Heat Effect Analysis of Paraffin Wax Catalytic Oxidation

Journal of Liaoning Petrochemical University ›› 2006, Vol. 26 ›› Issue (2): 31-33.

Previous Articles Next Articles

Heat Effect Analysis of Paraffin Wax Catalytic Oxidation

School of Petrochemical Technology , Liaoning University of Petroleum & Chemical Technology ,Fushun Liaoning 113001, P .R .China

Received:2005-10-21 Published:2006-02-25 Online:2006-02-25

石蜡催化氧化反应热效应分析

康　蕾, 廖克俭^＊ , 丛玉凤

辽宁石油化工大学石油化工学院, 辽宁抚顺113001

作者简介:康蕾(1981 -), 女(蒙古族), 辽宁朝阳市, 在读硕士。

Abstract

Abstract:

　 Paraffin wax was mix ed with microcry stalline paraffin wax by the mass ratio o f 4∶1.The total mass is 100 g .The catalyst and cocatalyst were added.The oxidation reaction w as taken place at the certain reaction temperature, air flow , and reaction time.The analysis of the heat -effect indicates that the maximum energy of forming the free radical and the activation energy are greatly affected by the air flow and the reaction temperature .When the air flow is 4 L/min, the temperature is 170 ℃, the maximum energy of forming the free radical and the activation energy are lower , the reaction is easy to occur .The forming of free radical is greatly affected by the mass of the catalyst and cocatalyst .When the catalyst mass is 0 .016 g and the cocatalyst mass is 1 .6 g , the free radical is easy to be formed.The optimal reaction time is 6 h .

Key words: 　Paraffin wax , 　Oxidation, 　Heat effect

摘要： 　将石蜡与微晶蜡按质量比为4∶1 进行混合共100 g , 添加催化剂、助剂, 在反应温度、空气流量、反应时间一定的条件下进行氧化反应。反应热效应的分析表明, 空气流量和反应温度对反应过程中生成自由基所需的最高能量以及活化能的影响较大。空气流量在4 L/ min, 温度在170 ℃时, 反应过程中生成自由基所需的最高能量较小, 活化能较小, 反应容易进行。添加的催化剂和助剂质量对自由基生成的难易程度影响较大, 催化剂质量为0 .016g , 助剂质量为1.6 g 时, 较易生成自由基。反应时间为6 h 较好。

关键词: 　石蜡, 　氧化, 　热效应

KANG Lei,LIAO Ke -jian,et al. Heat Effect Analysis of Paraffin Wax Catalytic Oxidation[J]. Journal of Liaoning Petrochemical University, 2006, 26(2): 31-33.

康　蕾, 廖克俭,丛玉凤. 石蜡催化氧化反应热效应分析[J]. 辽宁石油化工大学学报, 2006, 26(2): 31-33.

[1]	Wei GAO, Xin ZENG, Jinxiao LI, Chunhua YANG, Yaqi WANG, Sumin LI, Shuang LÜ, Liwei PAN. Preparation of Pt/γ⁃Al₂O₃ by Rotary Microemulsion Method for Catalytic Oxidation of Methanol [J]. Journal of Liaoning Petrochemical University, 2023, 43(6): 44-47.
[2]	Dongbei YU, Xue LI, Xinyu YANG, Caishun ZHANG, Jiao HAN, Honghao WANG, Lei ZHANG, Zhixian GAO. The Effect of Precipitators on the Texture Properties and CO Catalytic Oxidation Performance of CuO/CeO₂ Catalysts [J]. Journal of Liaoning Petrochemical University, 2023, 43(6): 48-53.
[3]	Jianwei Song, Jing Zhang, Kaiwen Tan, Liwei Pan, Hexiang Zhong. Research Progress of Non⁃Homogeneous Ozone Oxidation Catalysts in Water Treatment [J]. Journal of Liaoning Petrochemical University, 2022, 42(3): 8-13.
[4]	Sun Lijuan, Cao Zubin, Han Dongyun, Wang Rong, Gao Yi . Removal of Sulfur Compounds in Residue by Peracetic Acid Oxidation⁃Extraction [J]. Journal of Liaoning Petrochemical University, 2021, 41(3): 10-14.
[5]	Hao Guodong， Su Shuangyue， Hao Chunli， Liu Binxia. Research Status on High Temperature Oxidation of Micro⁃Arc Oxidation of Titanium Alloy [J]. Journal of Liaoning Petrochemical University, 2021, 41(2): 21-26.
[6]	Zhao Peng， Liu Zhibo， Yu Fang. The Synthesis of 1⁃Hydroxytryptamine Derivatives [J]. Journal of Liaoning Petrochemical University, 2021, 41(1): 18-22.
[7]	Huang Huiyang, Cao Zubin, Han Dongyun, Liang Feixue, Zhu Tao, Zhu Yao. Desulfurization of Petroleum Coke by Chemical Oxidation [J]. Journal of Liaoning Petrochemical University, 2020, 40(3): 14-17.
[8]	Zhou Shixin， Zhang Jing， Qiao Haiyan， Han Dongyun， Cao Zubin， Shi Weiwei. Oxidation⁃Extraction Desulfurization of Visbreaking Diesel Fuel [J]. Journal of Liaoning Petrochemical University, 2020, 40(2): 6-10.
[9]	Wang Erze，Wang Xin，Chen Ping. Progress in Synthesis of Anthraquinone [J]. Journal of Liaoning Petrochemical University, 2019, 39(2): 15-20.
[10]	Chen Kexian，Yin Lu，Xie Haiying. Structure Activity Relationship of Nitrogenous Six Membered Heterocyclic Nitroxide Radical Organocatalysts [J]. Journal of Liaoning Petrochemical University, 2017, 37(6): 1-5.
[11]	. Removal of Sulfides from Simulated Oil by CH₃CONH₂/ZnCl₂ Deep Eutectic Solvent [J]. Journal of Liaoning Petrochemical University, 2017, 37(5): 1-7.
[12]	Liu Jia,Wang Xin,Xie Ruixia,Guan Yang,Chen Ping. Catalytic Performance of a New Type Mononuclear Cobalt Schiff Base Complex for Water Oxidation [J]. Journal of Liaoning Petrochemical University, 2017, 37(3): 11-14.
[13]	Xu Feng, Wu Yang, Zhu Lihua. Syntheisi of Methanol through Partial Oxidation of Low-Concentration Coal Mine Gas in Liquid Phase Catalyzed by Pt(bipy)Cl₂ [J]. Journal of Liaoning Petrochemical University, 2016, 36(6): 1-4.
[14]	Sun Zhenbo, Cao Zubin, Han Dongyun, Zhao Rongxiang. Exploratory Study on Ultrasonic Oxidation Desulfurization of Catalytic Cracking Diesel Oil [J]. Journal of Liaoning Petrochemical University, 2016, 36(5): 10-13.
[15]	Gong Yuning，Han Bing，Wang Zhongyuan，Li Xiaoman，Zhou Guangxing, Li Junfeng. Quantitative Analysis Based on Laboratory Test of Heavy Oil Injection Air Oxidation State [J]. Journal of Liaoning Petrochemical University, 2016, 36(1): 12-15.

Heat Effect Analysis of Paraffin Wax Catalytic Oxidation

石蜡催化氧化反应热效应分析

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics