resistance of polyvinylidene fluoride nanofiber alkyd coating［J］.Composites Communications，2022，36：101404.
17	GHADERI M，SAADATABADI A R，MAHDAVIAN M，et al.PH⁃sensitive polydopamine⁃La（Ⅲ） complex decorated on carbon nanofiber toward on⁃demand release functioning of epoxy anti⁃corrosion coating［J］.Langmuir，2022，38（38）： 11707⁃11723.
18	ASADI N，NADERI R，MAHDAVIAN M.Synergistic effect of imidazole dicarboxylic acid and Zn²⁺ simultaneously doped in halloysite nanotubes to improve protection of epoxy ester coating［J］.Progress in Organic Coatings，2019，132：29⁃40.
19	LIU X H，CHENG Y C，WANG W，et al.Application of 1D attapulgite as reservoir with benzotriazole for corrosion protection of carbon steel［J］.Materials Chemistry and Physics，2018，205：292⁃302.
20	TONG H T，LIU X H，LIU Y P，et al.Polyaniline modified attapulgite incorporated in alkyd paint for carbon steel corrosion inhibition［J］.Corrosion Engineering， Science and Technology，2021，56（7）：618⁃625.
21	NAJMI P，KESHMIRI N，RAMEZANZADEH M，et al.Synthesis and application of Zn⁃doped polyaniline modified multi⁃walled carbon nanotubes as stimuli⁃responsive nanocarrier in the epoxy matrix for achieving excellent barrier⁃self⁃healing corrosion protection potency［J］.Chemical Engineering Journal，2021，412：128637.
22	ASAAD M A，RAJA P B，HUSEIEN G F，et al.Self⁃healing epoxy coating doped with slaesis guineensis/silver nanoparticles：A robust corrosion inhibitor［J］.Construction and Building Materials，2021，312：125396.
23	DONG J H，PAN W H，LUO J，et al.Synthesis of inhibitor⁃loaded polyaniline microcapsules with dual anti⁃corrosion functions for protection of carbon steel［J］.Electrochimica Acta，2020，364：137299.
24	张立畅，吴凯云，董佳豪，等.乳液模板法制备自修复缓蚀双功能微胶囊［J］.功能高分子学报，2022，35（3）：270⁃278.
	ZHANG L C，WU K Y，DONG J H，et al.Preparation of self⁃healing and anti⁃corrosion dual⁃function microcapsules via emulsion template method［J］.Journal of Functional Polymers，2022，35（3）：270⁃278.
25	ZHANG Z H，YAN D S，LIU X C，et al.Self⁃healing nanocomposite coatings containing organic⁃inorganic inhibitors functionalized dendritic silica nanocontainers for synergistic corrosion protection of carbon steel［J］.Colloids and Surfaces A： Physicochemical and Engineering Aspects，2023，656：130430.
26	GUO C B，LIAN Y B，HUANG C，et al.Sustained⁃release system based on BTA@MOF⁃5 for self⁃healing coating application［J］.Colloids and Surfaces A： Physicochemical and Engineering Aspects，2022，654：130139.
27	HE Z C，LIN H M，ZHANG X，et al.Self⁃healing epoxy composite coating based on polypyrrole@MOF nanoparticles for the long⁃efficiency corrosion protection on steels［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects， 2023，657：130601.
28	DAVOODI M，GHASEMI E，RAMEZANZADEH B，et al.Designing a zinc⁃encapsulated feldspar as a unique rock⁃forming tectosilicate nanocontainer in the epoxy coating；improving the robust barrier and self⁃healing anti⁃corrosion properties［J］.Construction and Building Materials，2020，243：118215.
29	ZHANG C，CHEN L，HE Y，et al.Designing a high⁃performance waterborne epoxy coating with passive/active dual self⁃healing properties by synergistic effect of V₂O₅@polyaniline⁃tannic acid inhibitors［J］.Progress in Organic Coatings，2021，151：106036.
30	董邯海，程勇，程庆利，等.六亚甲基二异氰酸酯微胶囊的制备及其在自修复涂料中的应用［J］.表面技术，2023，52（4）：272⁃284.
	DONG H H，CHENG Y，CHENG Q L，et al.Preparation of hexamethylene diisocyanate microcapsules and their application in self⁃healing coatings［J］.Surface Technology，2023，52（4）：272⁃284.
31	HOU L F，LI Y L，SUN J L，et al.Enhancement corrosion resistance of Mg⁃Al layered double hydroxides films by anion⁃exchange mechanism on magnesium alloys［J］.Applied Surface Science，2019，487：101⁃108.
