石油化工高等学校学报

石油化工高等学校学报 ›› 2013, Vol. 26 ›› Issue (4): 35-41.DOI: 10.3969/j.issn.1006396X.2013.04.008

• 石油化工 • 上一篇    下一篇

新型受阻酚防老剂合成及对橡胶防护性能研究

陈忠保1,赵晓彦2,郭绍辉2   

  1. (1.中海石油炼化有限责任公司,北京100010;2.中国石油大学(北京)理学院,北京102200)
  • 收稿日期:2013-05-09 出版日期:2013-08-25 发布日期:2013-08-25
  • 作者简介:陈忠保(1953-),男,广东遂溪县,高级工程师,硕 士。

Synthesis of a Hindered Phenolic Antioxidant and Its  AntiAging Properties for Rubber Vulcanizates

  1. (1.CNOOC Oil & Petrochemicals Co., Ltd., Beijing 100010, China;  2. College of Science, China University of Petroleum, Beijing 102200, China)
  • Received:2013-05-09 Published:2013-08-25 Online:2013-08-25

PDF

摘要： 以3-(3,5-二叔丁基-4-羟基苯基)丙酸和正丁醇为原料,采用酯化反应,合成了新型受阻酚防老剂。并采用红外光谱、热重分析及荧光测试对合成的防老剂结构进行表征。结果表明,合成的防老剂是3-(3,5-二叔丁基-4-羟基苯基)丙酸正丁酯。受阻酚防老剂最佳合成实验条件是回流时间8h、催化剂质量分数3.2%、丙酸与正丁醇物质的量比为1:2。采用力学性能测试、红外光谱、热重分析等方法研究了受阻酚防老剂对NR硫化胶的防护性能,结果表明受阻酚防老剂对NR硫化胶有显著的防老化作用,其防老化效果优于防老剂BHT,且对橡胶无色泽污染性。

关键词: 橡胶,   , 受阻酚 ,  , 防老剂 ,  , 防老化 ,  , 酯化反应, 硫化胶

Abstract: The hindered phenolic antioxidant was synthesized with 3(3,5ditertbutyl4hydroxyphenyl) propionic acid and nbutyl alcohol as raw materials by esterifying reaction. The antioxidant characterized by infrared spectroscopy and HNMR was 3(3,5ditertbutyl4hydroxyphenyl) nbutyl propionate. The optimal synthesis conditions were as follows: reflux time 8 h, the molar ratio of 3(3,5ditertbutyl4hydroxyphenyl) propionic acid to nbutyl alcohol 1∶2 and the catalyst amount 3.2% on the total reacts. The effects of hindered phenolic antioxidant on the protective effect of NR vulcanizates were studied by mechanical property testing, infrared spectroscopy, thermal analysis. These results indicate that the hindered phenolic antioxidant havepronounced antiaging properties, which is higher than those of BHT antioxidant. Besides, the synthesized hindered phenolic antioxidant had no color pollution for rubber.

Key words: Rubber,    ,  Hindered phenolic antioxidant,    ,  Antioxidant,    ,  Antiaging,    ,  Esterifying reaction,    ,  Vulcanizates

引用本文

陈忠保,赵晓彦,郭绍辉. 新型受阻酚防老剂合成及对橡胶防护性能研究[J]. 石油化工高等学校学报, 2013, 26(4): 35-41.

CHEN Zhongbao,ZHAO Xiaoyan,GUO Shaohui. Synthesis of a Hindered Phenolic Antioxidant and Its  AntiAging Properties for Rubber Vulcanizates[J]. Journal of Petrochemical Universities, 2013, 26(4): 35-41.

使用本文

0
    /   /   推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal.lnpu.edu.cn/syhg/CN/10.3969/j.issn.1006396X.2013.04.008

               http://journal.lnpu.edu.cn/syhg/CN/Y2013/V26/I4/35



网站版权 © 2021《石油化工高等学校学报》编辑部

本系统由北京玛格泰克科技发展有限公司设计开发