The Study of Synthesis and Electrochemical  Properties of Calix\[4\]arene Tert Sulfonic Acid

doi:10.3696/j.issn.1672-6952.2014.03.001

Journal of Liaoning Petrochemical University ›› 2014, Vol. 34 ›› Issue (3): 1-4.DOI: 10.3696/j.issn.1672-6952.2014.03.001

The Study of Synthesis and Electrochemical  Properties of Calix $4$ arene Tert Sulfonic Acid

Liu Limei1, Zhang Dailiang1, Song Lipeng2， Chen Ping1

（1.School of Chemistry and Materials Science, Liaoning Shihua University, Fushun Liaoning 113001, China； 2. Petrochina Fushun Petrochemical Company Ethylene Chemical Plant，Fushun Liaoning 113000，China）

Received:2013-11-25 Revised:2014-03-08 Published:2014-06-25 Online:2017-07-14

杯[ 4] 芳烃四磺酸的合成及电化学行为

刘丽梅¹,张岱良¹,宋立鹏²,陈平¹

( 1. 辽宁石油化工大学化学与材料科学学院,辽宁抚顺1 1 3 0 0 1; 2. 中国石油抚顺石化分公司乙烯化工厂, 辽宁抚顺1 1 3 0 0 0)

通讯作者: 陈平( 1 9 6 3 - ) , 女, 硕士, 教授, 从事有机绿色催化研究; E - m a i l : c h e n p i n g - f s @s o h u. c o m。
作者简介:刘丽梅( 1 9 8 8 - ) , 女, 硕士研究生, 从事杯芳烃衍生物合成及性能的研究; E - m a i l : l i u l i m e i 1 9 8 8@1 2 6. c o m。
基金资助:
教育部科学技术研究重点项目( 2 0 9 0 3 1)

Abstract

Abstract: 5,11,17,23tetrasulphonated25,26,27,28tetrahydroxycalix $4$ arene was synthesized from calix $4$ arene and concentrated sulfuric acid as raw materials, and characterized with a UVvisible spectrophotometer, thermal gravimetric (TG) and differential thermal analysis (DTA)；finally its electrochemical behavior was studied in the potassium dihydrogen phosphatesodium hydrogen phosphate buffer solution, and the results show that there is an irreversible reduction peak at about 0.93 V in the scan potential between -1.2 ~ 0.8 V, and the reduction peak potential changed with scanning speed.

Key words: Calix $4$ arene tert sulfonic acid, Synthesis, Glassy carbon electrode, Cyclic voltammetry, Electrochemical behavior

摘要： 以杯[ 4] 芳烃和浓硫酸为原料, 合成了杯[ 4] 芳烃四磺酸, 即5, 1 1, 1 7, 2 3 - 四磺酸基 - 2 5, 2 6, 2 7, 2 8 - 四羟
基杯[ 4] 芳烃, 对其进行紫外可见和热重与差热分析( TG - DTA) , 同时以KH2P O4 - N a 2HP O4 为缓冲溶液, 研究5, 1 1,
1 7, 2 3 - 四磺酸基 - 2 5, 2 6, 2 7, 2 8 - 四羟基杯[ 4] 芳烃电化学行为。实验结果表明, 当扫描电位在-1. 2~0. 8V时, 有一不
可逆的还原峰, 还原峰电位在0. 9 3V左右, 且还原峰电位因扫描速度的改变而改变。

关键词: 杯[ 4] 芳烃四横酸 , 合成 , 玻碳电极 , 循球伏安法 , 电化学行为

Liu Limei, Zhang Dailiang, Song Lipeng， Chen Ping. The Study of Synthesis and Electrochemical  Properties of Calix $4$ arene Tert Sulfonic Acid[J]. Journal of Liaoning Petrochemical University, 2014, 34(3): 1-4.

刘丽梅,张岱良,宋立鹏,陈平. 杯[ 4] 芳烃四磺酸的合成及电化学行为[J]. 辽宁石油化工大学学报, 2014, 34(3): 1-4.

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The Study of Synthesis and Electrochemical  Properties of Calix $4$ arene Tert Sulfonic Acid

杯[ 4] 芳烃四磺酸的合成及电化学行为

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The Study of Synthesis and Electrochemical  Properties of Calix4arene Tert Sulfonic Acid

杯[ 4] 芳烃四磺酸的合成及电化学行为

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The Study of Synthesis and Electrochemical  Properties of Calix $4$ arene Tert Sulfonic Acid