Journal of Liaoning Petrochemical University
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Journal of Liaoning Petrochemical University 2018 Vol.38
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Abstract242)      PDF (1083KB)(198)      
2018, 38 (02): 0-.
Research Progress in Preparation and Catalytic Performance of the Carbon-Based Non Noble Metal Catalysts
Yang Fan, Li Yongfeng
Abstract742)      PDF (2833KB)(574)      
The research and development of carbon-based non noble metal catalysts is one of the leading directions in the field of materials science and catalysis. Although, compared with conventional noble metal catalysts, it has the unique advantages of large surface area, wide source, low cost, environmental friendliness, corrosion resistance and so on. Combining the research progress of carbon-based non noble metal catalysts at home and abroad in recent years, the synthesis methods and research status of graphenebased non-metal catalysts, graphene-based non-precious metal oxide catalysts and carbon materials dispersed nonprecious metal catalysts are reviewed.
2018, 38 (02): 1-8. DOI: 10.3969/j.issn.1672-6952.2018.02.001
Hydrothermal Cracking Reaction Mechanism of the Residue under the Effect of Ultrasonic Wave
Wang Chong, Zhao Dezhi, Song Guanlong, Li Ying, Yang Zhanxu, Zhao Yun, Zhang Wenjun
Abstract634)      PDF (1853KB)(217)      
Using a high-temperature and high-pressure ultrasonic reactor, the hydrothermal cracking reaction of vacuum residue of Huizhou Refinery. The gas product composition, liquid product composition, reaction coke SEM morphology, and element analysis were investigated to discuss the mechanism of hydrothermal cracking reaction under the effect of ultrasonic wave. The results show that there is no significant difference in the yield of gas products in hydrothermal cracking reaction mechanism of the residue under the effect of ultrasonic wave and the production rate of light oil has been increased slightly while that of coke has been slightly reduced. The angularity of the coke particles is relatively smooth and the pore structure appears, indicating that under the effect of ultrasonic wave, the hydrothermal cracking reaction of residual oil is mainly based on the radical thermal reaction mechanism and the cavatition of ultrasonic wave can promote the residuum to have cracking reaction so that the production rate of light oil has been slightly increased. The mechanical effect of ultrasonic wave causes the raw coke precursor suspended in the residue to oscillate violently, so as to prevent its polymerization, thus having reduced coking, the large increase of Ni in the coke indicates that the catalyst provides a coking center for coking.
2018, 38 (02): 9-12. DOI: 10.3969/j.issn.1672-6952.2018.02.002
Effect of F-T Wax on the Blending Properties of Paraffin Wax
Peng Yida,Dai Yongchuan,Zhao Dezhi,Feng Shuo,Zhang Zhe,Yin Yunzhi
Abstract706)      PDF (2192KB)(285)      
Paraffin wax was blended with F-T wax. The effects of the mass fraction of F-T wax on paraffin 46 # and 58 # were investigated respectively. The results show that the addition of F-T wax can significantly increase the melting point of paraffin, when the mass fraction of F-T wax increases from 0.05% to 30.00%, the melting point of 46 # and 58 # blended wax drops from 72.4 ℃ to 44.4 ℃, and drops from 88.4 ℃ to 62.4 ℃, respectively. With the increase of the mass fraction of F-T wax, the melting point and penetration of blended wax decrease continuously, that is, the mass fraction of F-T wax is inversely proportional to the drop melting point and penetration. The analysis of the crystalline structure of the blended wax shows that, the content of non-isoparaffins in the blended wax is higher. So its crystal structure is an array of inclined lattice arrangement of the long needlelike wax crystals, and the natural paraffin crystallization is different with others, which composition is more complex.
