Application of GPC-ELSD in the Deterimination of Relative Molecular Weight and Its Distribution of VGO

Journal of Petrochemical Universities ›› 2007, Vol. 20 ›› Issue (2): 15-17.

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Application of GPC-ELSD in the Deterimination of Relative Molecular Weight and Its Distribution of VGO

ZHUANG Li-hong¹， TIAN Yan-wen²， L Zhen-bo², ZHANG Da-wei²

1. School of Materials & Metallurgy,Northeastern University,Shenyang Liaoning 110004,P.R.China ; 
2. Research Centre of Analysis and Test,Liaoning University of Petroleum & Chemical Technology, Fushun Liaoning 113001,P.R.China

Published:2007-06-20 Online:2017-06-28

GPC-ELSD测定VGO馏分油的相对分子质量及其分布

庄丽宏¹, 田彦文¹, 吕振波², 张大伟²

1.东北大学材料与冶金学院,辽宁沈阳110004; 2.辽宁石油化工大学分析测试研究中心,辽宁抚顺113001

作者简介:庄丽宏(1965-),女,辽宁抚顺市,高级工程师,博士研究生
基金资助:
国家自然基金资助项目(50174016)。

Abstract

Abstract:

A High performance gel permeation chromatography(GPC),evaporative light-scattering detector(ELSD) method were applied to determine the relative molecular weight and its distribution of vacuum gas oil(VGO),adopting linear calibration with kown relative molecular weight calibration standard and complicated mathematics operation. Also the precision of the technique was evaluated and the relative molecular weight between GPC and VPO was compared. The results show that the relative error is less than 1%, comparison with traditional method of VPO the analysical rate is promoted five times, the sample oils less to 1/10. The technique is accurate, fast and high level of automatic operation. 

Key words: High performance gel permeation chromatography（GPC）, , Evaporative light-scattering detector（ELSD）, Vacuum gas oil , Relative molecular weight , Relative molecular weight distribution

摘要： 应用高效凝胶色谱仪(GPC)、蒸发光散射检测器(ELSD)及已知相对分子质量的标样,采用线性校正
法进行校正,经过复杂的数学运算得到VGO 馏分油的相对分子质量及其分布。考察了该方法测定的精密度,并与
传统蒸汽压渗透计法(VPO)进行了对比实验。结果表明,该实验相对偏差小于1%,与传统VPO 方法相比分析速度
提高5倍,进样量减少到1/10。该方法具有准确快速、自动化高的特点。

关键词: 高效凝胶色谱 , , 蒸发光散射检测器 , VGO 馏分油 , 相对分子质量 , 相对分子质量分布

ZHUANG Li-hong， TIAN Yan-wen， LZhen-bo, ZHANG Da-wei. Application of GPC-ELSD in the Deterimination of Relative Molecular Weight and Its Distribution of VGO[J]. Journal of Petrochemical Universities, 2007, 20(2): 15-17.

庄丽宏, 田彦文, 吕振波, 张大伟. GPC-ELSD测定VGO馏分油的相对分子质量及其分布[J]. 石油化工高等学校学报, 2007, 20(2): 15-17.

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Application of GPC-ELSD in the Deterimination of Relative Molecular Weight and Its Distribution of VGO

GPC-ELSD测定VGO馏分油的相对分子质量及其分布

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