SAPO-5分子筛固载铜双核金属配合物的结构及催化性能

doi:10.3696/j.issn.1006-396X.2009.03.014

石油化工高等学校学报 ›› 2009, Vol. 22 ›› Issue (3): 55-59.DOI: 10.3696/j.issn.1006-396X.2009.03.014

SAPO-5分子筛固载铜双核金属配合物的结构及催化性能

高丽娟,焦帅斌,葛春花,田永华

宁夏大学化学化工学院，宁夏银川750021

收稿日期:2008-10-02 修回日期:2009-05-18 出版日期:2009-09-25 发布日期:2009-09-25
作者简介:高丽娟(1968 -), 女, 山西太原市, 副教授, 博士
基金资助:
教育部科学技术研究重点资助项目(203143)

Structure and Catalytic Properties of Dinuclear Copper Complex Encapsulated in SAPO－５

College of Chemistry and Chemical Engineering，Ningxia University, Yinchuan Ningxia 750021,P.R.China

Received:2008-10-02 Revised:2009-05-18 Published:2009-09-25 Online:2009-09-25

摘要/Abstract

摘要： 合成了一种铜双核大环金属配合物。采用浸渍法将双核配合物固载在分子筛SAPO-5中制得负载催化材料，其中磷酸铝分子筛SAPO-5采用三甲氧基氨丙基硅烷将表面官能化。BET，IR，UV-Vis，XRD，ICP-AES和TG/DTA表征结果表明配合物被固载后，其结构仍保持完整。以环己烷氧化为探征反应，考察了负载催化材料的催化性能。结果表明该负载催化剂具有较高的活性，当选用乙腈做溶剂时，环己烷的转化率高达55 .1%。该负载催化剂在环己烷液相反应中的最佳反应条件为：反应时间在10～12 h，反应温度在80～90℃。

关键词: 双核配合物 , SAPO－５ , 催化氧化反应 , 固载

Abstract:

The dinuclear copper complexe was synthesized and characterized. The macrocyclic copper complexe was immobilized on SAPO-5 molecular sieve, functionalized SAPO-5 molecular sieve by γ-aminopropyl. The sample was characterized by BET, IR and UV-vis spectroscopies, XRD, ICP-AES and TG/DTA techniques,and its structure still remained intact. The catalytic properties of the prepared catalyst were studied by the cyclohexane oxidation with H2O2 as an oxidant. The catalytic results show that the catalyst has the better activity and stability in cyclohexane oxidation. Amongst all the solvents ,cyclohexane conversion is the highest (55.1%) when acetonitrile was used as solvent. The influences of time and temperature on cyclohexane conversion are also further investigated. The considerable reactive condition should be reaction time (10～12 h), reaction temperature (80～90 ℃) respectively.

Key words: Dinuclear complex , SAPO－５ , Oxidation reaction , Encapsulation

高丽娟,焦帅斌,葛春花,田永华. SAPO-5分子筛固载铜双核金属配合物的结构及催化性能[J]. 石油化工高等学校学报, 2009, 22(3): 55-59.

GAO Li-juan,JIAO Shuai-bin,GE Chun-hua,TIAN Yong-hua. Structure and Catalytic Properties of Dinuclear Copper Complex Encapsulated in SAPO－５[J]. Journal of Petrochemical Universities, 2009, 22(3): 55-59.

[1]	秦玉才,段林海,潘明雪,张晓彤,连丕勇,王红,宋丽娟. 复合分子筛Y/SAPO-5的合成与表征[J]. 石油化工高等学校学报, 2011, 24(3): 5-7.
[2]	高丽娟, 李瑞丰. MCM-4 1固载异双核金属配合物的合成表征及催化性能[J]. 石油化工高等学校学报, 2007, 20(1): 42-47.

SAPO-5分子筛固载铜双核金属配合物的结构及催化性能

Structure and Catalytic Properties of Dinuclear Copper Complex Encapsulated in SAPO－５

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