Research Status of C4 Olefin Oligomerization and Catalysts

doi:10.3969/j.issn.1672-6952.2016.05.001

Journal of Liaoning Petrochemical University ›› 2016, Vol. 36 ›› Issue (5): 1-5.DOI: 10.3969/j.issn.1672-6952.2016.05.001

1.College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University,  Fushun Liaoning 113001, China; 2.Sinopec Catalyst (Beijing) Co., Ltd., Beijing 102400, China

Received:2016-03-25 Revised:2016-04-18 Published:2016-10-20 Online:2016-10-29

C₄ 烯烃叠合反应及催化剂研究现状

李丹阳¹,刘姝¹,王晓宁¹,孟凡立²

1.辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001;2.中石化催化剂(北京)有限公司,北京102400

通讯作者: 王晓宁(1972-),男,博士,副教授,从事化工节能技术及工艺流程设计;E-mail:wxning333@163.com。
作者简介:李丹阳(1989-),女,硕士研究生,从事化工新技术的研究;E-mail:li1798666@126.com。
基金资助:
国家自然科学基金项目(21276120);辽宁省科技厅产业基地发展建设计划项目(2011415048)。

Abstract

Abstract: The research status of C₄olefin polymerization at home and abroad is briefly described, and the chemical utilization ways of C₄ olefins are summarized combining with the progress of relevant technology. Isobutylene was used as an example to introduce the chemical reaction mechanism of the oligomerization; the catalytic properties and research situation of solid phosphoric acid catalyst, zeolite catalyst are emphatically described. According to the present situation of the utilization of low carbon olefins in China, the development prospects and suggestions of C₄ are put forward.

Key words:

C₄ olefin, Oligomerization, Mechanism, Situation of solid phosphoric acid, Zeolite

摘要： 简述了国内外C₄ 烯烃叠合反应的研究现状,结合相关技术进展对C₄ 烯烃的化工利用途径进行了归纳。以异丁烯为例,介绍了叠合反应的化学反应机理;着重阐述固体磷酸催化剂、分子筛催化剂的催化性能和研究概况。针对我国低碳烯烃的利用现状,提出了C₄ 烯烃的发展应用前景和建议。

关键词: C₄ 烯烃, 叠合反应, 机理, 固体磷酸, 分子筛

Li Danyang, Liu Shu Wang Xiaoning, Meng Fanli. Research Status of C₄ Olefin Oligomerization and Catalysts[J]. Journal of Liaoning Petrochemical University, 2016, 36(5): 1-5.

李丹阳,刘姝,王晓宁,孟凡立. C₄ 烯烃叠合反应及催化剂研究现状[J]. 辽宁石油化工大学学报, 2016, 36(5): 1-5.

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Research Status of C₄ Olefin Oligomerization and Catalysts

C₄ 烯烃叠合反应及催化剂研究现状

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