32	TABISH M，ZHAO J M，WANG J B，et al.Improving the corrosion protection ability of epoxy coating using CaAl LDH intercalated with 2⁃mercaptobenzothiazole as a pigment on steel substrate［J］.Progress in Organic Coatings，2022，165：106765.
33	FANG S，CHEN K F，YAO H R，et al.Preparation of gallic acid intercalated layered double hydroxide for enhanced corrosion protection of epoxy coatings［J］.Coatings，2023，13（1）：128.
34	PANCRECIOUS J K，VINEETHA S V，BILL U S，et al.Ni⁃Al polyvanadate layered double hydroxide with nanoceria decoration for enhanced corrosion protection of aluminium alloy［J］.Applied Clay Science，2021，211：106199.
35	ABRANTES⁃LEAL D，WYPYCH F，BRUNO MARINO C E.Zinc⁃layered hydroxide salt intercalated with molybdate anions as a new smart nanocontainer for active corrosion protection of carbon steel［J］.ACS Applied Materials & Interfaces， 2020，12（17）：19823⁃19833.
36	AGHZZAF A A，RHOUTA B，ROCCA E，et al.Heptanoic acid adsorption on grafted palygorskite and its application as controlled⁃release corrosion inhibitor of steel［J］.Materials Chemistry and Physics，2014，148（1⁃2）：335⁃342.
37	AGHZZAF A A，RHOUTA B，ROCCA E，et al.Grafted palygorskite as containers of heptanoate for corrosion protection of steel in NaCl medium［J］.Corrosion Science，2017，114：88⁃95.
38	EMELYANENKO K A，EMELYANENKO A M，BOINOVICH L B.Laser obtained superhydrophobic state for stainless steel corrosion protection， a review［J］.Coatings，2023，13（1）：194.
39	CAO Y H，ZHENG D J，LUO J S，et al.Enhanced corrosion protection by Al surface immobilization of in⁃situ grown layered double hydroxide films co⁃intercalated with inhibitors and low surface energy species［J］.Corrosion Science，2020，164： 108340.
40	ZHOU Y，CHEN G B，YAN S G，et al.Epoxy composite coating with excellent anticorrosion and self⁃healing properties based on acrylate copolymers［J］.Progress in Organic Coatings，2022，172：107098.
41	XUE S Y，LI B F，MU P，et al.Designing attapulgite⁃based self⁃healing superhydrophobic coatings for efficient corrosion protection of magnesium alloys［J］.Progress in Organic Coatings，2022，170：106966.
42	ZHAO W，HAN X T，LU Y B，et al.Fabrication of mechanically robust urushiol⁃based polymer coatings with excellent self⁃healing property and hydrophobicity［J］.Progress in Organic Coatings，2023，174：107237.
43	GUO Z H，LI T，CHEN T L，et al.Salt⁃gated releasing effect to open visual self⁃reporting/self⁃repairing function of coatings toward corrosion protection［J］.ACS Sustainable Chemistry & Engineering，2023，11（12）：4738⁃4748.
44	WANG J K，MA L W，GUO X，et al.Two birds with one stone：Nanocontainers with synergetic inhibition and corrosion sensing abilities towards intelligent self⁃healing and self⁃reporting coating［J］.Chemical Engineering Journal，2022，433：134515.
45	LIU C B，WU H，QIANG Y J，et al.Design of smart protective coatings with autonomous self⁃healing and early corrosion reporting properties［J］.Corrosion Science，2021，184：109355.
46	LI W，TAO J J，CHEN Y X，et al.Porous microspheres with corrosion sensing and active protecting abilities towards intelligent self⁃reporting and anti⁃corrosion coating［J］.Progress in Organic Coatings，2023，178：107468.
47	SONG Y K，LEE T H，KIM J C，et al.Dual monitoring of cracking and healing in self⁃healing coatings using microcapsules loaded with two fluorescent dyes［J］.Molecules，2019，24（9）：1679.
48	SONG Y K，LEE T H，LEE K C，et al.Coating that self⁃reports cracking and healing using microcapsules loaded with a single AIE fluorophore［J］.Applied Surface Science，2020，511：145556.
49	TIAN H L，ZHAN Y C，TIAN L M，et al.Corrosion resistance self⁃healing coating with bioinspired interfacial structure［J］. Progress in Organic Coatings，2023，174：107303.
50	CHENG M，LIU J H，LIU Y Q，et al.Three birds with one stone： Contemporaneously boosting passive， active and self⁃healing properties for long⁃term anticorrosion coatings［J］.Chemical Engineering Journal，2023，459：141532.
