硅基固体胺吸附剂捕集空气中CO2的研究进展

doi:10.3969/j.issn.1006-396X.2022.04.001

石油化工高等学校学报 ›› 2022, Vol. 35 ›› Issue (4): 1-9.DOI: 10.3969/j.issn.1006-396X.2022.04.001

硅基固体胺吸附剂捕集空气中CO₂的研究进展

荣振洋¹^,²(), 祁路明¹^,², 刘清¹^,²(), 费兆阳¹^,²(), 崔咪芬¹^,², 乔旭¹^,²^,³

^1.南京工业大学化工学院，江苏南京 210009
^2.南京工业大学材料化学工程国家重点实验室，江苏南京 210009
^3.江苏省先进材料协同创新中心，江苏南京 210009

收稿日期:2022-06-14 修回日期:2022-08-22 出版日期:2022-08-25 发布日期:2022-09-27
通讯作者: 刘清,费兆阳
作者简介:荣振洋（1998⁃），男，硕士研究生，从事CO2捕集方面的研究；E⁃mail：202161204271@njtech.edu.cn。
基金资助:
国家自然科学青年基金项目(21606130);国家重点研发计划项目(2019YFC1905804);江苏省重点研发计划项目(BE2019735)

Research Progress in Silicon⁃Based Solid Amine Adsorbents for CO₂ Capture

Zhenyang Rong¹^,²(), Luming Qi¹^,², Qing Liu¹^,²(), Zhaoyang Fei¹^,²(), Mifen Cui¹^,², Xu Qiao¹^,²^,³

^1.College of Chemical Engineering，Nanjing Tech University，Nanjing Jiangsu 210009，China
^2.State Key Laboratory of Materials?Oriented Chemical Engineering，Nanjing Tech University，Nanjing Jiangsu 210009，China
^3.Jiangsu National Synergetic Innovation Center for Advanced Materials，Nanjing Tech University，Nanjing Jiangsu 210009

Received:2022-06-14 Revised:2022-08-22 Published:2022-08-25 Online:2022-09-27
Contact: Qing Liu, Zhaoyang Fei

摘要/Abstract

摘要：

人类活动导致的CO₂过量排放，是造成全球气候变暖的主要原因，因此亟需一种能够有效控制CO₂浓度增长的方法。直接空气捕获技术是目前唯一能够大规模实现碳排放负增长的技术。固体胺吸附剂，特别是硅载体固体胺吸附剂，因其具有高吸附能力、抗腐蚀、低能耗等优点，被广泛研究并用于环境空气中捕获CO₂。将硅基固体胺吸附剂按照负载方式进行分类，并归纳了不同硅基载体对吸附剂性能的影响；提出粉末状固体胺吸附剂在工业应用中遇到的难题，整理并分析了固体胺吸附剂当前的成型方法；指出了开发高吸附量、高稳定性的成型固体胺吸附剂是CO₂吸附剂工业化的未来趋势。

关键词: CO₂捕集, 吸附剂, 载体, 有机胺, 成型

Abstract:

Excessive CO₂ emission caused by a large number of human activities is the main cause of global warming,so a method to effectively control the increase in CO₂ concentration is urgently needed.Currently,direct air capture is the only technology capable of achieving negative growth of carbon emissions on a large scale.Solid amine adsorbents,especially silicon?based ones, have been widely studied and used to capture CO₂ from ambient air due to their advantages of high adsorption capacity,corrosion resistance,and low energy consumption.In this paper,silicon?based solid amine adsorbents were classified according to the mode of loading,and the influence of different silicon?based supports on the adsorbent performance was summarized.At the same time,the problems encountered in the industrial application of powdered solid amine adsorbents were put forward,and the current forming methods of solid amine adsorbents were sorted out.Finally,it is pointed out that the development of formed solid amine adsorbents with high adsorption capacity and high stability is the future trend of CO₂ adsorbent industrialization.

Key words: CO₂ capture, Adsorbents, Support, Organic amine, Pelletization

中图分类号:

TQ116.3

荣振洋, 祁路明, 刘清, 费兆阳, 崔咪芬, 乔旭. 硅基固体胺吸附剂捕集空气中CO₂的研究进展[J]. 石油化工高等学校学报, 2022, 35(4): 1-9.

Zhenyang Rong, Luming Qi, Qing Liu, Zhaoyang Fei, Mifen Cui, Xu Qiao. Research Progress in Silicon⁃Based Solid Amine Adsorbents for CO₂ Capture[J]. Journal of Petrochemical Universities, 2022, 35(4): 1-9.

