Journal of Liaoning Petrochemical University
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Research Progress on Modification of Bismuth Oxide as Visible Light Photocatalyst
Yonghui Zhang, Xuebing Chen, Jing Zhang
Abstract4149)   HTML    PDF (1443KB)(914)      

As an important semiconductor photocatalytic material, bismuth oxide (Bi2O3) is considered as a promising visible photocatalyst due to its special electronic structure and excellent visible light response performance. It displays a good application prospect in photocatalytic treatment of wastewater. However, the application of Bi2O3 is limited by its low photocatalytic performance, therefore, Bi2O3 pholocatalyst with superior performance is expected to be obtained by modifying methods by the researchers. In this review, a series of modification methods, such as surface morphology regulation, surface modification, metal ion modification and semiconductor combination, are summarized. Then, the future development of modified Bi2O3 photocatalytic materials is prospected.

2021, 41 (6): 1-8. DOI: 10.3969/j.issn.1672-6952.2021.06.001
Review of Copper⁃Based Catalysts for Electrocatalytic Reduction of Carbon Dioxide
Guohua Diao, Liwei Pan, Lin Fan, Xinyu Han, Hexiang Zhong
Abstract3049)   HTML    PDF (855KB)(506)      

With the rapid economic development, the demand for energy continues to increase, and the emission of CO2 gas keep growing. The electrochemical reduction of carbon dioxide (ERC) to fuel and chemicals is an effective way to realize the conversion and utilization of CO2 as well as the storage of renewable energy. Cu?based catalysts are one of the materials which can directly reduce CO2 to high value?added chemicals(such as hydrocarbons) with high efficiency. Thus, the Cu?based catalysts have been one of the research focus of ERC technology research. The main research progress of Cu?based catalysts for ERC technology in recent years is reviewed. Firstly, reaction principle of ERC and the technology challenge are summarized, and then the cooperative control strategy for the structure and composition of copper?based catalysts is discussed for monometallic copper?based catalysts, polymetallic copper?based catalysts, copper oxide and oxide?derived copper catalysts, and copper?organic composite catalysts. In addition, research progress and unsolved problems of Cu?based catalysts are also summarized. Finally, the future trend these catalysts is also prospected.

2021, 41 (4): 1-8. DOI: 10.3969/j.issn.1672-6952.2021.04.001
Abstract2672)      PDF (2792KB)(139)      
2022, 42 (3): 0-.
Abstract2487)      PDF (6292KB)(263)      
2022, 42 (1): 0-.
Analysis of Factors Affecting the Dehydration Effect of Shale Gas Triethylene Glycol Dehydration Unit
Kexi Liao, Min'an Wang, Hao Peng, Guoxi He, Jihui Leng
Abstract2485)   HTML    PDF (2294KB)(202)      

In different production stages of shale gas fields, various operating conditions and parameters vary widely, and the operating conditions of the triethylene glycol dehydration unit may deviate from the optimal range, which may easily lead to insignificant dehydration effects, which will affect normal production. The HYSYS software was used to simulate the process of a 300.0×104 Nm3/d shale gas triethylene glycol dehydration unit.The influence of the process parameters on the dehydration effect of the triethylene glycol such as the triethylene glycol circulation volume, the mass fraction of the triethylene glycol lean liquid, the flow rate of the feed gas into the tower, and the temperature of the feed gas into the tower,the operating pressure of the absorption tower, the temperature of the lean triethylene glycol liquid entering the tower, the total efficiency of the trays and the number of trays in the absorption tower were quantitatively analyzed.And the reasonable operating range of each process parameter was determined to achieve the best dehydration effect and meet the requirements of dry gas export. The results show that increasing the triethylene glycol circulation, lean liquid mass fraction, absorption tower operating pressure, total tray efficiency and number of absorption trays, as well as reducing the flow and temperature of feed gas into the tower, and the temperature of triethylene glycol lean liquid entering the tower are all helpful to improve the dehydration effect of triethylene glycol; increasing the temperature of the reboiler and the flow of stripping gas are beneficial to increase the mass fraction of the lean triethylene glycol. In addition, the HYSYS simulation calculation results are compared with the on?site production data. The results show that the two are basically consistent, which verifies the accuracy of the simulation calculation results, which can be used to guide actual production. The above research has certain guiding significance for improving dehydration efficiency and reducing investment cost.