51	HABIBIYAN A，RAMEZANZADEH B，MAHDAVIAN M，et al.Rational assembly of mussel⁃inspired polydopamine（PDA）⁃Zn（Ⅱ）complex nanospheres on graphene oxide framework tailored for robust self⁃healing anti⁃corrosion coatings application［J］.Chemical Engineering Journal，2020，391：123630.
52	LIN D，WANG X，ZHANG M，et al.A robust and eco⁃friendly waterborne anti⁃corrosion composite coating with multiple synergistic corrosion protections［J］.Composites Part B：Engineering，2022，232：109624.
53	ZHONG F，HE Y，WANG P Q，et al.One⁃step hydrothermal synthesis of reduced graphene oxide/aspartic acid intercalated layered double hydroxide for enhancing barrier and self⁃healing properties of epoxy coating［J］.Reactive and Functional Polymers，2019，145：104380.
54	HUANG Y，LIU T，MA L W，et al.Saline⁃responsive triple⁃action self⁃healing coating for intelligent corrosion control［J］. Materials & Design，2022，214：110381.
55	赵亚梅，曹婷婷，丁思奇，等.形状记忆环氧树脂/聚二甲基硅氧烷@ZnO@SiO₂自修复超疏水涂层及其防腐性能［J］.复合材料学报，2022，39（12）：5946⁃5957.
	ZHAO Y M，CAO T T，DING S Q，et al.Self⁃healing superhydrophobic shape memory epoxy resin/polydimethylsiloxane @ZnO@SiO₂ coating and its anticorrosion performance［J］.Acta Materiae Compositae Sinica，2022，39（12）：5946⁃5957.
56	BAI H H，ZHANG Z X，HUO Y J，et al.Tetradic double⁃network physical crosslinking hydrogels with synergistic high stretchable， self⁃healing， adhesive， and strain⁃sensitive properties［J］.Journal of Materials Science & Technology，2022，98：169⁃176.
57	LIU S P，WANG C J，LIU S Y，et al.pH⁃responsive smart composite coating with active anticorrosion and efficient scale inhibition properties［J］.Progress in Organic Coatings，2022，170：106973.
58	SUN Y，YUAN S C，FAN W H，et al.A smart composite coating with photothermal response，anti⁃UV and anti⁃corrosion properties［J］.Chemical Engineering Journal，2023，452：138983.
59	WU Y H，WEI J M，SHI X L，et al.Achieving anti⁃corrosion and anti⁃biofouling dual⁃function self⁃healing coating by natural carrier attapulgite loading with 2⁃Undecylimidazoline［J］.Journal of Materials Science & Technology，2023，148：222⁃234.
60	ZHANG T，DENG J，ZHANG L Z.A photothermal self⁃healing superhydrophobic coating with anti⁃frosting and anti⁃corrosion properties［J］.Progress in Organic Coatings，2023，180：107569.
61	ZHAO P Y，YAN J，YAN H M，et al.Wear and corrosion resistance of self⁃healing epoxy coatings filled by polydopamine⁃modified graphene oxide assembly of polysulfone double⁃walled microcapsules［J］.Progress in Organic Coatings，2023，177：107416.

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[2]	Rui Xun, Lijuan Wang. Preparation and Characterization of Polyaniline Coated Lithium Zinc Titanate Anode Materials [J]. Journal of Liaoning Petrochemical University, 2022, 42(1): 1-6.
[3]	Cheng Jianqiang， Wang Wenguang， Han Jie. Research Progress on Mechanical Properties of Carbon Fiber Reinforced Cement⁃Based Composites [J]. Journal of Liaoning Petrochemical University, 2021, 41(3): 33-42.
[4]	Hao Guodong， Su Shuangyue， Hao Chunli， Liu Binxia. Research Status on High Temperature Oxidation of Micro⁃Arc Oxidation of Titanium Alloy [J]. Journal of Liaoning Petrochemical University, 2021, 41(2): 21-26.
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[7]	Zhang Xiuming, Chen Shengjun, Deng Zilong, Jiang Wenquan, Yang Fan, Du Guangyu. Research on Damping Coating of Steam Turbine Blade Damping Coating [J]. Journal of Liaoning Petrochemical University, 2020, 40(3): 57-62.
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[9]	Yao Yuan. Salvage Technology of Corroded and Scale⁃Stucked Tubing in Bohai Oilfields: Taking SZ 36⁃1A Well as an Example [J]. Journal of Liaoning Petrochemical University, 2019, 39(2): 83-87.
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[15]	LIANG Ping. Electrochemical Study of Q235 Steel in the Snow Water in North Region [J]. Journal of Liaoning Petrochemical University, 2011, 31(3): 62-65.