Journal of Liaoning Petrochemical University

Journal of Liaoning Petrochemical University ›› 2018, Vol. 38 ›› Issue (1): 1-9.DOI: 10.3969/j.issn.1672-6952.2018.01.001

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RareEarthMetal􀆼MediatedGroupTransferPolymerization inthePolymerizationofPolarMonomers

Dong Xiaozhe1,Hou Liman2,Zhou Mingdong1,Zhang Ning2   

  1. 1.College of Chemistry,Chemical Engineering and Environmental Engineering, Liaoning Shihua University,Fushun Liaoning 113001,China; 2.Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry,  Chinese Academy of Sciences, Changchun Jilin 130012, China
  • Received:2016-11-03 Revised:2017-04-07 Published:2018-02-28 Online:2018-02-27

稀土金属催化的基团转移聚合在极性单体聚合中的应用

董晓哲1,侯丽曼2,周明东1,张 宁2   

  1. 1.辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001; 2.中国科学院长春应用化学研究所中科院合成橡胶重点实验室,吉林长春130012
  • 通讯作者: 周明东(1980-),女,博士,教授,从事过渡金属均相催化的研究:E-mail:mingdong.zhou@lnpu.edu.cn。
  • 作者简介::董晓哲(1989-),女,硕士研究生,从事功能型聚合物刷的研究;E-mail:dongxiaozhe0729@163.com。
  • 基金资助:
    :国家自然科学基金项目(51673194);中国科学院合成橡胶重点实验室开放课题(KLSR1602)。

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Abstract: The research progress of rare earth metal-mediated group transfer polymerization (REM-GTP) is reviewed. The main features of this polymerization method, the polymerization mechanism and its application in the polymerization of vinyl phosphonates and other nitrogencoordinating monomers are introduced. The application prospect and developing direction of this kind of polymerization method are also forecasted.

Key words: Rare earth metal complexes, REM-GTP, Polar monomer

摘要： 综述了稀土金属催化的基团转移聚合的研究进展,介绍了这一聚合方法的主要特征、聚合的机理及其在乙烯基磷酸酯和其他含氮单体聚合中的应用,并对这类聚合的应用前景和发展方向进行了展望。

关键词: 稀土金属配合物, 基团转移聚合, 极性单体

Cite this article

Dong Xiaozhe,Hou Liman,Zhou Mingdong,Zhang Ning. RareEarthMetal􀆼MediatedGroupTransferPolymerization inthePolymerizationofPolarMonomers[J]. Journal of Liaoning Petrochemical University, 2018, 38(1): 1-9.

董晓哲,侯丽曼,周明东,张 宁. 稀土金属催化的基团转移聚合在极性单体聚合中的应用[J]. 辽宁石油化工大学学报, 2018, 38(1): 1-9.

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