Corrosion Inhibition by Schiff Base and Its Synergize System on Carbon Steel

doi:10.3969/j.issn.1006-396X.2014.01.001

Journal of Petrochemical Universities ›› 2014, Vol. 27 ›› Issue (1): 1-5.DOI: 10.3969/j.issn.1006-396X.2014.01.001

Received:2013-06-19 Revised:2013-12-20 Published:2014-02-25 Online:2014-06-10

席夫碱化合物及其复配体系对碳钢缓蚀性能的研究

( 辽宁石油化工大学化学与材料学院, 辽宁抚顺1 1 3 0 0 1)

通讯作者: 吕振波( 1 9 6 4 - ) , 男, 博士, 教授, 从事催化反应工程及石油化学品研究; E - m a i l : l z h b 6 6 8 4 7 0 8@1 6 3. c o m。
作者简介:王舒青( 1 9 8 4 - ) , 女, 硕士研究生, 从事金属腐蚀与防护研究; E - m a i l : s h u q i n g 0 4 7 1@1 6 3. c o m。
基金资助:
国家自然科学基金项目( 2 1 1 0 3 0 7 7) ; 教育部新世纪优秀人才支持计划( NC E T 灢 1 1 灢 1 0 1 1) ; 教育部重点项目( 2 0 9 0 3 1) ;辽宁省高等学校杰出青年学者成长计划( L J Q 2 0 1 1 0 3 5) ; 辽宁省自然科学基金项目( 2 0 1 1 0 2 1 2 0, 2 0 1 2 0 2 1 2 3) 。

Abstract

Abstract: The inhibition effect between 3methy4aminocinnamaldehydene5mercapto1,2,4triazole Schiff base (short for MACHMT) and cinnamic aldehyde (short for CA), 3methy4amino5mercapto1,2,4triazole（short for MACMT）on Q235 steel in the hydrochloric acid was studied by polarization curves, electrochemical impedance spectroscopy. The corrosion performance and inhibition mechanism was discussed and compared. Experiments show that stability and inhibition effeciency of cinnamic aldehyde with a 3methyl4amino5mercapto1, 2,4triazole’s complex system for Q235 carbon steel are higher than the same concentration of seats Schiff base compounds MACHMT. 

Key words: Schiff base, , Inhibitor, , , Q235 Carbonsteel, , Cinnamic aldehyde, , Synergize

摘要： 采用极化曲线、交流阻抗法对比研究了 3 - 甲基 - 4- 胺基缩肉桂醛 - 5 - 巯基 - 1, 2, 4- 三氮唑席夫碱( MACHMT)与其原料的复配体系肉桂醛( CA) 、 3 - 甲基 - 4 - 氨基 - 5 - 巯基 - 1, 2, 4 - 均三唑( 简称 MACMT) 对 Q 2 3 5碳钢在2 5曟下、 0. 5m o l / L盐酸介质中的缓蚀性能, 并探讨了这两种缓蚀剂的缓蚀机理。实验表明, 肉桂醛与3 - 甲基 - 4 -氨基 - 5 - 巯基 - 1, 2, 4 - 均三唑的复配体系对 Q 2 3 5碳钢的整体缓蚀性和稳定性均高于相同浓度席夫碱化合物 MACH -MT。

关键词: 席夫碱, , 缓蚀剂, , Q 2 3 5碳钢, , 肉桂醛, , 复配

Wang Shuqing, Wang Xingzhi, Lyu Zhenbo, et al. Corrosion Inhibition by Schiff Base and Its Synergize System on Carbon Steel [J]. Journal of Petrochemical Universities, 2014, 27(1): 1-5.

王舒青, 王兴之, 吕振波,刘丹,桂建舟,曹淑云,焦健. 席夫碱化合物及其复配体系对碳钢缓蚀性能的研究[J]. 石油化工高等学校学报, 2014, 27(1): 1-5.

[1]	Ren Zhengbo，Lu Shuang，Liu Lin. Corrosion Inhibition Performance of Two Kinds of Schiff Base Inhibitors of o⁃Phenylenediamine [J]. Journal of Petrochemical Universities, 2019, 32(2): 8-14.
[2]	Shi Xuewei,Wu Yanyang,Xu Shouhong,et al. Removal of Co²⁺ and Mn²⁺ from Wastewater with CH-90 Exchange Resin [J]. Journal of Petrochemical Universities, 2017, 30(5): 1-5.
[3]	Hu Wenxue,Zhou Rujin,Shen Jian. The Effects of Operating Parameters on the Coking of the HVGO during Pyrolysis Process [J]. Journal of Petrochemical Universities, 2017, 30(5): 6-11.
[4]	Lai Junling, Lai Xiaochen, Liu Ye, et al. Preparation of Dry Water and Dry Bases for Catalytic Hydrolysis of Carbonyl Sulfide [J]. Journal of Petrochemical Universities, 2017, 30(5): 12-16.
[5]	Song Guanlong,Zhao Dezhi,Wu Qing,et al. Effect of Reaction Conditions on Hydrocracking Reaction of Slurry Bed [J]. Journal of Petrochemical Universities, 2017, 30(5): 17-21.
[6]	Qi Bangfeng， Song Junhui. Hydrofining Process Research on Removing PAHs by Naphthenic Vacuum Gas Oil [J]. Journal of Petrochemical Universities, 2017, 30(5): 22-25.
[7]	Yang Zihao,Zhao Ji,Tang Yongliang,et al. Plugging Effect of Micro Crosslinked Polymer Microspheres on Nucleopore Membrane [J]. Journal of Petrochemical Universities, 2017, 30(5): 26-31.
[8]	Zhu Zhou,Kang Wanli,Yang Hongbin,Zhang Bo. Synthesis and Rheological Properties of a Sulfobetaine Amphiphilic Polymer [J]. Journal of Petrochemical Universities, 2017, 30(5): 32-36.
[9]	Han Guilin. Characterization of Contribution of Emulsification to Injection Pressure and Its Affecting Factors [J]. Journal of Petrochemical Universities, 2017, 30(5): 37-41.
[10]	Wu Hongchen,Zhang Xiaoli,He Jinxian,et al. Dissolution Mechanism of Feldspar of Tight Sandstone and Its Influencing Factors [J]. Journal of Petrochemical Universities, 2017, 30(5): 42-49.
[11]	Zhang Dong, Hou Yawei, Zhang Mo,et al. Quantitative Research of Relationship Between Oil Displacement Efficiency  and Pore Volume Injection Ratio Based on Logistic Model [J]. Journal of Petrochemical Universities, 2017, 30(5): 50-54.
[12]	Zhang Jicheng, Zheng Lingyun. The Study on Technical Limits for Interlayer Channeling of InjectionProduction Well Area [J]. Journal of Petrochemical Universities, 2017, 30(5): 60-65.
[13]	Chen Jianheng, He Limin, Lyu Yuling, Li Xiaowei. Analysis on the Movement Characteristics of Bypass  Pig and PigGenerated Slug Dissipation [J]. Journal of Petrochemical Universities, 2017, 30(5): 66-71.
[14]	Wan Yufei, Chen Zhengwen, Liu Chunyu,et al. Dynamic Analysis on Pressure Relief Process under Blocking Accident [J]. Journal of Petrochemical Universities, 2017, 30(5): 72-79.
[15]	Gong Qingjun,Ma Guiyang,Pan Zhen,et al. Prediction of Natural Gas Hydrate Formation Based on Support Vector Machine (SVM)CV [J]. Journal of Petrochemical Universities, 2017, 30(5): 80-85.