层状双氢氧化物在防腐领域应用的研究进展

doi:10.12422/j.issn.1006-396X.2023.03.007

摘要/Abstract

摘要：

层状双氢氧化物（LDHs）简单的合成工艺、可灵活设计的结构、经济性、环保性和阴离子交换性强化了它在防腐涂料领域的应用范围。可以通过一种或多种工艺相结合实现LDHs的目标性能，也可以通过表面修饰和内部阴离子置换进行化学改性，增强LDHs的可应用性，满足不同领域的应用需求。主要聚焦了LDHs的合成方法、防腐蚀机理、防腐蚀的实际应用以及局限性和展望，分析归纳了各种合成方法的优点和不足，并对未来LDHs在防腐领域的应用研究提出了一些建议。

关键词: 层状双氢氧化物, 纳米填料, 防腐蚀, 阴离子置换, 共沉淀

Abstract:

Layered double hydroxides (LDHs) has simple synthesis process,flexible structure,economy,environmental protection and anion exchange,which strengthen its application range in the field of anti?corrosion coatings.The target properties of LDHs can be achieved by a combination of one or more processes,or chemically modified by surface modification and internal anion replacement,enhancing the applicability of LDHs to meet the needs of different fields of application.This paper mainly focuses on the synthesis method of LDHs,the mechanism of corrosion protection,the practical application of LDHs corrosion protection,and its limitations and prospects.It analyzes the advantages and disadvantages of various synthesis methods,and provides suggestions for future research on the application of LDHs in the field of corrosion protection.

Key words: Layered double hydroxide, Nanofillers, Anti?corrosion, Anion substitution, Coprecipitation

中图分类号:

TQ63

郭洪山, 杨康博, 姜浩然, 杨程程, 王传兴. 层状双氢氧化物在防腐领域应用的研究进展[J]. 石油化工高等学校学报, 2023, 36(3): 44-51.

Hongshan Guo, Kangbo Yang, Haoran Jiang, Chengcheng Yang, Chuanxing Wang. Research Progress of Layered Double Hydroxide in the Field of Anticorrosion[J]. Journal of Petrochemical Universities, 2023, 36(3): 44-51.

图/表 4

图1 LDHs的结构示意图

Fig.1 Structure diagram of LDHs

图2 微胶囊的耐腐蚀机理及应用领域

Fig.2 Corrosion resistance mechanism and application fields of microcapsules

图3 MgAl?SDS?LDHs膜的腐蚀防护机理示意图

Fig.3 Schematic diagram of corrosion protection mechanism of MgAl?SDS?LDHs membrane

图4 Cu?BTA?MgAl?MoO42-?LDHs智能防腐涂料的合成路线

Fig.4 Synthetic route of Cu?BTA?MgAl?MoO42-?LDHs intelligent anticorrosive coatings

