Abstract: Intermetal diffusion phenomenon will happen when metal matrix Pdcomposite membranes are under high temperature for a long time, which will influence the service life of the Pdcomposite membrane. By electroless plating, the palladium membrane on the surface of the porous metal supporter with different materials was prepared. And the Pdcomposite membranewas then heat treatment under high temperature in inert gas. Backscattered Electron Microscopy (BSE) and Energy Dispersive Spectrometer (EDS) crosssectional line scans were used to analysis the elements distribution of various Pdcomposite membranes, and the diffusion level of the metal matrix Pdcomposite membrane was studied by comparing it with the ceramic composite membrane. The results showed that there was no diffusion phenomenon happening to Pd/titanium (Ti) composite membranes and Pd/titaniumaluminum (TiAl) alloy composite membranes in the temperature range of 500 to 700 ℃, while serious intermetal diffusion phenomenon happened when Pd/porousstainlesssteel (PSS) composite membrane was under high temperature heat treatment (700 ℃) for 40

Key words: Intermetallic diffusion,    ,  Pd composite membrane,    ,  Ceramic,    ,  TiAl alloy,   , Porous stainless steel

摘要： 金属基钯复合膜长期处于高温下会发生金属间相扩散问题, 严重影响复合膜的使用寿命。运用化学 镀的方法, 在不同材料的多孔金属支撑体表面制备钯膜, 然后对钯复合膜进行惰性气体保护下的高温热处理。运用 背散射和能谱线扫描的方法分析、 表征所制备的各种钯复合膜的元素分布状况, 并且将金属基钯复合膜与P d /陶瓷 复合膜相对比, 研究前者的相扩散程度。结果表明, 在测试的温度范围内( 5 0 0~7 0 0℃) , 没有发现P d / T i复合膜、 P d / T i - A l合金复合膜发生相扩散现象, P d / P S S( 多孔不锈钢) 复合膜经历7 0 0℃、 4 0h的高温热处理后发生了严重 的金属间相扩散现象。

关键词: 相扩散, 钯复合膜, 陶瓷, T i - A l合金, 多孔不锈钢