Preparation of HZSM-5/Monolithic Catalyst and its Application in Conversion of Methanol to Gasoline

doi:10.3696/j.issn.1672-6952.2015.01.004

Journal of Liaoning Petrochemical University ›› 2015, Vol. 35 ›› Issue (1): 12-15.DOI: 10.3696/j.issn.1672-6952.2015.01.004

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Preparation of HZSM-5/Monolithic Catalyst and its Application in Conversion of Methanol to Gasoline

Lu Yanbin1, Ma Biao2, Zhang Weichen3

1.Montoring Station of BeichenDsitrict’s Environmental Protection Department, Tianjin 300400,China；
2.Planning Department of Fushun Petrochemical Company, Petro. Co., Ltd., Fushun Liaoning113008,China； 3.Beijing University of chemical Technology,Beijing100029, China

Published:2015-02-15 Online:2015-02-28

HZ SM - 5 /整体式催化剂的制备及其在甲醇制汽油反应中的应用

陆彦彬1,马彪2,张伟辰3

( 1. 天津市北辰区环境保护监测站, 天津3 0 0 4 0 0; 2. 中国石油天然气股份有限公司抚顺石化分
, 1 1 3 0 0 8; 3. , 1 0 0 0 2 9)

作者简介:陆彦彬( 1 9 7 0 - ) , 男, 高级工程师, 从事环境保护监测方面的研究; E - m a i l : q x b c h q@1 6 3. c o m。
基金资助:
国家科技支撑计划项目( 2 0 1 0 B AK 6 9 B 2 4) 。

Abstract

Abstract:

HZSM-5 was loaded on the cordierite monolithic, and the effect of porous size of the carrier, solid content in slurry, solvent and binder on the loaded amount and loaded quality has been studied. The results show that the big channel, high solid content and the addition of ethanol solvent could increase the loaded amount of the active components in each immobilization process, yet the loaded quality of HZSM5/monolithic catalyst was decreased. While silica sol could significantly increas ethe loaded quality of HZSM5 on monolithic. In conversion of methanol to gasoline, HZSM-5/ monolithic catalyst exhibited high methanol conversion, and oil yield could reach 30.53% at 380 ℃.

Key words: HZSM-5, Monolithic catalyst, Methanol, Gasoline, Cordierite, Preparation, Oil yield

摘要： 采用涂覆法将 HZ SM - 5负载到堇青石整体式载体上, 研究了载体的孔直径、浆液固含量、溶剂及黏结
剂对负载量和负载牢固度的影响。实验结果表明, 载体的孔直径大、浆液固含量高和以乙醇为溶剂可以提高 HZ SM -
5在整体式载体上的单次负载量, 但是却降低了 HZ SM - 5在整体式载体表面的负载牢固度, 黏结剂硅溶胶可以大幅
度提高活性组分在整体式载体表面的负载牢固度。在甲醇制汽油反应中, HZ SM - 5 /整体式催化剂表现出较高的甲
醇转化率, 在3 8 0℃时汽油收率达到3 0. 5 3%。

关键词: HZ SM - 5, 整体式催化剂, 甲醇, 汽油, 堇青石载体, 制备, 汽油收率

Lu Yanbin, Ma Biao, Zhang Weichen.

Preparation of HZSM-5/Monolithic Catalyst and its Application in Conversion of Methanol to Gasoline[J]. Journal of Liaoning Petrochemical University, 2015, 35(1): 12-15.

陆彦彬,马彪,张伟辰. HZ SM - 5 /整体式催化剂的制备及其在甲醇制汽油反应中的应用[J]. 辽宁石油化工大学学报, 2015, 35(1): 12-15.

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Preparation of HZSM-5/Monolithic Catalyst and its Application in Conversion of Methanol to Gasoline

HZ SM - 5 /整体式催化剂的制备及其在甲醇制汽油反应中的应用

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