纺锤状氧化锌的制备与形成机理

辽宁石油化工大学学报 ›› 2009, Vol. 29 ›› Issue (4): 43-46.

纺锤状氧化锌的制备与形成机理

赵荣祥¹,曹群²,陈海丽²,李秀萍³

1.辽宁石油化工大学石油化工学院,辽宁抚顺113001;2.中国矿业大学化工学院,江苏徐州221008;
3.辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001

收稿日期:2009-04-12 出版日期:2009-12-25 发布日期:2017-07-05
作者简介:赵荣祥(1971-),男,辽宁锦州市,讲师,博士

Preparation and Growth Mechanism of ZnO With Spindle Shape

ZHAO Rong-xiang¹, CAO Qun², CHEN Hai-li², LI Xiu-ping³

1.School of Petrochemical Engineering, Liaoning University of Petroleum ＆ Chemical Technology, Fushun Liaoning 113001, P.R.China; 2.School of Chemical Engineering, China University of Mining and Technology,  Xuzhou Jiangsu 221008, P.R.China; 3.School of Chemistry and Materials Science, Liaoning University of Petroleum ＆ Chemical Technology, Fushun Liaoning 113001, P.R.China

Received:2009-04-12 Published:2009-12-25 Online:2017-07-05

摘要/Abstract

摘要： 采用超声波辅助回流法制备了高纯度且尺寸一致的纺锤状氧化锌。用扫描电镜、透射电镜和X射线
粉末衍射技术对氧化锌的形貌和结构进行了表征。实验结果表明,溶液的碱度、超声处理和二乙醇胺的质量对氧化
锌形貌的调控起了重要作用,初步探讨了纺锤状氧化锌的形成机理并用紫外-可见吸收光谱和荧光光谱测定了其
光学性质。

关键词: 氧化锌 , 纺锤 , 形成机理

Abstract: ZnO with spindle shape was synthesized by ultrasonic-assisted reflux method. The micrograph and structure of ZnO sample were charactered by SEM, TEM and XRD.The results show that basic content of solution, ultrasonic treatment and the mass of diethanolamine play an important role on the formation of ZnO with spindle shape. The growth mechanism of ZnO with spindle shape was discussed. Furthermore, the optical properties of ZnO with spindle shape were revealed by UV-Vis and fluorescence spectroscopy.

Key words: Zinc oxide , Spindle , Growth mechanism

赵荣祥,曹群,陈海丽,李秀萍. 纺锤状氧化锌的制备与形成机理[J]. 辽宁石油化工大学学报, 2009, 29(4): 43-46.

ZHAO Rong-xiang, CAO Qun, CHEN Hai-li, LI Xiu-ping. Preparation and Growth Mechanism of ZnO With Spindle Shape[J]. Journal of Liaoning Petrochemical University, 2009, 29(4): 43-46.

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