2021, 41 (5): 1-8. DOI: 10.3969/j.issn.1672-6952.2021.05.001
Design of L∞ Reliable Controller for Delayed Systems with Controller Failure
Li Chang, Li Xin, Nie Hong
Abstract2308)      PDF (1508KB)(257)      
The problem of robust L∞ reliable control for a class of time-delay systems with controller failures is investigated. Based on the idea of switching, the system with possible failure of the controller is transformed into a switching system with two subsystems, one of which is a stable subsystem without controller failure and the other is unstable in the event of controller failure subsystem. By using the multiple Lyapunov function theory and the average dwell-time method, the exponential stabilization and L∞performance of LMI are obtained, and the design scheme of the L∞reliable switching controller is obtained. Finally, the effectiveness of the scheme is verified by simulation.
2017, 37 (6): 60-66. DOI: :10.3969/j.issn.1672-6952.2017.06.01
Abstract2248)   HTML    PDF (3367KB)(95)      
2022, 42 (2): 0-.
Abstract2228)      PDF (5011KB)(147)      
2022, 42 (4): 0-.
Electrochemical Behaviors of Ferrocene Using Cyclic Voltammetry
Qiao Qingdong, Li Qi
Abstract2108)      PDF (1784KB)(1108)      
The ferrocene shows definite aromatic and redox properties, which can used as a switch model substance. In alcohol solution of lithium perchlorate, the redox reaction process of ferrocene is quasi-reversible, in which the electron transfer number determined is 1, and the diffusion coefficients of ferrocene ion (Fc+) and Fc are 2.24×10-3 cm2/s and 4.34×10-3 cm2/s, i.e. the diffusion velocity of Fc+ is faster than Fc. The standard rate constant tested is 2.79 cm/s.
2014, 34 (3): 5-7. DOI: 10.3696/j.issn.1672-6952.2014.03.002
Effect of Chloride Ion on Corrosion Resistance of 2205 Duplex  Stainless Steel in Hydrofluoric Acid
Pang Xuguang, Hou Guanyu, Liang Ping
Abstract1988)      PDF (2187KB)(301)      
The corrosion behavior of 2205 duplex stainless steel (DSS) in hydrofluoric acid (HF) was affected by the chlorine ion. The methods including immersion, potentiodynamic polarization and electrochemical impedance spectra (EIS) were used to understand the effect. The results showed that while the NaCl concentration was added into HF solution from 0.015 mol/L to 0.030 mol/L, the corrosion potential got more positive, and the corrosion current density and average corrosion rate increased with the increasing NaCl content. It was because that NaCl decreased the pH of HF solution.
2018, 38 (02): 30-32. DOI: 10.3969/j.issn.1672-6952.2018.02.007
Preparation and Characterization of Polyaniline Coated Lithium Zinc Titanate Anode Materials
Rui Xun, Lijuan Wang
Abstract1564)   HTML    PDF (1733KB)(287)      

The Li2ZnTi3O8@polyaniline (LZTO@PANI) composite materials were prepared by sol?gel and chemical oxidation polymerization methods using tetrabutyl titanate, zinc acetate, lithium acetate and aniline as raw materials. The materials were characterized and analyzed by X?ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscope (SEM) transmission electron microscope (TEM) and electrochemical testing. The results show that the polyaniline in the composite material has an amorphous structure and no impurities are introduced. When the coating amount of polyaniline is 5.3%, the discharge specific capacity is 330.0 (mA·h)/g at 0.1 A/g. In addition, after 100 cycles, the specific discharge capacity is 281.3 (mA·h)/g.

