石油化工高等学校学报

石油化工高等学校学报 ›› 2017, Vol. 30 ›› Issue (5): 1-5.DOI: 10.3969/j.issn.1006-396X.2017.05.001

• 石油化工 • 上一篇    下一篇

CH-90交换树脂对废水中Co2+ 丶Mn2+的去除

史学伟1,2,吴艳阳2,徐首红1,赵双良2   

  1. (1.华东理工大学化学与分子工程学院,上海200237;2.华东理工大学化工学院,上海200237)
  • 收稿日期:2017-01-26 修回日期:2047-04-23 出版日期:2017-10-31 发布日期:2017-11-10
  • 通讯作者: 赵双良(1979-),男,博士,副教授,从事非平衡态统计力学理论与分子传递方面研究;E-mail:szhao@ecust.edu.cn。
  • 作者简介:史学伟(1991-),男,硕士研究生,从事重金属离子螯合剂的制备与应用研究;E-mail:sxw19910620@163.com。
  • 基金资助:
    国家重点基础研究发展计划青年科学家专题项目(2014CB748500);上海市浦江人才计划项目(16PJD019)。

Removal of Co2+ and Mn2+ from Wastewater with CH-90 Exchange Resin

  1. 1.School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237,China; 
     2. School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
  • Received:2017-01-26 Revised:2047-04-23 Published:2017-10-31 Online:2017-11-10

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摘要： 研究了CH-90阳离子交换树脂对PTA模拟废水及工业废水中Co2+ 、Mn2+ 的吸附性能,考察了不同 pH、CH-90树脂的质量浓度、接触时间对树脂吸附性能的影响。结果表明,当pH=3.5、CH-90树脂的质量浓度为 2.0g/L时,CH-90树脂对模拟废水中Co2+ 、Mn2+去除率达到最佳,最大吸附量分别为55.4、50.5mg/g,其吸附过程符合准二级动力学描述。而在工业废水中,由于有机物的大量存在及pH 的影响,最合适的CH-90树脂的质量浓度为24g/L。吸附后的树脂在强酸中脱附,能够重复再生15次以上,降低树脂的使用成本。

关键词: Co2+ ,    , Mn2+ ,    ,  离子交换树脂,    ,  废水处理

Abstract: The adsorption of Co2+ and Mn2+ in both simulated and industrial PTA wastewater by CH-90 cation exchange resin was investigated. Different parameters including the pH value, contact time and dosage on the adsorption performance were conducted. The optima adsorption capacity in simulated wastewater was obtained under the condition of pH=3.5 and 2 g/L dosage, and the maximum adsorption capacities were 55.4 mg/g, 50.5 mg/g for Co (II) and Mn (II) respectively. While in industrial wastewater the optima dosage reached high up to 24 g/L likely due to the interference of concentrated COD and the unfavorable pH value. The adsorption kinetics data were analyzed which followed the pseudosecondorder kinetics model. It was shown that the CH-90 resin could be regenerated in strong acid solution and then reused for more than 15 times, which therefore greatly reduced the usecost. 

Key words: Co (II),    ,  Mn (II),    , Ion exchange resins,    ,  Wastewater

引用本文

史学伟,吴艳阳,徐首红,赵双良. CH-90交换树脂对废水中Co2+ 丶Mn2+的去除[J]. 石油化工高等学校学报, 2017, 30(5): 1-5.

Shi Xuewei,Wu Yanyang,Xu Shouhong,et al. Removal of Co2+ and Mn2+ from Wastewater with CH-90 Exchange Resin[J]. Journal of Petrochemical Universities, 2017, 30(5): 1-5.

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