参考文献 53

1	刘术辉，刘斌，徐大伟，等.层状双金属氢氧化物防腐蚀涂层材料的研究进展［J］.中国腐蚀与防护学报，2022，42（1）：16⁃24.
	Liu S H，Liu B，Xu D W，et al.Research progress on anti⁃corrosion coatings of layered double hydroxides［J］.Journal of Chinese Society for Corrosion and Protection，2022，42（1）：16⁃24
2	Chubar N G，Gilmour R F，Gerda V E，et al.Layered double hydroxides as the next generation inorganic anion exchangers：Synthetic methods versus applicability［J］.Advances in Colloid and Interface Science，2017，245（7）：62⁃80.
3	Goh K H，Lim T T，Dong Z.Application of layered double hydroxides for removal of oxyanions：A review［J］.Water Research，2008，42（6⁃7）：1343⁃1368.
4	黄任枢，姚金环，梁晓丽，等.均相沉淀法制备Ni/Al⁃LDHs/rGO复合电极材料的电化学性能［J］.辽宁石油化工大学学报，2020，40（4）：80⁃86.
	Huang R S，Yao J H，Liang X L，et al.Electrochemical performances of Ni/Al⁃LDHs/rGO composites prepared by homogeneous precipitation method［J］.Journal of Liaoning Petrochemical University，2020，40（4）：80⁃86.
5	许雪容，彭祥.层状双金属氢氧化物电催化剂的合成与应用研究进展［J］.石油化工高等学校学报，2022，35（5）：1⁃11.
	Xu X R，Peng X.Research progress in preparation and application of layered double hydroxides electrocatalysts［J］.Journal of Petrochemical Universities，2022，35（5）：1⁃11.
6	秦旻，王亚茹，赵毅.层状双金属氢氧化物阻燃高分子材料的制备及研究进展［J］.化工新型材料，2022，50（10）：5⁃9.
	Qin M，Wang Y R，Zhao Y.Research advance on LDHs flame⁃retardant polymer material［J］.New Chemical Materials，2022，50（10）：5⁃9.
7	Zhang X L，Guo L，Huang H L，et al.Removal of phosphorus by the core⁃shell bio⁃ceramic/Zn⁃layered double hydroxides （LDHs） composites for municipal wastewater treatment in constructed rapid infiltration system［J］.Water Research，2016，96（11）：280⁃291.
8	Zhang Z X，Li P L，Zhang X，et al.Recent advances in layered⁃double⁃hydroxides based noble metal nanoparticles efficient electrocatalysts［J］.Nanomaterials，2021，11（10）：2644.
9	Wen J，Lv Y H，Xu Y Q，et al.Construction of a biodegradable，versatile nanocarrier for optional combination cancer therapy［J］.Acta Biomaterialia，2019，83（1）：359⁃371.
10	Li Z S，Xiao K C，Yu C L，et al.Three⁃dimensional graphene⁃like carbon nanosheets coupled with MnCo⁃layered double hydroxides nanoflowers as efficient bifunctional oxygen electrocatalyst［J］.International Journal of Hydrogen Energy，2021，46（69）：34239⁃34251.
11	Xu W Z，Zhang B L，Xu B L，et al.The flame retardancy and smoke suppression effect of heptaheptamolybdate modified reduced graphene oxide/layered double hydroxide hybrids on polyurethane elastomer［J］.Composites Part A：Applied Science and Manufacturing，2016，91（12）：30⁃40.
12	Wang J，Li Y S，Chen W Y，et al.The rapid coagulation of graphene oxide on La⁃doped layered double hydroxides［J］.Chemical Engineering Journal，2017，309（3）：445⁃453.
13	李战国，纪文军，李悦，等.层状双金属氢氧化物在水泥混凝土中的应用研究进展［J］.混凝土，2021，375（1）：25⁃30.
	Li Z G，Ji W J，Li Y，et al.Research progress on application of layered double hydroxides in cement concrete［J］.Concrete，2021，375（1）：25⁃30.
14	Liu B Y，Zhang M，Wang Y C，et al.Facile synthesis of defect⁃rich ultrathin NiCo⁃LDHs，NiMn⁃LDHs and NiCoMn⁃LDHs nanosheets on Ni foam for enhanced oxygen evolution reaction performance［J］.Journal of Alloys and Compounds，2021，852（3）：156949
15	Tao X M，Liu D L，Cong W W，et al.Controllable synthesis of starch⁃modified ZnMgAl⁃LDHs for adsorption property improvement［J］.Applied Surface Science，2018，457（31）：572⁃579.
16	Bukhtiyarova M V.A review on effect of synthesis conditions on the formation of layered double hydroxides［J］.Journal of Solid State Chemistry，2019，269（1）：494⁃506.
17	杨正芳，张悦，蔡金霄，等.层状双金属氢氧化物及其复合材料的制备与应用研究新进展［J］.材料导报，2021，35（19）：19062⁃19069.
	Yang Z F，Zhang Y，Cai J X，et al.Recent advances in the preparation and application of layered double hydroxides and their composites［J］.Materials Reports，2021，35（19）：19062⁃19069.
18	方洪波.采油污水中保留聚合物对污水配制聚合物溶液黏度的影响［J］.油田化学，2021，38（1）：173⁃178.