2022, 42 (1): 1-6. DOI: 10.3969/j.issn.1672-6952.2022.01.001
Abstract1546)      PDF (1881KB)(127)      
2022, 42 (6): 0-.
Abstract1361)      PDF (3366KB)(182)      
2023, 43 (2): 0-.
Abstract1311)      PDF (2228KB)(121)      
2023, 43 (1): 0-.
Research Progress of Reaction Mechanism of Carbon Dioxide Hydrogenation to Methanol
Wang Yan, Wang Xiaoyue, Cao Ruiwen, Ban Hongyan, Li Congming
Abstract1255)   HTML    PDF (3312KB)(880)      
With the rapid development of industry, the negative impact of the use of fossil fuels on the ecological environment is becoming more and more prominent. Among them, CO2, as the main greenhouse gas, causes serious harm to global climate change. The selective hydrogenation of CO2 to methanol is one of the important ways to solve the greenhouse effect, develop green energy and realize sustainable economic development. Copper⁃based catalysts are widely employed for CO2 hydrogenation to methanol due to their excellent catalytic performance and low cost. The difference in reaction mechanism is due to the highly adjustable chemical and electronic properties of copper⁃based catalysts, resulting in the different catalytic performance. This article reviewed the representative reaction mechanism of selective hydrogenation of CO2 to methanol over copper⁃based catalysts was presented, aiming to provided a theoretical guidance for the design of efficient and stable copper⁃based catalysts.
2020, 40 (4): 11-20. DOI: 10.3969/j.issn.1672-6952.2020.04.003
Stress Analysis of Pressure Vessel Tube Sheet Based on ANSYS Workbench Software
Qian Han,Zhang Yingying,Gao Lei
Abstract1248)      PDF (5480KB)(466)      
The finite element analysis software ANSYS Workbench is used to analyze the tube shell of shell-and-tube heat exchanger. According to the stress analysis standard JB 4732—1995, the stress intensity of tube sheet under four kinds of transient and steady-state operating conditions which may occur during normal operation, start-up and shutdown are analyzed. The results show that the maximum stress occurs at the junction of the heat exchange tube and the tube sheet and the joint between tube and tube sheet. The main influencing factor of the connection strength between the heat exchange tube and the tube sheet and the connection strength between tube and tube sheet is the pressure load.According to the strength check results, the design of the heat exchanger conforms to the standard of use.
2018, 38 (06): 70-75. DOI: 10.3969/j.issn.1672-6952.2018.06.013
Simulation Study on Residual Stress of Nickel-Based Superalloys Based on Deform-3D
Shi Ruotong, Deng Zilong, Gao Xingjun, Zhang Shaoyu, Luo Lin
Abstract1178)      PDF (3252KB)(413)      
GH4169 Nickel-based superalloys widely used, but it was difficult to cut.The residual stress of the machined surface could easily lead to the deformation of the workpiece, thereby the machining quality of the workpiece was affected.The variation of residual stress under different cutting parameters was studied by the simulation software Deform-3D. Simulation results showed that the change of cutting speed had little influence on the surface residual stress, the surface residual stress was increased with the increase of the cutting depth and the feed rate. The residual stress in workpiece was increased with the increased cutting parameters.
2017, 37 (4): 49-52. DOI: 10.3969/j.issn.1672-6952.2017.04.011
Progress in Photoinduced Atom Transfer Radical Polymerization
Cui Haiqing,Cui Ye,Liu Furui,Lei Liangcai,Li Haiying
Abstract1132)      PDF (1824KB)(290)      
Photoinduced ATRP is a controlled radical polymerization in the presence of UV/visible light and can be used to synthesize functional polymer materials which can control the molecular structure. The polymerization kinetics was studied by changing illumination time, intensity and frequency of the light source. The amount of transition metal catalyst in photo-induced ATRP polymerization is reduced to less than 100 μg/g, which makes industrial application of controlled free radical technology possible. In this paper, the research progress of direct/indirect light-induced atom transfer radical polymerization (ATRP) is reviewed from the aspects of light source, catalyst, ligand and initiator.
2018, 38 (03): 29-34. DOI: 10.3969/j.issn.1672-6952.2018.03.006
Abstract1093)      PDF (2030KB)(77)      
2022, 42 (5): 0-.
Abstract1090)   HTML    PDF (1813KB)(82)      
2021, 41 (3): 0-.
Correlation Analysis among Real Estate Development Investment ,GDP and House Price in China
YuDan, QinJie, FangDan, WangBo, KuaiChuting
Abstract1078)      PDF (1686KB)(1019)      
In recent years, due to excessive freedom, some real estate developers' speculation and other reasons, the real estate market prices drift influenced national welfare and the people's livelihood. So this problem needed to be solved. In order to explore the deep-seated reasons affecting China's housing prices, study the irrationality of housing prices and solve the problem, the time series data was selected from 2005 to 2014, using E-view analysis software, through cointegration test, Grainger causality test and generalized impulse response function method, analyzes the impact of China's GDP and real estate development investment to changes in prices. The research results showed that China's GDP had long-term stable equilibrium relationship of prices, and price influence of real estate development and investment gradually weakened with the passage of time.  
 
2017, 37 (1): 70-74. DOI: 10.3969/j.issn.1672-6952.2017.01.014

Study on the Interface of Monitoring Configuration Software Based on SVG

Liu Yi, Hou Ligang
Abstract1063)      PDF (1387KB)(304)      

The graphical interface is one of the basic components of the monitoring configuration software, which has a great impact on the software. However, a variety of configuration software currently used different graphic styles to form the monitor screen, so that different systems interact difficultly. To overcome this shortcoming and improve the reusing rate of code writing monitor screen and enhance applications efficiency of dealing with a lot of graphics information, this paper sets up a monitoring graphics elements library of configuration software, which uses SVG recommended by the international image formats of monitoring interface, and elaborates the way to define equipment element property. Integrating Batik project of ASF (Apache software foundation) and adopting Object Orient Design Thought, the paper analyses and designs the monitoring graphics elements library module of configuration software. Configuring graph's properties as the corresponding with relational SQL datebase which facilitate the programmer inputs data, can improve the total level of the configuration software.

