改性分子筛吸附脱硫

石油化工高等学校学报 ›› 2007, Vol. 20 ›› Issue (1): 48-51.

改性分子筛吸附脱硫

徐林刚, 李永红

天津大学绿色合成与转化教育部重点实验室,天津300072

收稿日期:2007-07-15 出版日期:2007-03-20 发布日期:2017-06-28
作者简介:徐林刚(1982-),男,山东平邑县,在读硕士。

Adsorptive Desulfurization by Modified Zeolites

XU Lin-gang, LI Yong-hong

Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin University, Tianjin 300072,P.R.China

Received:2007-07-15 Published:2007-03-20 Online:2017-06-28

摘要/Abstract

摘要： 以ZSM-5、Y型、MCM-41分子筛为载体,采用离子交换法制备了一系列用于汽油脱硫的负载金属离子的改性分子筛吸附剂。对不同的吸附剂作了X-射线衍射和比表面积分析,考察了静态吸附条件对其脱硫性能的影响。结果表明,不同吸附剂对噻吩的吸附效果不同,CuY的效果较为明显,并得出适宜的吸附条件:常温,常压,剂油质量比为0.15。通过对再生前后吸附剂CuY的变化分析,对吸附脱硫的机理进行了探讨。

Abstract: A series of adsorbents involving modified ZSM-5,Y,MCM-41 molecular sieves were prepared by ion-exchanging method for gasoline desulfurization. The composition and specific surface area of the adsorbents were determined by XRD technique. The effect of adsorption conditions on the desulfurization performance of the adsorbents was studied. The results show that the desulfurization performance varies for different adsorbents, CuY performs the best and the optimum adsorption conditions is ambient temperature , atmospheric pressure and mass ratio of adsorbent to oil ratio of 0.15. By analyzing the varations of the adsorbent CuY through regeneration process, the mechanism of adsorptive desulfurization was investigated.

徐林刚, 李永红. 改性分子筛吸附脱硫[J]. 石油化工高等学校学报, 2007, 20(1): 48-51.

XU Lin-gang, LI Yong-hong. Adsorptive Desulfurization by Modified Zeolites[J]. Journal of Petrochemical Universities, 2007, 20(1): 48-51.