2018, 38 (02): 13-15. DOI: 10.3969/j.issn.1672-6952.2018.02.003
Study on High Carbon Chain Erucic Acid Clean Fracturing Fluid
Ma Chao, Wan Zhilong, Zhang Ningtao, Li Shengsheng, Hu Feng, Yin Lingxue
Abstract685)      PDF (2159KB)(208)      
At present, most of the main agent of conventional clean fracturing fluids are viscoelastic sixteen (or eighteen) alkyltrimethylammonium chloride, which has poor temperature resistance (generally less than 60 ℃). The quaternary ammonium salt type surfactant (JS-VES) based on high carbon chain erucic acid has good temperature resistance. In this paper, a high-carbon erucic acidtype clean fracturing fluid (mass fraction) (0.80% JS-VES+0.68%NaSal+2.60%KCl+0.40%Na 2S 2O 3) was developed with JSVES as the main agent, and compared with the conventional clean fracturing fluid system performance. The highcarbon erucic acidtype clean fracturing fluid system (25 ℃, 170 s -1) has an apparent viscosity of 25 mPa•s. It has good shear resistance, and can meet the requirements of suspended sand in the static suspension of sand, with a good breaking capacity (2 mPa•s) and temperature resistance (80 ℃).
2018, 38 (02): 16-19. DOI: 10.3969/j.issn.1672-6952.2018.02.004
Research Status and Prospect of Adsorption and Diffusion
Li Xianming, Liu Shu, Wang Xiaoning
Abstract945)      PDF (1226KB)(262)      

The common research methods for the adsorption and diffusion of zeolite molecular sieves at home and abroad, the characteristics and applicable scope of each method, and the research status of adsorption and diffusion phenomena at home and abroad are introduced. The research results of domestic and foreign scientific research workers are systematically introduced. On this basis, the scientific problems that existed in this field are put forward. Aiming at these problems, a research program by using gas chromatography for the study of adsorption and diffusion phenomena is proposed. The principle of gas chromatography and the method of adsorption and diffusion are described in detail. The corresponding formulas are deduced, and the application of gas chromatography in the study of adsorption and diffusion is also prospected.

2018, 38 (02): 20-25. DOI: 10.3969/j.issn.1672-6952.2018.02.005
Noble Metal Nanoparticles Supported Strontium Titanate Photocatalyst
Dong Yingnan, Tian Xiaoming, Liu Jin, Li Shanshan, Bi Xiaoguo
Abstract684)      PDF (2194KB)(225)      
Recently, strontium titanate (SrTiO 3) is becoming a research hotspot due to its potential application for a new photocatalytic material. In this paper, M/SrTiO 3 catalysts (M=Ag, Pd) were prepared by loading Ag or Pd nanoparticles on the surface of strontium titanate powder in different proportions. The experimental results showed that both Ag and Pd nanoparticles could effectively promote the photocatalytic degradation of methyl orange by strontium titanate, and the type and load of noble metal have obvious effect on the activity of the catalyst. The catalyst had the highest methyl orange degradation rate of 95.1% after the reaction for 2 h when the Ag mass fraction was 0.2%. Notably, the degradation rate over the catalyst increased by about 35% comparing with pure strontium titanate powder. Similar to Ag/SrTiO 3, the degradation rate with Pd mass fraction of 0.2% increased by about 26% comparing with that on pure strontium titanate powder. The mechanism and effect of noble metals on the photocatalytic performance of strontium titanate were briefly discussed.
2018, 38 (02): 26-29. DOI: 10.3969/j.issn.1672-6952.2018.02.006
Effect of Chloride Ion on Corrosion Resistance of 2205 Duplex  Stainless Steel in Hydrofluoric Acid
Pang Xuguang, Hou Guanyu, Liang Ping
Abstract1984)      PDF (2187KB)(301)      
The corrosion behavior of 2205 duplex stainless steel (DSS) in hydrofluoric acid (HF) was affected by the chlorine ion. The methods including immersion, potentiodynamic polarization and electrochemical impedance spectra (EIS) were used to understand the effect. The results showed that while the NaCl concentration was added into HF solution from 0.015 mol/L to 0.030 mol/L, the corrosion potential got more positive, and the corrosion current density and average corrosion rate increased with the increasing NaCl content. It was because that NaCl decreased the pH of HF solution.