2016, 36 (6): 60-63. DOI: 10.3969/j.issn.1672-6952.2016.06.013
The Research Progress of Corrosion Properties of Stainless Steel in Seawater
Shao Dongxue, Wu Ming, Xie Fei, Wang Dan
Abstract1061)      PDF (3381KB)(419)      
Stainless steel was widely used in industrial production with its excellent oxidation resistance, corrosion resistance and other properties. But in the marine environment, the stainless steel material was affected by the seawater environment easily and the corrosion resistant properties reduced. It was analyzed that the corrosion mechanism of stainless steel in seawater, and the influence factors of influence in seawater corrosion of stainless steel were discussed from the angle of content, salinity, dissolved oxygen and water flow rate, microbial. Finally the research situation of the current stainless steel anti-corrosion technology was discussed.
2018, 38 (1): 26-30. DOI: 10.3969/j.issn.1672-6952.2018.01.005
Research on the Integrity Detection of Aluminum Foil Sealing Based on Infrared Imaging Technology
Zhao Shilong, Li Weijun, Shi Chengjiang
Abstract1021)      PDF (5658KB)(265)      
A method for detecting the integrity of aluminum foil seals with high detection accuracy and high detection efficiency is proposed.First of all,in order to obtain the infrared image of the sealing part aluminum foil,the method has adopted the infrared imaging technology.Then,the infrared image is preprocessed and the feature is extracted by circular symmetric Gabor wavelet.Lastly,KNN is used to identify and classify the acquired imaging.Experiments show that the circular symmetric Gabor wavelet used by this sealing detection method has higher recognition rate and faster algorithm than the traditional Gabor transform algorithm, and provides technical assurance for the automatic screening and rejection of defective sealing products in the subsequent aluminum foil sealing production line.
2018, 38 (02): 80-84. DOI: 10.3969/j.issn.1672-6952.2018.02.016
Progress in Research of the Synthesis Methods of Nanometer Ceria
LiuYujuan,XuJi,TongYufei,et al
Abstract1008)      PDF (1032KB)(567)      
Cerium oxide is a kind of rare earth oxides of extensive uses. It has a wide range of applications in ultraviolet absorption, luminescent materials, catalysts and so on. Nano cerium oxide has special properties and can be widely used in various fields. This paper combined the research of preparation of cerium oxide based on domestic and international literature including hydrothermal, precipitation, solgel, microemulsion, microwave and so on, and summarized the advantages and disadvantages of various preparation methods.
2017, 37 (5): 8-12. DOI: 10.3969/j.issn.1672-6952.2017.05.002
Research Progress of Raman Spectroscopy in Exploring Structural and Physical Properties of Two Dimensional Atomic Crystals
Guo Huaihong,Zhao Bo
Abstract983)      PDF (7706KB)(356)      
Two-dimensional atomic crystals (2DAC) have potential application prospects in nanoelectronic devices and optoelectronic devices,and have attracted widespread attention in recent years. Raman spectroscopy has long been recognized as a unique "fingerprint spectroscopy" of material structure. It has many important characteristics,such as fast,accurate,no damage to samples,no sample pretreatment,and greatly reduced research costs. With the successful preparation of a large number of new types of 2DAC,Raman spectroscopy will play an essential role in the establishment of the corresponding fingerprint spectrum and the exploration of exotic physical properties. This paper summarizes the research progress of Raman spectroscopy in detecting the structural characterization of two-dimensional atomic crystals,such as stacking mode,layer number,and anisotropic defects of lattice orientation. At the same time,the resonant Raman spectroscopy is also introduced to reveal the interaction between electrons and photons,electrons and phonons in twodimensional atomic crystals,and even in the acquisition of lattice vibration phonon structures. It is hoped to provide readers with a new perspective to understand the indispensable position of Raman spectroscopy in the basic research and functional application of nanomaterials.
2018, 38 (06): 1-09. DOI: 10.3969/j.issn.1672-6952.2018.06.001
Experimental Study on Melting Treatment of Fly Ash of MSW
Zhang Chu,Wang Shuang
Abstract960)   HTML    PDF (875KB)(182)      
Melting characteristics of MSW incineration fly ash was analyzed by high temperature tubular furnace in the paper, including the material migration of fly ash at high temperature and the leaching analysis of molten glass. The results show that with the increase of reaction temperature, the molten slag produced by fly ash melting decreases relative to the original fly ash, and the volatile matter of fly ash increases at high temperature. The density of the melt vitreum is 5 times more than the stacking density of fly ash, which has good volume reduction effect. The content of chloride ion in fly ash slag became less, most chlorine elements volatilized into gas phase and secondary fly ash. The influence of the Cl- entering gas on the corrosion caused by the melting system will be a process problem to be solved in the future.
2019, 39 (6): 31-35. DOI: 10.3969/j.issn.1672-6952.2019.06.006
Research Progress of Porous Solid Materials for CO 2 Adsorption and Removal
Siqi Tong, Weiwei Jian, Qiuyan Hai, Weixin Xie, Yi Sun
Abstract960)   HTML    PDF (672KB)(661)      

As the greenhouse effect becomes gradually significant, CO2 capture and storage (CCS) has turned into a potential emission reduction measure, and the adsorption method of CO2 capture is one of the most promising technologies. Porous solid adsorbents have attracted widespread attention due to their excellent CO2 adsorption performance. This review focused on the research of CO2 removal by adsorption. Five different adsorption materials were introduced, and the main factors affecting CO2 adsorption were summarized, as well as the adsorption performance of modified materials. The results show that the changes of temperature, pressure, and pore structure can affect the physical adsorption properties of the materials; reduction, oxidation, and metal ion loading modification can improve the CO2 adsorption performance by Changing the type or number of functional groups on the surface of the material.

2022, 42 (2): 30-37. DOI: 10.3969/j.issn.1672-6952.2022.02.005
 Research Stateand Prospective of Natural Gas Hydrates
Tong Le,Yang Shuang chun,Wang Lu,Wang Lili,Rong Jiguang
Abstract960)      PDF (2537KB)(635)      

        In recent years, the natural gas hydrate as a new type of high efficiency, energy saving, environmental protection energy was praised by the world's energy industry, and its potential value could not be ignored. The study of gas hydrate was integrated in different countries of the world history, the present research situation and prospect analysis. In view of the natural gas hydrate in China started to be late and a series of actual situation, a set of research strategies suitable for the current development of our country was put forward, and some problems in the process of the actual mining were introduced.

