石油化工高等学校学报

石油化工高等学校学报 ›› 2016, Vol. 29 ›› Issue (4): 13-17.DOI: 10.3969/j.issn.1006-396X.2016.04.003

• 石油化工 • 上一篇    下一篇

聚酯增塑剂增塑PVC最新研究进展

张欣华,李泽天,王 静,韩释剑,高传慧   

  1. (青岛科技大学化工学院,山东青岛266042)
  • 收稿日期:2016-05-27 修回日期:2016-07-07 出版日期:2016-08-25 发布日期:2016-08-24
  • 通讯作者: 高传慧(1980-),女,博士,副教授,从事新型高分子材料及绿色化工研究;E-mail:chuanhuigao@126.com。
  • 作者简介:张欣华(1991-),男,硕士研究生,从事新型功能材料设计与合成研究;E-mail:17864201236@163.com。
  • 基金资助:
    国家自然科学青年基金项目(51308314);青岛市应用基础研究计划项目(15-9-1-101-jch)。

The Newest Research Progresses of Polyester Plasticizer for PVC

Zhang Xinhua, Li Zetian, Wang Jing, Han Shijian, Gao Chuanhui   

  1. (College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao Shandong 266042,China)
  • Received:2016-05-27 Revised:2016-07-07 Published:2016-08-25 Online:2016-08-24

摘要: PVC增塑剂以邻苯二甲酸酯类增塑剂为主,因其较高的增塑效率被广泛使用,但此类增塑剂耐久性差,使产品的使用寿命变短,具有毒性和潜在致癌性,影响人类及动物健康,已逐渐被新型增塑剂所取代。聚酯增塑剂是一种绿色环保型增塑剂,可以较好地解决传统增塑剂的缺点,所以被国内外广泛地研究,本文概述了聚酯增塑剂的增塑机理(凝胶理论、润滑理论和自由体积理论)、合成过程和选用准则,并对聚酯增塑剂进行分类,包括生物基聚酯增塑剂、石油基聚酯增塑剂。

关键词: PVC, 增塑剂, 增塑机理, 选用准则, 聚酯增塑剂

Abstract: Polyvinyl chloride (PVC) is generally used for phthalate plasticizers, because of its high plasticizing efficiency. These phthalate plasticizers will cause the problems of durability, toxicity and potential carcinogenicity, they can make service life shorter, endanger human and animal health. So it has been gradually replaced by the new type of plasticizer. Polyester plasticizer is a kind of green environmental protection plasticizer and can better solve the disadvantage of traditional plasticizer, so it was widely studied at home and abroad. In this article, plasticizing mechanism(Lubricity theory, Gel theory, Free volume theory), selection criteria, synthesis and classification of the polyester plasticizer are introduced. The polyester plasticizer is mainly divided into two categories:biological polyester plasticizer and petroleum polyester plasticizer.

Key words: PVC, Plasticizers, Plasticizing mechanism, Selection criteria, Polyester plasticizer

引用本文

张欣华,李泽天,王 静,韩释剑,高传慧. 聚酯增塑剂增塑PVC最新研究进展[J]. 石油化工高等学校学报, 2016, 29(4): 13-17.

Zhang Xinhua, Li Zetian, Wang Jing, Han Shijian, Gao Chuanhui . The Newest Research Progresses of Polyester Plasticizer for PVC[J]. Journal of Petrochemical Universities, 2016, 29(4): 13-17.

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