辽宁石油化工大学学报

辽宁石油化工大学学报 ›› 2010, Vol. 30 ›› Issue (2): 11-14.DOI: 10.3696/j.issn.1672-6952.2010.02.004

• 石油化工 • 上一篇    下一篇

铜单质价电子结构参数统计值的计算

李 飞,赵 侠   

  1. 辽宁石油化工大学职业技术学院,辽宁抚顺113001
  • 收稿日期:2009-09-15 出版日期:2010-06-25 发布日期:2017-07-05
  • 作者简介:李飞(1979-),男,辽宁沈阳市,讲师,硕士

Calculation of Statistical Values of Valence Electron Structure Parameters of Cu Simple Substance

 

LI Fei, ZHAO Xia
  

  1. College of Vocational Technology, Liaoning Shihua University, Fushun Liaoning 113001, P.R.China
  • Received:2009-09-15 Published:2010-06-25 Online:2017-07-05

摘要: 基于固体与分子经验电子理论,对Cu单质的价电子结构进行了分析,计算了价电子结构参数统计值
n'A、E'A,给出了价电子结构参数统计值的计算方法,将统计值n'A、E'A 与最可几值nA、EA 进行了对比。计算结果
表明,Cu原子处于甲种杂化第1~12杂阶时所处的状态为其实际中可能存在的;Cu的统计值n'A、E'A 与相应的最
可几值nA、EA 的计算偏差分别为5.72%和6.86%,可以用n'A、E'A 代替nA、EA 来讨论铜的宏观性能。

关键词: 铜单质 ,  ,  , 价电子结构 ,  , 统计值 ,  , 计算

Abstract:  

Based on the empirical electron theory of solids and molecules, the valence electron structure and statistical values of valence electron structure parameters of Cu simple substance (n′A, E′A ) were analyzed and calculated. The calculation method of statistical values of valence electron structure parameters was given, and the statistical values n′A, E′A were compared with the most probable value nA and EA. The calculation results show that a type hybridization of Cu atoms are on the first to twelfth hybrid level which the status of their practice that may exist. The calculation deviation of the statistical values n′A, E′A and the corresponding most probable value nA, EA are 5.72% and 6.86%, respectively. These results show that nA and EA can be replaced by n′A and E′A for discussing the macro properties of Cu.

Key words: Cu simple substance  ,  , Valence electron structure ,  , Statistical value ,  ,  Calculation

引用本文

李 飞,赵 侠. 铜单质价电子结构参数统计值的计算[J]. 辽宁石油化工大学学报, 2010, 30(2): 11-14.

LI Fei, ZHAO Xia. Calculation of Statistical Values of Valence Electron Structure Parameters of Cu Simple Substance[J]. Journal of Liaoning Petrochemical University, 2010, 30(2): 11-14.

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链接本文: https://journal.lnpu.edu.cn/CN/10.3696/j.issn.1672-6952.2010.02.004

               https://journal.lnpu.edu.cn/CN/Y2010/V30/I2/11