2017, 37 (2): 17-21. DOI: 10.3969/j.issn.1672-6952.2017.02.004
Research Status and Prospect of Adsorption and Diffusion
Li Xianming, Liu Shu, Wang Xiaoning
Abstract945)      PDF (1226KB)(262)      

The common research methods for the adsorption and diffusion of zeolite molecular sieves at home and abroad, the characteristics and applicable scope of each method, and the research status of adsorption and diffusion phenomena at home and abroad are introduced. The research results of domestic and foreign scientific research workers are systematically introduced. On this basis, the scientific problems that existed in this field are put forward. Aiming at these problems, a research program by using gas chromatography for the study of adsorption and diffusion phenomena is proposed. The principle of gas chromatography and the method of adsorption and diffusion are described in detail. The corresponding formulas are deduced, and the application of gas chromatography in the study of adsorption and diffusion is also prospected.

2018, 38 (02): 20-25. DOI: 10.3969/j.issn.1672-6952.2018.02.005
Research Progress of Photocatalysis of TiO2 Supported on Mineral Materials
Wang Ning, Zhao Zhentao, Ma Kunyi, Xing Jinjuan
Abstract936)   HTML    PDF (2450KB)(224)      
With the development of chemical industry, the discharge of industrial wastewater increase gradually, which has caused serious environmental pollution. Therefore, developing an efficient treatment technology to solve this problem is urgently needed. Photocatalysis is an efficient strategy to remove organic pollutants in aqueous condition. TiO2 is one of the most excellent photocatalytic material to be used in pollutant degradating, due to its higher chemical stability, photocatalytic activity and environmental friendliness. However, TiO2 particles are aggregated easily in aqueous media and difficult to be recycled, which hinders its practical applications. Dispersing TiO2 nanoparticles on the surface of mineral materials can reduce the aggregation of TiO2, increase the number of surface active sites, and improve its photocatalytic activity. This paper reviews new research progress of mineral supported TiO2 composites in photocatalytic degradation of organic pollutants.
2021, 41 (3): 1-9. DOI: 10.3969/j.issn.1672-6952.2021.03.001
Effect of Temperature on Corrosion Behavior of 316L Stainless Steel in 3.5% NaCl Solution
Lin Haibo,Zhang Juwei,Li Siyu
Abstract934)   HTML    PDF (2958KB)(216)      
The effect of temperature on corrosion behavior of 316L stainless steel (316L SS) in 3.5% NaCl solution was studied by potentiodynamic polarization and electrochemical impedance,the semiconductor properties of the passivated film were analyzed by Mott⁃Schottky curve. The surface morphology of 316L SS after corrosion was observed by metallographic microscope.The results show that in the NaCl solution with a mass fraction of 3.5%, the open circuit potential and corrosion potential of 316L SS gradually decrease with the gradual increase of temperature, and the self⁃corrosion current density increases gradually.And the pitting potential is also gradually reduced. The results of surface corrosion morphology observation showed that the number and diameter of corrosion pits on the surface of 316L SS increased as the temperature increased.This is mainly because the temperature decreased the density of the passivation film and increased the dissolution rate of the passivation film, and decreases the corrosion resistance.
2019, 39 (2): 54-58. DOI: 10.3969/j.issn.1672-6952.2019.02.010
Research on Keyword Extraction Algorithm Based on Improved TF-IDF
贾 强, 冯锡炜, 王志峰, 朱 睿, 秦 航
Abstract933)      PDF (1813KB)(261)      
In the text feature word extraction algorithm,TF-IDF algorithm is the most common feature weight calculation method. On the basis of the traditional TF-IDF extract algorithm, a new keyword extraction algorithm based on the text word length is proposed.Using chinese phrase word segmentation technique to identify long words and ordinary words in text,the proposed TF-IDF-WL method is used to recompute weights for different lengths of words, and the keywords are sorted by weights. Experimental results show that the new feature word extraction algorithm can more accurately reflect the lexical length of the feature words.Compared with the traditional TF-IDF algorithm, the algorithm has greatly improved accuracy and recall rate.
2017, 37 (4): 61-64. DOI: 10.3969/j.issn.1672-6952.2017.04.014
Heat Transfer Oil Pipeline Pressure Calculation
Wang Guowei, Wang Shengzhi, Wang Weimin
Abstract923)      PDF (1115KB)(581)      
According to the actual production, in order to guarantee asphalt tank heating of the heat transfer oil could smooth return to the heat transfer oil boiler and generally appropriated heat conduction oil pressure. For the whole pipeline pressure drop was calculated, and the friction of pipe and partial friction had carried on the detailed discussion and calculation, and the total pressure dropped along the pipeline. Through the relevant data to calculate the flow rate of heat conduction oil, the pressure centrifugal pump selection scheme of ascension was selected.
2014, 34 (5): 36-38,43. DOI: 10.3696/j.issn.1672-6952.2014.05.010
Aza-Henry Reaction Induced by Photosensitizer under the Visible Light Conditions
Li Shijie,Yan Fei,Wang Jingyun,Zhou Mingdong
Abstract881)      PDF (3250KB)(296)      
3-Methoxythioxanthone was synthesized, and the structure is identified by 1H NMR, 13C NMR, IR and HRMS spectra. The UV-Vis absorption spectra of 3-Methoxythioxanthone shows that it absorbs near the purple light (380 nm) in the visible range and is a visible light photosensitizer. 3-Methoxythioxanthone was applied to the Aza-Henry reaction of 2-phenyl-1,2,3,4-Tetrahydroisoquinoline and Nitromethane. Under the irradiation of purple LED, the photosensitizer with a molar fraction of 5% allowed the reaction to be isolated in a yield of 84% within 6 h. According to the experimental results, the mechanism of photocatalytic reaction of AzaHenry was proposed. The photosensitizer could transfer energy to produce singlet oxygen under the illumination, and singlet oxygen promoted the Aza-Henry reaction.