2018, 38 (02): 30-32. DOI: 10.3969/j.issn.1672-6952.2018.02.007
Numerical Simulation on Leakage of Buried Gas Pipeline Based under Multi Building Condition
Zhang He, Ma Guiyang
Abstract520)      PDF (5949KB)(235)      
Aiming at the process on leakage of buried gas pipeline in urban area, and considering gas of different constituents and concentration leakage based under multi building condition, using computational fluid dynamics (CFD) software to establish the three-dimensional physical model of buried pipeline in the leakage process, the environmental wind field and leakage rate into the boundary conditions in the form of user-defined functions were introduced, and the simulation process was divided into steady-state simulation in environmental wind field and transient simulation in leakage. And the leakage process was divided into continuous leakage and leakage after pipe valve closing, and the gas leakage rules were analyzed. The results showed that: It was necessary to simulate the steady state in environmental wind field. There existed three low velocity zones near the flow field and a large velocity gradient on the edge of the building. It showed the following characteristics that the confined leakage of oil layer diffusion, low velocity zone upstream gathering, gas cloud rising, hydrogen sulfide deposition and diffusion and so on in the gas continuous leakage stage. It showed the characteristics of the gas diffusion continuity and dissipation from top to bottom in the valve closed stage. Based on the conditions above, comparing methane, hydrogen sulfide had larger diffusion range, later dissipation time, and greater risk.
2018, 38 (02): 33-39. DOI: 10.3969/j.issn.1672-6952.2018.02.008
Application of River Prediction Based on Gray Relational and  Support Vector Machine in N Area of S Oilfield
Li Yang
Abstract438)      PDF (10978KB)(178)      
It is difficult to predict the accuracy of the river by using the conventional seismic attributes, due to the complex conditions of the terrigenous clastic basin reservoirs and the rapid change of the rock facies. In this paper, XII7-12 layer in N area of S oilfield is taken as an example. Through the seismic forward analysis, the seismic section reflection characteristics of different types of reservoirs are different, and the seismic attributes of the combined layer can be used as the effective dimension for the main channel prediction in this area. On this basis, using the method of the combination of Gray Relational Analysis and Support Vector Machine, the N zone seismic attribute prediction based on Gray Relational Support Vector Machine is completed. Drilling confirmed that based on Gray Correlation and Support Vector Machine attribute prediction, the drilling coincidence rate is higher. By using the advantage of seismic inversion to predict the boundary of the channel sand, the comprehensive analysis of dynamic and static data of the polymer flooding well group effectively solved the contradiction between the injection and production system of the XII7-12 strata system in the N area of the S oilfield, thus, it further confirms the accuracy of attribute prediction based on GRA-SVM. Comprehensive research shows that this method is suitable for high accuracy of the river prediction and can be used as a better river prediction method under complex geological conditions.
2018, 38 (02): 40-46. DOI: 10.3969/j.issn.1672-6952.2018.02.009
Numerical Simulation Research in Erosion-Corrosion of 90° Elbow Pipe
Sun Zonglin, Xing Zhenhua, Zhang Mengyun, Duan Pengfei, Wu Yuguo
Abstract756)      PDF (2973KB)(250)      
For the problem of erosion-corrosion in oil pipeline system, used ANSYS FLUENT software, by changed the inlet velocity, the particle mass flow rate and the particle diameter, conducted numerical simulation for flow field distribution and severe erosion area of 90° elbow pipe. The results show that: with the increase of inlet velocity, the pipe erosion rate increases gradually; with the increase of particle diameter, the pipe erosion rate decreases; with the increase of particle mass flow rate, the pipe erosion rate increases linearly; and there have interaction between the three erosion factors of inlet velocity, particle mass flow rate and particle diameter.
