辽宁石油化工大学学报

辽宁石油化工大学学报 ›› 2014, Vol. 34 ›› Issue (6): 1-4.DOI: 10.3696/j.issn.1672-6952.2014.06.001

• 石油化工 •    下一篇

淀粉改性P E T - P EG的制备、 表征及性质研究

  吴 爽1,任珈明1,王 鑫2,臧树良1   

  1.    ( 1. 辽宁石油化工大学化学化工与环境学部, 辽宁抚顺1 1 3 0 0 1;2. 中国石油化工股份有限公司抚顺石油化工研究院, 辽宁抚顺1 1 3 0 0 1)
  • 收稿日期:2014-08-27 出版日期:2014-12-25 发布日期:2017-07-14
  • 通讯作者: : 王鑫( 1 9 7 9 - ) , 男, 博士, 高级工程师, 从事生物材料研究; E - m a i l : w a n g x i n 0 2. f s h y@s i n o p e c . c o m。
  • 作者简介:吴爽( 1 9 8 0 - ) , 女, 博士研究生, 讲师, 从事高分子材料及催化材料分析研究; E - m a i l : w u s h u a n g 0 5 7 1 5@1 6 3. c o m。
  • 基金资助:
    基金项目: 国家科技支撑计划项目( 2 0 1 2 B A F 0 3 B 0 0)

Synthesis, Characterization and Properties of Starch-Modified PET-PEG

Wu Shuang1, Ren Jiaming1, Wang Xin2, Zang Shuliang1   

  1. 1.College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University， Fushun Liaoning 113001,China; 2.Sinopec Fushun Research Institute of Petroleum and  Petrochemicals, Fushun Liaoning 113001,China
  • Received:2014-08-27 Published:2014-12-25 Online:2017-07-14

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摘要：  使用淀粉改性对苯二甲酸乙二醇酯 - 聚乙二醇共聚物( P E T - P E G) , 以六亚甲基二异氰酸酯为偶联剂,
制备了一系列含淀粉的P E T - P E G共聚物( P E T - P E G / S T) , 并对其进行了结构表征和性质分析。实验结果表明, 淀
粉与P E T - P E G发生了偶联反应, 随着淀粉质量分数的增加, 共聚物的热稳定性有所降低。P E T - P E G / S T具有良好
的生物降解性, 能在淀粉酶作用下快速降解, 在不同p H条件下的降解速率由大到小的顺序为: 碱性、 酸性、 中性。

关键词: 淀粉, P E T - P E G, 改性, 生物降解, 偶合反应

Abstract: Starch was reacted with polyethylene terephthalate polyethylene glycol (PET-PEG) copolymer using hexamethylenediisocyanate as a coupling agent in order to prepare new PET-PEG/ST copolymers. The obtained PET-PEG/ST was characterized by FTIR and 1HNMR spectroscopy, thermal analysis, and the water absorption and biodegradable tests. The results show that starch was attached to PET-PEG via couple reaction in the presence of hexamethylenediisocyanate. As compared to PETPEG, PET-PEG/ST has avariable thermal stability with decreasing melting temperature. PET-PEG/ST has degraded in aqueous solution with different pH under different levels, and the degradation rate of PET-PEG/ST in aqueous solution under different pH values from big to small order as follows: alkaline solution,acidic solution,neutral solution. PET-PEG/ST also tends to degrade in biologically active environments like amylase.

Key words: Starch, PET-PEG, Modification, Biodegradation, Coupling reaction

引用本文

吴 爽,任珈明,王 鑫,臧树良. 淀粉改性P E T - P EG的制备、 表征及性质研究[J]. 辽宁石油化工大学学报, 2014, 34(6): 1-4.

Wu Shuang, Ren Jiaming, Wang Xin, Zang Shuliang. Synthesis, Characterization and Properties of Starch-Modified PET-PEG[J]. Journal of Liaoning Petrochemical University, 2014, 34(6): 1-4.

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