Mo P催化剂的制备及对溶剂油的加氢活性

doi:10.3969/j.issn.1006-396X.2015.02.009

石油化工高等学校学报 ›› 2015, Vol. 28 ›› Issue (2): 46-49.DOI: 10.3969/j.issn.1006-396X.2015.02.009

Mo P催化剂的制备及对溶剂油的加氢活性

阎松, 娄艳艳, 张静

( 辽宁石油化工大学, 辽宁抚顺1 1 3 0 0 1)

收稿日期:2014-11-17 修回日期:2014-12-24 出版日期:2015-04-25 发布日期:2015-06-23
作者简介:阎松( 1 9 7 8 - ) , 男, 硕士, 实验师, 从事绿色化学与催化方面研究; E - m a i l : y a n s o n g 5 8 5 9@s i n a. c o m。
基金资助:
辽宁省自然科学基金项目( 2 0 1 0 2 1 3 1) 。

Preparation of Molybdenum Phosphide Catalyst and Its  Hydrogenation Activity on Mineral Solvents

(Liaoning Shihua University, Fushun Liaoning 113001, China)

Received:2014-11-17 Revised:2014-12-24 Published:2015-04-25 Online:2015-06-23

摘要/Abstract

摘要： 用浸渍法制备了 Mo P / A l₂O₃ 催化剂前体, 通过该前体采用体外还原 - 钝化 - 还原的方法制备了 Mo P / A l₂O₃。选用C ₆、 C ₇ 溶剂油作为模型化合物, 以 A l₂O₃ 为载体, 考察不同实验条件下磷化钼催化剂的活性。结果表明, Mo O₃ 质量分数为2 2%的磷化钼催化剂的使用条件为反应温度2 1 0℃、空速1. 5h^-1; 当 Mo O₃质量分数为1 4% 时, 其反应条件为反应温度2 3 0℃、空速1. 5h^-1。

关键词: 磷化钼催化剂, 溶剂油, 加氢饱和, 加氢活性

Abstract: The MoP/A l₂O₃ catalyst precursor was prepared with impregnation method and a series of A l₂O₃supported molybdenum phosphide catalysts were prepared by convention reductionpassivationreduction method using the precursor. The catalytic activity of MoP/A l₂O₃ was investigated on different conditions in solvent oil C6, C7 as model compounds. The results showed that the application conditions of MoP/A l₂O₃ catalyst with 22% and 14% molybdenum trioxide content were reaction temperature 210 ℃, space velocity 1.5 h^-1 and reaction temperature 230 ℃ and space velocity 1.5 h^-1 respectively.

Key words: Molybdenum phosphide catalyst, , Mineral solvent, , Hydrogenation saturation, , Hydrogenation activity

阎松, 娄艳艳, 张静. Mo P催化剂的制备及对溶剂油的加氢活性[J]. 石油化工高等学校学报, 2015, 28(2): 46-49.

Yan Song, Lou Yanyan, Zhang Jing. Preparation of Molybdenum Phosphide Catalyst and Its  Hydrogenation Activity on Mineral Solvents [J]. Journal of Petrochemical Universities, 2015, 28(2): 46-49.

[1]	杨靖华, 亓玉台. C 2H4C l 2 / T i C l 4 催化制备石油树脂蒸出C 9 馏分脱烯烃研究[J]. 石油化工高等学校学报, 2015, 28(2): 35-40.
[2]	刘世达,王海燕,杨秀娜. PROII流程模拟软件在溶剂油分离中的应用[J]. 石油化工高等学校学报, 2012, 25(6): 18-20.

Mo P催化剂的制备及对溶剂油的加氢活性

Preparation of Molybdenum Phosphide Catalyst and Its  Hydrogenation Activity on Mineral Solvents

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