正常与脱落头发中铜和锌的分析———微波消解-火焰原子吸收光谱法

辽宁石油化工大学学报 ›› 2006, Vol. 26 ›› Issue (2): 8-11.

正常与脱落头发中铜和锌的分析———微波消解-火焰原子吸收光谱法

张金生, 喻育红, 李丽华^＊ , 李秀萍

辽宁石油化工大学石油化工学院, 辽宁抚顺113001

收稿日期:2005-12-29 出版日期:2006-02-25 发布日期:2006-02-25
作者简介:张金生(1968 -), 男, 辽宁沈阳市, 博士, 教授。

Analysis of Copper and Zinc in Regular Hair and Dropped Hair : Microw ave Digestion -Flame Atomic Absorption Spect rometry

School of Petrochemical Technology , Liaoning University of Petrochemical Technology ,
Fushun Liaoning 113001, P .R .China

Received:2005-12-29 Published:2006-02-25 Online:2006-02-25

摘要/Abstract

摘要： 　采用微波消解系统消解头发样品, 将头发样品置于密闭容器内, 加入一定量的硝酸和双氧水, 放在微波炉内进行消解。用火焰原子吸收光谱法测定正常头发和脱落头发中Cu 和Zn 的质量分数, 得出30～ 40 岁中年男子正常发样Cu 和Zn 的质量分数分别为7 .78, 146.87 μg/ g , 脱落发样Cu 和Zn 的质量分数分别为6 .88, 138.67 μg/g ;30～ 40 岁中年妇女正常发样Cu 和Zn 的质量分数分别为8.14 , 159 .63 μg/g , 脱落发样Cu 和Zn 的质量分数分别为7 .92 , 155 .20 μg/g ;30 岁以下哺乳期女子正常发样中Cu 和Zn 的质量分数分别为7.33 , 143.66 μg/ g , 脱落发样中Cu 和Zn 的质量分数分别为6 .23 , 129 .39 μg/g 。结果表明, 对于同一个人来说, 脱落头发中Cu 和Zn 的质量分数明显低于正常头发。

关键词: 微波消解, 　正常头发, 　脱落头发, 　火焰原子吸收光谱法, 　铜, 　锌

Abstract:

　 Hair samples were digested in a microwave digestion system .Nitric acid and hydrogen peroxide solution were added to the sample in a closed digestion vessel and then digested in a microwave oven .The mass fraction of Cu and Zn in regular and dropped hair were detected by flame atomic absorption spectrometry .The results show that the mass fraction of Cu and Zn in regular hair of men whose age is 30 ～ 40 are 7 .78, 146 .87μg/ g and in dropped hair are 6 .88, 138.67μg/ g respectively .The mass fraction of Cu and Zn in regular hair of women whose age is 30 ～ 40 are 8 .14, 159.63μg/ g and in dropped hair are 7.92 , 155.20μg/g respectively .The mass fraction of Cu and Zn in regular hair of suckling women who are less than 30 are 7.33 , 143 .66μg/g and in dropped hair 6 .23 , 129.39μg/g respectively .The results also show that the mass fraction of Cu and Zn in dropped hair are obviously lower than those of Cu and Zn in regular hair of the same person.

Key words: 　Microwave digestion , 　Regular hair , 　Dropped hair , 　Flame atomic absorption spectrometry , 　Copper , 　Zinc

张金生, 喻育红, 李丽华,李秀萍. 正常与脱落头发中铜和锌的分析———微波消解-火焰原子吸收光谱法[J]. 辽宁石油化工大学学报, 2006, 26(2): 8-11.

ZHANG Jin -sheng,YU Yu -hong,LI Li -hua,et al. Analysis of Copper and Zinc in Regular Hair and Dropped Hair : Microw ave Digestion -Flame Atomic Absorption Spect rometry[J]. Journal of Liaoning Petrochemical University, 2006, 26(2): 8-11.

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