2018, 38 (05): 14-18. DOI: 10.3969/j.issn.1672-6952.2018.05.003
A Molecular Dynamic Simulation Investigation of RDFs of Water
Wu Fangdi, Zheng Huidong, Liu Junshao, Zheng Ximing
Abstract879)      PDF (4225KB)(521)      
Radial distribution function (RDF) of water in different conditions was studied by MD simulation with SPC/E water model. The results of RDFs between water oxygens and oxygens ( gOO( r) ) ) indicate that the nearest distance of water molecule is 0.25 nm. The first and second peaks of ( gOO( r) ) are in 0.28 nm and 0.45 nm which are the positions of first and second "water hull" respectively. The results of RDFs between water oxygens and hydrogens( gOO( r) )  indicated that the main distances of hydrogen bonds of water molecules are 0.18 nm. RDFs between water hydrogens and hydrogens( gOO( r) ) depended on the changes of hydrogen bonds of water molecules and( gOO( r) ) .
2014, 34 (3): 8-13. DOI: 10.3696/j.issn.1672-6952.2014.03.003
Research Progress in Surface and Interface Control of Silicon⁃Based Anode Materials for Lithium Ion Batteries
Zhang Li, Zhao Xuebo
Abstract871)   HTML    PDF (2512KB)(567)      
Among the anode materials, silicon is an ideal anode material for high⁃energy and high⁃power lithium ion batteries because of its exceptionally high theoretical capacity (4 200 mA·h/g) and low operation potential (~0.4 V vs Li/Li+). However, the huge volume change of silicon anode material during Li+ insertion/extraction processes causes serious structural damage and rapid capacity decay. In this paper, the lithium storage mechanism, structure evolution process, interface reaction and dynamic behavior of silicon anode material were explored. The recent progress of surface and interface modification methods, focusing on silicon electrode surface modification, electrolyte optimization and binder development, and their applications in lithium⁃ion batteries were reviewed. Challenges and perspectives about the future development of the surface and interface control of silicon anode were proposed.
2020, 40 (4): 49-58. DOI: 10.3969/j.issn.1672-6952.2020.04.008
The Application of Bionic Riblets on Drag  Reduction in Gas Transmission Pipeline
Yu Yang, Liu Dejun
Abstract862)      PDF (4258KB)(252)      
In recent years, with the increasing demand for natural gas, more and more attention was paid to the transmission efficiency of gas transmission pipeline. Because the main loss of gas pipeline was the friction resistance, therefore reducing the resistance became the focus of the study. To explore the Vshaped riblets in transmission gas pipeline of drag reduction application, FLUENT was used to simulate two different geometric size of Vshaped riblets. The pipeline drag reduction of bionic riblets could approximate switch into flat gas transmission for numerical simulation. The results of the study showed that: compared with the smooth gas transmission pipeline, Vshaped riblet gas transmission pipeline of the turbulent boundary layer of velocity profile in the logarithmic layer was different| in the same gas velocity inlet, Vshaped riblet at the top of the shear stress was greater than the bottom of the riblet, also riblet on the bottom of the near wall local turbulent kinetic energy was small| the riblet height and spacing size of both 0.90 mm Vshaped riblet pipeline had more drag reduction effect than the size of both 0.51 mm Vshaped riblet pipeline.
2017, 37 (4): 23-28. DOI: 10.3969/j.issn.1672-6952.2017.04.006
Calculation of the Equivalent Diameter in the Pipeline
WANG Jing -bo
Abstract853)      PDF (217KB)(369)      
    The paper studied the conversion of flux and flowing speed equivalent diameter' s friction resistance of unit length in rectangular pipeline , which had been adopted in design calculation of hydromechanics .Friction resistance of unit length of rectangular pipeline under the two definitions was analyzed and demonstrated theoretically .It' s concluded for rectangular pipeline in the same design condition, while searching for friction resistance of unit length of rectangular pipeline in linear diagraph by adopting flux and flowing speed equivalent diameter , obtained results are different .Thus, it' s difficult to ensure result optimization of other design scheme .
2005, 25 (3): 69-70.
Progress of Severe Slugging in Marine Riser System
Yan Rongju, Wang Weiqiang, Li Zimeng,et al
Abstract846)      PDF (1031KB)(316)      
With the development of marine petroleum industry, marine risers appeared a variety of forms. Due to pipe shapes and the complex seabed terrain factors, severe slugging often happened. This special flow pattern damaged the equipment, production and so on. Therefore, the simulation and the research for the severe slug flow of the marine riser system had very important significance. The research was summarized by the domestic and foreign scholars on the severe slug flow of the multiphase flow riser system, including its research methods, mechanism and characteristic parameters and theoretical model, etc,which provided a reference for further study of severe slug flow in riser system.
2017, 37 (5): 26-30. DOI: 10.3969/j.issn.1672-6952.2017.05.006
Calculation Method for Water Influx of Edge Water Gas Reservoir with Oil Ring
Xia Jing,Zheng Lingyun
Abstract833)      PDF (2027KB)(346)      
It is great important to accurately predict the water influx rate and cumulative water encroachment for the adjustment of oil and gas field development technology countermeasures. Combined with the principle of seepage flow mechanics, the mathematical model for calculating the water and water influx is established for a gas reservoir with an oil ring with an oil band. The model takes into account the changes of water invasion velocity caused by the variation of the seepage resistance in the oil zone. Through the argumentation and calculation, the rapid and practical algorithm is obtained. The example of the mathematical model for practical calculation established shows that the algorithm has comparatively high serviceability.
2017, 37 (3): 30-34. DOI: 10.3969/j.issn.1672-6952.2017.03.007
A Forecasting Model  of Natural Gas Long-Term Load Based on SVM-GA
Dong Mingliang,Liu Peisheng,Pan Zhen,Wen Jiangbo,Li Bingfan
Abstract832)      PDF (2990KB)(318)      

