Journal of Petrochemical Universities ›› 2015, Vol. 28 ›› Issue (4): 13-17.DOI: 10.3969/j.issn.1006-396X.2015.04.003

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Preparation of CuO/C Adsorbent for Removal of HCl

  

  1. （1.College of Chemistry, Chemical Engineering and Environment, Liaoning Shihua University, Fushun Liaoning 113001, China; 2. School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China)
  • Received:2014-12-29 Revised:2015-01-16 Published:2015-08-25 Online:2015-08-25

C u O / C吸附剂的制备、 表征及其脱氯性能的研究

庄 超1,  牟川川1,  李 艺2,  杨丽霞1,  刘道胜1,  刘 丹2,  桂建舟2   

  1.                 
    ( 1. 辽宁石油化工大学化学化工与环境学部, 辽宁抚顺1 1 3 0 0 1; 2. 天津工业大学环境与化学工程学院, 天津3 0 0 3 8 7)
  • 通讯作者: 刘道胜( 1 9 7 6 - ) , 男, 博士, 副教授, 从事催化化学研究; E - m a i l : d s l i u 0 5@1 2 6. c o m。
  • 作者简介:庄超( 1 9 9 0 - ) , 女, 硕士研究生, 从事催化化学研究; E - m a i l : z c 1 1 2 5 4 8@1 6 3. c o m。
  • 基金资助:
    国家自然科学基金项目 ( 2 1 1 0 3 0 7 7) ; 新世纪优秀人才支持计划( NC E T - 1 1 - 1 0 1 1) 。

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Abstract: The adsorbents of SMC loaded copper oxide were prepared by using equal volume impregnation method, and their dechlorination performance of adsorbing hydrogenchloride in the reformate was investigated. Xray Diffraction (XRD) and N2 adsorption were used to characterize the prepared adsorbents. The effect of the loading amounts of copper oxide species, LHSV, nitial content of chlorine in reformate and reaction temperature were studied. The results showed that the dechlorination capacity could reach to 19.5% at a LHSV of 4 h-1 under 50 ℃ with the initial content of chlorine in reformate was not less than 20 ng/μL when load of CuO/C was 15%.

Key words: Reformate,    , Dechlorination,    ,  Chlorination capacity,    , Loading amounts,     , CuO/C

摘要： 采用等体积浸渍法制备了以碳分子筛为载体的C u O / C吸附剂, 并进行了重整生成油脱氯性能研究。 采用XR D及 N2 吸附等技术对吸附剂进行表征, 并考察了负载量、 温度、 液空速和重整生成油中氯化氢含量对吸附 剂脱氯效果的影响, 当吸附剂的最佳C u O负载量为1 5%, 在温度5 0℃、 液空速为4h-1, 氯含量≤2 0n g / μ L的条件 下, 氯容可以达到1 9. 5%。

关键词: 重整生成油,  , 脱氯, 氯容,  , 负载量,  , C u O / C

Cite this article

Zhuang Chao, Mou Chuanchuan, Li Yi,et al. Preparation of CuO/C Adsorbent for Removal of HCl[J]. Journal of Petrochemical Universities, 2015, 28(4): 13-17.

庄 超, 牟川川, 李 艺,. C u O / C吸附剂的制备、 表征及其脱氯性能的研究[J]. 石油化工高等学校学报, 2015, 28(4): 13-17.

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