	Fang H B.Effect of retained polymer in oil produced wastewater on the viscosity of polymer solution prepared by wastewater［J］.Oilfield Chemistry，2021，38（1）：173⁃178..
19	Tang Y，Wu F，Fang L，et al.A comparative study and optimization of corrosion resistance of ZnAl layered double hydroxides films intercalated with different anions on AZ31 Mg alloys［J］.Surface and Coatings Technology，2019，358（2）：594⁃603.
20	Nestroinaia O V，Ryltsova I G，Lebedeva O E.Effect of synthesis method on properties of layered double hydroxides containing Ni（Ⅲ）［J］.Crystals，2021，11（11）：1429⁃1441.
21	Iqbal A，Sun L Y，Barrett A T，et al.Layered double hydroxide protective films developed on aluminum and aluminum alloys：Synthetic methods and anti⁃corrosion mechanisms［J］.Coatings，2020，10（4）：428⁃451.
22	Wang N，Gao H Y，Zhang J，et al.Anticorrosive waterborne epoxy （EP） coatings based on sodium tripolyphosphate⁃pillared layered double hydroxides （STPP⁃LDHs）［J］.Progress in Organic Coatings，2019，135（10）：74⁃81.
23	Zhang M，Li C，Wang X，et al.Ultrahigh anti⁃corrosion performance of polymer⁃based coating filled with a novel micro network nanofiller［J］.Corrosion Science，2021，190（13）：109685.
24	Wang X G，Zhu J L，Lei Y X，et al.Synthesis and characterization of layered double hydroxides hybrid microcapsules for anticorrosion via self⁃healing and chloride ion adsorption［J］.Applied Clay Science，2022，221（6）：106481.
25	Li X X，Liu C，Shi T，et al.Preparation of multifunctional Al alloys substrates based on micro/nanostructures and surface modification［J］.Materials & Design，2017，122（10）：21⁃30.
26	Zheng S L，Li C，Fu Q T，et al.Fabrication of self⁃cleaning superhydrophobic surface on aluminum alloys with excellent corrosion resistance［J］.Surface and Coatings Technology，2015，276（16）：341⁃348.
27	Wang P，Zhang D，Qiu R，et al.Super⁃hydrophobic film prepared on zinc as corrosion barrier［J］.Corrosion Science，2011，53（6）：2080⁃2086.
28	Wang F Y，Guo Z G.Insitu growth of durable superhydrophobic Mg⁃Al layered double hydroxides nanoplatelets on aluminum alloys for corrosion resistance［J］.Journal of Alloys and Compounds，2018，767（37）：382⁃391.
29	Eili M I，Shameli K F，Ibrahim N A，et al.The effect of the divalent metal on the intercalation capacity of stearate anions into layered double hydroxide nanolayers［J］.Journal of Industrial and Engineering Chemistry，2015，22（2）：63⁃69.
30	Song Y L，Wang H Y，Liu Q，et al.Sodium dodecyl sulfate （SDS） intercalated MgAl layered double hydroxides film to enhance the corrosion resistance of AZ31 magnesium alloy［J］.Surface and Coatings Technology，2021，422（18）：127524.
31	Wang Y B，Yuan Z Y，Zhang Z K，et al.In situ one⁃step fabrication of superhydrophobic layered double hydroxide on Al alloys for anti⁃corrosion［J］.Applied Surface Science，2022，593（23）：153400.
32	Zhu K，Zhang J W，Zhang H，et al.Fabrication of durable superhydrophobic coatings based on a novel branched fluorinated epoxy［J］.Chemical Engineering Journal，2018，351（21）：569⁃578.
33	David R F，Raja V S，Singh S K，et al.Development of anti⁃corrosive paint with improved toughness using carboxyl terminated modified epoxy resin［J］.Progress in Organic Coatings，2018，120（7）：58⁃70.
34	Gonçalves F F，Santos M E，Cernadas T F，et al.Influence of fillers on epoxy resins properties：A review［J］.Journal of Materials Science，2022，57（32）：15183⁃15212.
35	Gao X，Yan R，Lv Y J，et al.In situ pretreatment and self⁃healing smart anti⁃corrosion coating prepared through eco⁃friendly water⁃base epoxy resin combined with non⁃toxic chelating agents decorated biomass porous carbon［J］.Journal of Cleaner Production，2020，266（25）：121920.