      Long-term natural gas load forecasting can solve the problem of the imbalance between supply and demand of city gas and provide assistance for the city gas company's management and running. In order to improve the accuracy of predicting the longterm natural gas loada forecasting model of natural gas longterm load was built based on SVM-GA(Support Vector MachinesGenetic Algorithm). The relevant factors influencing natural gas consumption was analyzed and determined. In order to improve prediction accuracy the penalty factor c and the kernel parameter g of support vector machines were optimized using genetic algorithm and cross validation methods. Optimized parameters were inputted support vector machines model and long-term natural gas load forecasting was made. In a case study from a certain citya comparative analysis was made of the forecasting results among SVM-GASVM and crossvalidation method combined prediction model and BP(Back Propagation) neural networks. The forecasting model based on SVM-GA was validated with a high prediction accuracy and the resulted relative mean square errornormalization mean square errornormalization absolute square errornormalization rootmean square error maximum absolute error resulted from the SVM-GA were lower than those from SVM and crossvalidation method combined prediction model or BP neural networks by 0.58%3.98%2.99%4.58%8.64% and 6.13%26.28%19.71%21.09%31.48%. Thereforethe support vector machine and genetic algorithm combined model can accurately predict the long-term natural gas load.

2017, 37 (2): 31-36. DOI: 10.3969/j.issn.1672-6952.2017.02.007
Abstract828)      PDF (2706KB)(361)      
2016, 36 (1): 27-30. DOI: 10.3696/j.issn.1672-6952.2016.01.006
Simulation of Dune Vegetationunder Natural Conditions Based on Fractal and Graphics
Liu Yun,Zhang Yan
Abstract819)      PDF (9405KB)(246)      
        Under the natural conditions,the shape of sand dunes is varied and the natural conditions of the sand dunes are very poor, and the vegetation on which they live depends is often on different states. The computer graphics and fractal geometry were used to simulate the growth of dune and vegetation. Through the function iteration system,it can achieve a single tree and forest of the morphological simulation,and also simulation the trees in the dune growth by bolding the branches. The color of trees is divided by the method of tracing the affine transformation points to achieve the color of trees changing with the season. Using computer graphics to draw flowers and the random function to replace some of the points on the trees for flowers,little flower of trees was simulated. Using the combination of different phases of the sine curve the dune is drawn and then the dune vegetation scene is simulated by combining with the trees. The external factors are used to simulate the natural shape of the dune windward slope under natural conditions. Finally,by increasing the density of dune and the number of trees to expand the area of trees the local forest scene simulation is generated.
2017, 37 (3): 58-63. DOI: 10.3969/j.issn.1672-6952.2017.03.013
Power Grid Fault Forecast Based on Model Prediction Method
Xue Hanlei,Liu Xiaoqin
Abstract817)      PDF (2263KB)(416)      

      Power grid is diagnosed after a failure to prevent the fault occurred by inferring the information that the fault generated.The method of model prediction (MP) and abductive reasoning network(ARN) is proposed to forecast the power system fault. MP predicted the troublefree operation data of the power grid by using historical data, and compared with the actual grid runtime data, the difference was calculated and used as the input of fault diagnosis system. ARN was used to bulid the fault diagnosis system and solve the complicated relationships between data processing and the corresponding candidate fault section. The fault location can be found before protection device and circuit breaker by combining the method of MP and ARN. The test results showed that the model prediction method can quickly and accurately diagnose the fault compared with BP neural network method.

