Journal of Petrochemical Universities ›› 2015, Vol. 28 ›› Issue (4): 55-59.DOI: 10.3969/j.issn.1006-396X.2015.04.012

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The Synergetic Enhancement Foaming Properties in Mixed Zwitterionic and Anionic Surfactant Systems

  

  1. (1.College of Petroleum Engineering, China University of Petroleum(East China), Qingdao Shandong 266580,China;  2.Beijing Beyond Technologies Co., Ltd., Beijing 101100,China;  3. Dagang Petrochemical Corporation of CNPC, Tianjing 300280,China;  4. Yisheng Dahua Petrochemical Co. Ltd., Dalian Liaoning 116600,China)
  • Received:2014-10-20 Revised:2015-03-14 Published:2015-08-25 Online:2015-08-25

两性/阴离子型表面活性剂协同增强起泡性能研究

路传波1, 2,  张炳花3,  李丙成1,  郑祖业4,  王汉威1,  范海明1, 康万利1   

  1.           
    ( 1. 中国石油大学( 华东) 石油工程学院, 山东青岛2 6 6 5 8 0; 2. 北京中环碧洋科技有限公司, 北京1 0 1 1 0 0;
    3. 中国石油大港石化公司, 天津3 0 0 2 8 0; 4. 逸盛大化石化有限公司, 辽宁大连1 1 6 6 0 0)
  • 通讯作者: 范海明( 1 9 8 2 - ) , 男, 博士, 副教授, 从事油田化学教学和科研工作; E - m a i l :H a i m i n g F a n@1 2 6. c o m。
  • 作者简介:路传波( 1 9 8 2 - ) , 男, 博士, 高级工程师, 从事油田化学科研工作; E - m a i l :M a n a g e r b o y@1 6 3. c o m。
  • 基金资助:
    国家自然科学基金项目( 5 1 1 0 4 1 6 9) ; 霍英东教育基金会青年教师基金项目( 1 4 1 0 4 7) ; 中央高校基本科研业务费专
    项资金项目( 1 3 C X 0 2 0 4 5 A; 1 4 C X 0 6 0 9 2 A) ; 国家大学生创新创业训练计划项目( 2 0 1 4 1 0 4 2 5 0 0 8) 。

Abstract: The foam properties of single and mixed surfactant systems prepared by zwitterionic surfactant NhexadecylN,Ndimethyl3ammonio1propane sulfonate (HDPS) and anionic surfactant sodium dodecyl sulfate(SDS) were investigated by Waring Blender method. And the effect of intermolecular interaction between HDPS and SDS on the foam properties was analyzed. It has been found that the electrostatic attraction between the headgroups of HDPS and SDS not only reinforces the surface activity but also promotes the formation of compacted adsorption film in the gasliquid surface for the mixed surfactant system. Therefore the foam comprehensive exponents of mixed HDPS and SDS surfactant systems are higher than that of each single surfactant in clean water and highly mineralized water, which exhibits the synergetic enhancement foaming properties.

Key words: Mixed surfactant system,    ,  Foaming volume,    ,  Foam stability,    ,  Foam comprehensive exponent,    ,  Synergistic effect

摘要: 利用 Wa r i n gB l e n d e r法研究了不同矿化度下两性离子表面活性剂十六烷基磺基甜菜碱( HD P S) 与阴 离子型表面活性剂十二烷基硫酸钠( S D S) 单一体系和复配体系的起泡性能, 分析了两性/阴离子型表面活性剂间相 互作用对起泡性能的影响。结果表明, 由于两性和阴离子型表面活性剂亲水基间的静电吸引作用既增强了复配体 系的表面活性, 又促进了复配体系在气液表面形成更加紧密的吸附膜, 因而在清水和高矿化度水质中, HD P S / S D S 复配体系的泡沫综合指数均高于单一表面活性剂体系, 表现出协同增强泡沫性能的作用。

关键词: 表面活性剂复配,  , 起泡体积, 泡沫稳定性,  , 泡沫综合指数, 协同效应

Cite this article

Lu Chuanbo,Zhang Binghua,Li Bingcheng,et al. The Synergetic Enhancement Foaming Properties in Mixed Zwitterionic and Anionic Surfactant Systems[J]. Journal of Petrochemical Universities, 2015, 28(4): 55-59.

路传波, 张炳花, 李丙成. 两性/阴离子型表面活性剂协同增强起泡性能研究[J]. 石油化工高等学校学报, 2015, 28(4): 55-59.