基于可视化分析辅助探究钠离子电池硬碳负极研究进展

doi:10.3969/j.issn.1006-396X.2022.06.001

摘要/Abstract

摘要：

钠离子电池因成本低、安全性高等优势，已经成为当前储能领域的研究热点。为了明确钠离子电池硬碳负极的发展历程，解决钠离子电池初始库伦效率低、稳定性差以及高倍率性能差等问题，探索了硬碳中钠离子储存机制；运用CiteSpace可视化分析了钠离子电池的发展沿程，从材料设计、结构调控、功能设计及界面优化3个方面综述了硬碳负极的性能优化策略研究进展，并对现存硬碳储钠机制进行了总结与探讨。最后，对钠离子电池硬碳负极的发展方向进行了展望。

关键词: 钠离子电池, 硬碳, 性能优化, 首圈库伦效率, 可视化分析

Abstract:

Sodium?ion batteries have become one of the research hotspots in the field of energy storage because of their advantages of low cost and high safety. This paper tried to clarify the development history of the hard carbon anode of sodium?ion batteries and address the current disadvantages of sodium?ion batteries, such as low initial coulombic efficiency, poor stability, and insufficient high magnification performance. In addition, to explore the sodium?ion storage mechanism in hard carbon, this paper used CiteSpace to visually analyze the development process of sodium?ion batteries and reviewed the research progress of performance optimization strategies for hard carbon anode in terms of material design, structure regulation, and function design and interface optimization. Furthermore, the paper summarized and discussed the existing hard carbon sodium storage mechanisms and finally prospected the development direction of the hard carbon anode of sodium?ion batteries.

Key words: Sodium?ion batteries, Hard carbon, Performance optimization, Initial coulombic efficiency, Visualization analysis

中图分类号:

TQ150

张博, 郄佳鑫, 曹永安, 赵久成, 吴军, 王文举. 基于可视化分析辅助探究钠离子电池硬碳负极研究进展[J]. 石油化工高等学校学报, 2022, 35(6): 1-9.

Bo Zhang, Jiaxin Qie, Yongan Cao, Jiucheng Zhao, Jun Wu, Wenju Wang. Research Progress of Hard Carbon Anode of Sodium⁃Ion Batteries Based on Visualization Analysis[J]. Journal of Petrochemical Universities, 2022, 35(6): 1-9.

图/表 8

图1 2000-2021年文献数量分布

Fig.1 The distribution chart of the number of documents over time from 2000 to 2021

图2 3个阶段钠离子硬碳材料的国家/地区合作关系图

Fig.2 The map of cooperation among countries/regions in three stages of hard carbon in sodium?ion battery

图3 关键词突现图

Fig.3 Keywords with the strongest citation bursts

图4 静电纺丝法制备碳纳米纤维示意图

Fig. 4 Schematic illustration for preparation of carbon nanofibers film by electrospinning

图5 无珠串/有珠串碳纳米纤维SEM及直径分布

Fig.5 SEM images and diameter distributions of carbon nanofibers without beads?on?string and carbon nanofibers with beads?on?string

图6 碳纳米片、氮硫共掺杂碳纳米颗粒和氮掺杂碳材料的TEM图像及相应的层间距

Fig.6 The TEM images of carbon nano sheets, nitrogen and sulfur co doped carbon nanoparticles and nitrogen doped carbon materials and their corresponding interlayer distances

图7 卵黄结构Sb@C摘要图

Fig.7 Graphical abstract of yolk?shell structure Sb@C

图8 硬碳中钠离子储存机制示意图

Fig.8 Schematic illustration of the mechanisms for Na?ion storage in hard carbon

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