图/表 6

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吸附剂	载体	胺	吸附剂类型	吸附容量/(mmol·g^-1)	循环稳定性	参考文献
SBA⁃PPG⁃50	SBA⁃15	PPG	Ⅰ类	0.62	4次循环后，容量下降56.25%	[15]
SBA⁃PEI⁃48	SBA⁃15	PEI⁃1800	Ⅰ类	1.09	4个循环后，容量下降16.00%	[15]
PGA/SBA⁃15	SBA⁃15	PGA	Ⅰ类	0.30	20次循环后，容量几乎不变	[16]
60% Ph⁃3⁃ED/SBA⁃15	SBA⁃15	Ph⁃3⁃ED	Ⅰ类	0.92	25次循环后，容量几乎不变	[17]
S/T4/D1	SBA⁃15	DEA＆TEPA	Ⅰ类	1.93	10次循环后，容量下降2.50%	[18]
SBA⁃15/PEI/PEG200⁃low	SBA⁃15	PEI⁃800	Ⅰ类	0.73	-	[19]
PEI⁃34.4/Al5⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.29	-	[20]
PEI⁃31.8/Ti4.3⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.64	4次循环后，容量下降5.00%	[20]
PEI⁃32.7/Ce0.4⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.68	-	[20]
PEI⁃34.7/Zr7⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.84	3次循环后，容量几乎不变	[21]
PEI/PME(40)	MCM⁃41	PEI⁃800	Ⅰ类	2.18	20次循环后，容量下降4.60%	[23]
PEI⁃MCF⁃46	MCF	PEI⁃800	Ⅰ类	1.74	-	[26]
PAA⁃MCF⁃41	MCF	PAA	Ⅰ类	0.86	3次循环后，容量几乎不变	[26]
PEI⁃MCF⁃80a	MCF	PEI	Ⅰ类	1.29	-	[27]
FS⁃PEI(800)⁃50	FS	PEI⁃800	Ⅰ类	2.43	-	[29]
HMS⁃10a⁃PEI (50)	HMS	PEI⁃800	Ⅰ类	1.79	4次循环后，容量几乎不变	[31]
MMSN⁃30/TEPA⁃50	MMSN	TEPA	Ⅰ类	3.68	6次循环后，容量几乎不变	[32]
TRI⁃PE⁃MCM⁃41	MCM⁃41	TRI⁃Silane	Ⅱ类	0.98	-	[34]
L⁃丙基⁃SBA⁃1.72	SBA⁃15	AEAPTMS	Ⅱ类	0.56	4次循环后，容量下降5.00%	[35]
TRI⁃SBA⁃15⁃130⁃0.4	SBA⁃15	TRI	Ⅱ类	1.51	12次循环后，容量几乎不变	[36]
SI⁃AEATPMS	硅胶	AEATPMS	Ⅱ类	0.21	40次循环后，容量几乎不变	[39]
W⁃AG⁃150A	硅胶	TRI⁃Silane	Ⅱ类	0.77	17次循环后，容量几乎不变	[40]
WG⁃HBS⁃0.6	HBS	TPD	Ⅱ类	1.04	10次循环后，容量几乎不变	[41]
AHTSA10	硅胶	APTES	Ⅲ类	1.64	15次循环后，容量几乎不变	[43]
MPS⁃LA⁃120	MPS	LA⁃120	Ⅲ类	2.65	-	[44]

吸附剂	载体	胺	吸附剂类型	吸附容量/(mmol·g^-1)	循环稳定性	参考文献
SBA⁃PPG⁃50	SBA⁃15	PPG	Ⅰ类	0.62	4次循环后，容量下降56.25%	[15]
SBA⁃PEI⁃48	SBA⁃15	PEI⁃1800	Ⅰ类	1.09	4个循环后，容量下降16.00%	[15]
PGA/SBA⁃15	SBA⁃15	PGA	Ⅰ类	0.30	20次循环后，容量几乎不变	[16]
60% Ph⁃3⁃ED/SBA⁃15	SBA⁃15	Ph⁃3⁃ED	Ⅰ类	0.92	25次循环后，容量几乎不变	[17]
S/T4/D1	SBA⁃15	DEA＆TEPA	Ⅰ类	1.93	10次循环后，容量下降2.50%	[18]
SBA⁃15/PEI/PEG200⁃low	SBA⁃15	PEI⁃800	Ⅰ类	0.73	-	[19]
PEI⁃34.4/Al5⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.29	-	[20]
PEI⁃31.8/Ti4.3⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.64	4次循环后，容量下降5.00%	[20]
PEI⁃32.7/Ce0.4⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.68	-	[20]
PEI⁃34.7/Zr7⁃SBA⁃15	SBA⁃15	PEI⁃800	Ⅰ类	0.84	3次循环后，容量几乎不变	[21]
PEI/PME(40)	MCM⁃41	PEI⁃800	Ⅰ类	2.18	20次循环后，容量下降4.60%	[23]
PEI⁃MCF⁃46	MCF	PEI⁃800	Ⅰ类	1.74	-	[26]
PAA⁃MCF⁃41	MCF	PAA	Ⅰ类	0.86	3次循环后，容量几乎不变	[26]
PEI⁃MCF⁃80a	MCF	PEI	Ⅰ类	1.29	-	[27]
FS⁃PEI(800)⁃50	FS	PEI⁃800	Ⅰ类	2.43	-	[29]
HMS⁃10a⁃PEI (50)	HMS	PEI⁃800	Ⅰ类	1.79	4次循环后，容量几乎不变	[31]
MMSN⁃30/TEPA⁃50	MMSN	TEPA	Ⅰ类	3.68	6次循环后，容量几乎不变	[32]
TRI⁃PE⁃MCM⁃41	MCM⁃41	TRI⁃Silane	Ⅱ类	0.98	-	[34]
L⁃丙基⁃SBA⁃1.72	SBA⁃15	AEAPTMS	Ⅱ类	0.56	4次循环后，容量下降5.00%	[35]
TRI⁃SBA⁃15⁃130⁃0.4	SBA⁃15	TRI	Ⅱ类	1.51	12次循环后，容量几乎不变	[36]
SI⁃AEATPMS	硅胶	AEATPMS	Ⅱ类	0.21	40次循环后，容量几乎不变	[39]
W⁃AG⁃150A	硅胶	TRI⁃Silane	Ⅱ类	0.77	17次循环后，容量几乎不变	[40]
WG⁃HBS⁃0.6	HBS	TPD	Ⅱ类	1.04	10次循环后，容量几乎不变	[41]
AHTSA10	硅胶	APTES	Ⅲ类	1.64	15次循环后，容量几乎不变	[43]
MPS⁃LA⁃120	MPS	LA⁃120	Ⅲ类	2.65	-	[44]

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硅基固体胺吸附剂捕集空气中CO₂的研究进展

Research Progress in Silicon⁃Based Solid Amine Adsorbents for CO₂ Capture

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