石油化工高等学校学报

石油化工高等学校学报 ›› 2008, Vol. 21 ›› Issue (1): 1-3.

• 石油化工 •    下一篇

磁铅石型催化剂的表征及其催化燃烧活性

任晓光1, 郑建东1,2,3, 宋永吉1, 于君英1   

  1. 1.北京石油化工学院,北京102617; 2.北京化工大学化学工程学院,北京100029;
    3.沈阳工业大学石油化工学院,辽宁辽阳111003
  • 收稿日期:2007-03-12 出版日期:2008-03-20 发布日期:2017-06-28
  • 作者简介:任晓光(1956-),女,辽宁锦州市,教授,博士
  • 基金资助:
    国家自然科学基金资助项目(20476012);北京市属、市管高校人才强教计划资助项目(BJJWR20051102)。

Characterization of MP-Like Catalysts and Investigation on Catalytic Activity of Methane Combustion

REN Xiao-guang1, ZHENG Jian-dong1,2,3, SONG Yong-ji1, YU Jun-ying1   

  1.  
    1.Beijing Institute of Petrochemical Technology,Beijing 102617,P.R.China; 
    2.College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P.R.China;
    3.School of Petrochemical Technology, Shenyang University of Technolony, Liaoyang Liaoning 111003,P.R.China
  • Received:2007-03-12 Published:2008-03-20 Online:2017-06-28

PDF

摘要： 用共沉淀法制备Cd,Zn,Zr和Mn共同搀杂作为活性组分的一系列磁铅石型镧六铝酸盐催化剂,通
过BET,XRD分析及甲烷燃烧,对催化剂的结构和性质进行了考察。研究了搀杂不同过渡金属的催化剂的结构以及
对甲烷催化燃烧活性的影响。结果表明,催化剂在1200℃焙烧后可以形成完整的六铝酸盐晶型,同时具有较高的
催化性能和高温稳定性,两种不同的金属离子同时取代对于催化剂的活性有较大的影响,进一步说明了不同离子之
间存在着一定的协同作用。由于协同效应的存在使催化剂的活性得到明显提高,其中以LaZnMnAl10O19催化剂的
活性最好,其起燃温度T10% 为472℃,完全转化温度T90% 为734℃。

关键词: 甲烷  ,  , 催化燃烧 ,   磁铅石  ,   活性

Abstract: A series of MP-like catalysts LaAAl11O19 and LaAMnAl10O19 (A stands of Cd,Zn,Zr) were prepared by co-precipitation method. The structure and the properties of these catalysts were investigated by using BET,XRD techniques and activities of methane catalytic combustion. The influence of different transition metal on the morphological and catalytic activity of the catalysts was studied. The results show that the catalyst with good crystal is obtained after calcination at 1 200 ℃. And all catalysts have the high catalytic activity and stability. The introduction of different transition metal has much effect on the properties of catalysts. The synergism is observed between the different metal ion. Catalytic activity is enhanced by synergism. LaZnMnAl10O19  has the higher catalytic activity in methane combustion and its light-off T 10% is 472 ℃, total conversion  T 90% is 734 ℃.

Key words: Methane   , Catalytic combustion    , Mannetoplumbite   ,  Activity

引用本文

任晓光, 郑建东, 宋永吉, 于君英. 磁铅石型催化剂的表征及其催化燃烧活性[J]. 石油化工高等学校学报, 2008, 21(1): 1-3.

REN Xiao-guang, ZHENG Jian-dong, SONG Yong-ji, YU Jun-ying. Characterization of MP-Like Catalysts and Investigation on Catalytic Activity of Methane Combustion[J]. Journal of Petrochemical Universities, 2008, 21(1): 1-3.

使用本文

0
    /   /   推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal.lnpu.edu.cn/syhg/CN/

               http://journal.lnpu.edu.cn/syhg/CN/Y2008/V21/I1/1



网站版权 © 2021《石油化工高等学校学报》编辑部

本系统由北京玛格泰克科技发展有限公司设计开发