36	Ding J H，Zhao H G，Shao Z Z，et al.Bioinspired smart anticorrosive coatings with an emergency⁃response closing function［J］.ACS Applied Materials & Interfaces，2019，11（45）：42646⁃42653.
37	Cui G，Bi Z X，Wang S H，et al.A comprehensive review on smart anti⁃corrosive coatings［J］.Progress in Organic Coatings，2020，148（11）：105821.
38	Jagtap A F，Wagle P G，Jagtiani E D，et al.Layered double hydroxides （LDHs） for coating applications［J］.Journal of Coatings Technology and Research，2022，19（4）：1009⁃1032.
39	Li D D，Wang F Y，Yu X，et al.Anticorrosion organic coating with layered double hydroxide loaded with corrosion inhibitor of tungstate［J］.Progress in Organic Coatings，2011，71（3）：302⁃309.
40	Dong Y H，Wang F，Zhou Q.Protective behaviors of 2⁃mercaptobenzothiazole intercalated Zn–Al⁃layered double hydroxide coating［J］.Journal of Coatings Technology and Research，2014，11（5）：793⁃803.
41	Xie P，He Y，Zhong F，et al.Cu⁃BTA complexes coated layered double hydroxide for controlled release of corrosion inhibitors in dual self⁃healing waterborne epoxy coatings［J］.Progress in Organic Coatings，2021，153（4）：106164.
42	Chen B，Zhang Z，Kim S G，et al.Ostwald ripening driven exfoliation to ultrathin layered double hydroxides nanosheets for enhanced oxygen evolution reaction［J］.ACS Applied Materials & Interfaces，2018，10（51）：44518⁃44526.
43	Guo X X，Xu S L，Zhao L L，et al.One⁃step hydrothermal crystallization of a layered double hydroxide/alumina bilayer film on aluminum and its corrosion resistance properties［J］.Langmuir，2009，25（17）：9894⁃9897.
44	Liu A，Tian H W，Li W H，et al.Delamination and self⁃assembly of layered double hydroxides for enhanced loading capacity and corrosion protection performance［J］.Applied Surface Science，2018，462（31）：175⁃186.
45	Lee H G，Dellatore S E，Miller W G，et al.Mussel⁃inspired surface chemistry for multifunctional coatings［J］.Science，2007， 318（5849）：426⁃430.
46	Zhang M，Xu F，Lin D，et al.A smart anti⁃corrosion coating based on triple functional fillers［J］.Chemical Engineering Journal，2022，446（20）：137078.
47	韩宇莹，刘梓良，王文学，等.石墨烯在有机防腐涂层领域的应用研究进展［J］.表面技术，2021，50（1）：196⁃207.
	Han Y Y，Liu Z L，Wang W X，et al.Application and development progress of graphene in the field of organic anticorrosive coatings［J］.Surface Technology，2021，50（1）：196⁃207.
48	Nguyen T D，Nguyen A S，Tran B A，et al.Molybdate intercalated hydrotalcite/graphene oxide composite as corrosion inhibitor for carbon steel［J］.Surface and Coatings Technology，2020，399（19）：126165.
49	Li H J，He Y，Luo P Y，et al.Construction and anti⁃corrosion behavior study of silanol⁃modified Ni⁃WS2 superhydrophobic composite coating［J］.Surface and Coatings Technology，2022，450（22）：129008.
50	Pourhashem S G，Vaezi M H，Rashidi A H，et al.Distinctive roles of silane coupling agents on the corrosion inhibition performance of graphene oxide in epoxy coatings［J］.Progress in Organic Coatings，2017，111（10）：47⁃56.
51	Zhong K，Zhang C L，Ren S W，et al.Remediation of soil in a deserted arsenic plant site using synthesised MgAlFe⁃LDHs［J］.Bulletin of Environmental Contamination and Toxicology，2021，107（1）：167⁃174.
52	Chhetri S E，Samanta P F，Murmu N C，et al.Anticorrosion properties of epoxy composite coating reinforced by molybdate⁃intercalated functionalized layered double hydroxide［J］.Journal of Composites Science，2019，3（1）：11⁃24.
53	Yang H，Xiong C G，Liu X Y，et al.Application of layered double hydroxides （LDHs） in corrosion resistance of reinforced concrete⁃state of the art［J］.Construction and Building Materials，2021，307（43）：124991.

[1]	杨蕊铭, 唐雅妮, 李婧雯, 费超, 王博. 钴铁层状双金属负载生物炭对水体硝氮的吸附研究[J]. 石油化工高等学校学报, 2024, 37(2): 16-23.
[2]	李敏, 李政, 顾贵洲, 于喜洋, 王辉. Zn⁃Mg⁃Al LDO的制备及其除氟性能研究[J]. 石油化工高等学校学报, 2023, 36(5): 73-80.
[3]	包洪洲, 张艳侠, 汤涛, 高鹏, 付秋红, 段日. 制备条件对铜铬催化剂酸性质的影响[J]. 石油化工高等学校学报, 2013, 26(6): 36-40.