Abstract: Calcium carbonate has attracted much attention due to its wide range of industrial applications. It is also considered to be the main scaly component in industrial water. Controlling the crystallization process of calcium carbonate is one of the main goals of research in many fields. The presence of foreign inorganic ions changes the rate of precipitation of calcium carbonate and also affects the nature and morphology of the precipitated phase. Combining research progress in recent years, the effects of inorganic ions on the crystallization process of calcium carbonate were reviewed. The effects of common metal cations and anions on the polymorphism and morphology of calcium carbonate were introduced. The mechanism of action was also analyzed, which provided theoretical support for the industrial application of calcium carbonate.

Key words: Calcium carbonate, Inorganic ion, Crystallization process, Polymorphic, Morphology

摘要： 　CaCO3因为广泛的工业应用而备受关注，同时也被认为是工业水中主要的垢质成分，控制CaCO3的结晶进程是众多领域研究的主要目标之一。外来无机离子的存在会改变CaCO3的沉淀速率，同时也会影响沉淀相的性质和形态。结合近几年研究进展，综述了无机离子对CaCO3结晶过程的影响，重点介绍了常见金属阳离子及阴离子对CaCO3多晶型和形貌的影响，并初步分析其作用机理，为CaCO3的工业应用提供理论支持。

关键词: CaCO3, 无机离子, 结晶过程, 多晶型, 形貌