2017, 37 (2): 60-65. DOI: 10.3969/j.issn.1672-6952.2017.02.013
Research Progress on Influencing Factors of Dust Removal Efficiency of Electrostatic Precipitator
Jian Wang, Jingshang Yu, Junfeng Mi, Shengnan Du
Abstract813)   HTML    PDF (973KB)(412)      

The dust removal characteristics and working mechanism of the current four major types of dust collectors were reviewed. It mainly focused on electrostatic precipitator technology, introduced its research status at home and abroad in recent years, analyzed the influence of many different factors (equipment structure parameters, gas characteristics, dust properties) on the efficiency of electrostatic precipitator equipment, and summarized electrostatic precipitator. The current technical shortcomings of the collector: The selection of the discharge electrode, the optimization of the best parameters, the anti?corrosion and cleaning of the dust collecting plate. In the future, the following issues should be focued on: development of discharge electrode materials suitable for new forms of electrostatic precipitators, discharge characteristics and dust removal efficiency in complex atmospheres, reduced insulation performance at the dust collector, and corrosion protection.

2021, 41 (6): 36-41. DOI: 10.3969/j.issn.1672-6952.2021.06.007
Dual Space of Space l→ pq
FU Ying,FAN Chuan -qiang,WANG Jing -xin
Abstract812)      PDF (213KB)(240)      
        Double sequence space is a kind of important Banach sequence space , but the expression of this kind of spaces' continuous linear functional is not completely clear .l→pq is a sort of double sequence space , in which the expression of continuous linear functional was talked about w hen 0 < p , q ≤1 .Firstly , {eij}∞i , j =1 being Schander basis of space l → pq was proved .Based on the result , the expression of continuous linear functional of the space l → pq was also studied .The dual space of double sequence space l→ pq being (l→pq)* =l → ∞∞ was proved
2005, 25 (2): 89-91.
The Rapid Testing Method of Methanol in Gasoline
WANG Jiushen, LV Huanming, DUAN Weiyu, HAN Xinbo, YU Zhong, TAN Qiuyan, LIU Huimei
Abstract812)      PDF (1638KB)(362)      
This research affords a new method to test the content of methanol in the gasoline, and a special portable instrument was developed according to this method. The disturbance caused by the existence of hydrocarbons and ethers in gasoline was excluded by extraction, and the alcohol was selective oxidized to aldehyde over catalyst A, and the presence of other alcohol can be neglected by selecting suitable color developing agent. The methanol content in 10 different kinds of gasoline samples (including samples of five Ethanol gasolines and of five unleaded gasoline) has been tested by this special instrument. According to the experimental data with GC and this method, the testing speed, selectivity and reliability of the method has been investigated, and the results shows that good reproducibility and accuracy of this method has been demonstrated as compared with those of other rapid test methods.
2013, 33 (3): 8-11.
Experimented Study on the Influence Factors of Spontaneous Imbibition in Ultra Low Permeability Fractured Reservoir
Liu Changli,Liu Xin,Zhang Lina,Chen Zhenlong
Abstract806)      PDF (2099KB)(262)      
        Water flooding development has become the only way for the ultra low permeability fractured reservoir development. However, due to the problems of reservoir micro fracture development, serious heterogeneity and critical water, resulting the water flooding recovery was low.Spontaneous imbibition oil production is an important way of oil production in this kind of reservoir, on the basis of the use of indoor experiment, the salinity of injected water, core permeability, oil saturation, surfactant, oil viscosity and temperature in a low permeability fractured reservoir were studied systematically. Experimental results show that when the environment formation water salinity is less than the mainland core layer water salinity, or joining a surface active agent could significantly improve spontaneous imbibition effect. as the permeability and oil saturation increased and the crude oil viscosity decreased; capillary imbibition became stronger and the ultimate imbibition recovery is greater; the increase of temperature can increase the initial imbibition rate, but the ultimate imbibition recovery is basically the same, the temperature is not the direct acting factors about imbibition effects in ultra low permeability fractured reservoir.
2017, 37 (3): 35-38. DOI: 10.3969/j.issn.1672-6952.2017.03.008
A Review of Fabric Defect Detection Methods Based on Computer Vision
Jiyang Han, Jiangtao Cao, Henan Wang, Xiaofei Ji
Abstract806)   HTML    PDF (696KB)(666)      

For a long time, fabric defect detection has been completed by quality inspectors. Meanwhile, the process of defect discrimination is greatly affected by subjective factors and has the problems of low detection efficiency and high cost. With the close combination of computer vision technology and various fields, fabric defect detection system based on vision has gradually become an important solution to replace manual quality inspection. For the fabric defect detection based on vision, this paper reviews the aspects including industry development, general detection standards, overall structure of the system and key technologies in detection algorithms, introduces the existing fabric defect detection products based on vision in the market, analyzes the common defect detection standards and the basic structure of the detection system, and summarizes and compares the research status of image processing and deep learning technology in the field of fabric defect detection in recent years. Finally, the paper summarizes the key problems to be solved, and discusses the possible development direction in the future.

2022, 42 (1): 70-77. DOI: 10.3969/j.issn.1672-6952.2022.01.013