2018, 38 (02): 47-51. DOI: 10.3969/j.issn.1672-6952.2018.02.010
Error Analysis of Residual Strength Assessment Methods for Pipeline with Volume Defect
Quan Dongyu, Wang Weiqiang, Sun Shaoyang
Abstract485)      PDF (1915KB)(218)      
The five common methods used residual strength assessment for oil and gas pipeline were studied.By comparing the results calculated by strength assessment equations and measured by blasting experiments, the calculation error of these equations were obtained.Then the error distribution interval was analyzed.The results showed that the equation of Modified B31G was less conservative than Origin B31G.Allowable stress method and PCORRC equation had the better evaluation results.The evaluation equation given by API 579-1 standard also had the problem of too-conservative evaluation results.For the different grade pipeline steels, the evaluation effects of the same evaluation equation were different.
2018, 38 (02): 52-56. DOI: 10.3969/j.issn.1672-6952.2018.02.011
Application of Dow Chemistry Method in Safety Evaluation of Styrene Tank Farm
Lü Zongyang, Wang Yue, Liao Zihan
Abstract779)      PDF (1456KB)(314)      
The safety of styrene tank farm whose harm was serious was evaluated by Dow Chemistry Method. According to the actual situation of tank farm, the typical storage tanks to be evaluation units were selected, then the risk coefficient of technologies was analyzed, and the fire-explosion index, exposure radius and regions were calculated. The fireexplosion index and class could be effectively reduced by some safety measures compensating. The results showed that this method could comprehensively and effectively evaluate the potential fire and explosion hazards in the styrene tank farm.
2018, 38 (02): 57-60. DOI: 10.3969/j.issn.1672-6952.2018.02.012
Application of Fuzzy Accident Tree Method in Safety Evaluation of Hydrocracking Unit
Zhao Chuanqi, Zhang Juwei, Zhang Yuanyuan, Wangchen Yushu
Abstract558)      PDF (1930KB)(176)      
The probability of a number of basic events itself was uncertain and fuzzy when the traditional FTA method was used in the practical quantitative analysis quite. It was difficult to obtain the exact probability from failures, which violated the premise of exact probability selected. In order to solve the traditional fault tree analysis (FTA) of the probability the basic event fuzzy and uncertain problems, the concept of fuzzy theory were introduced, and the fuzzy probability was used to deal with the basic events lack of statistical data. The basic events of fuzzy probability were described by using a clear triangular fuzzy number, the fuzzy probability distribution of top event layer by layer was obtained, and the fuzzy importance of each basic event was determined by using fuzzy numbers value method. And the sort of top event of failure factors was obtained, the main factors influencing the accident were identified and effective measures from fundamentally preventive and the key points to control the top event were proposed.
2018, 38 (02): 61-65. DOI: 10.3969/j.issn.1672-6952.2018.02.013
Analysis of Weld Microstructure and Low Temperature Impact Toughness of 07MnNiCrMoVDR Steel
Lin Yang, Tang Yingchun, Zhu Jian
Abstract547)      PDF (3665KB)(190)      
High strength low alloy 07MnNiCrMoVDR steel was welded by using shielded metal arc welding to form welded joint, weld microstructure observation, fracture surface analysis and low temperature impact toughness were operated to research weld microstructure and low temperature impact toughness. The results showed that weld microstructure was consisted of pre-eutectic ferrite along grain boundary, intragranular acicular ferrite and granular bainite, the acicular ferrite presents redial growth by micro-inclusions. The impact absorbing energy of different weld metal site gradually declined tendency with the depth increasing, and the toughness losses were by 67% in the region of half thickness compared with that of surface location. The impact absorbing energy of weld metal gradually declined tendency with the temperature reducing in the region of a quarter of thickness, and the impact absorbing energy was up to requirements at -40 ℃;The impact fracture of weld metal characterized by concavo convex was changed into flat and smooth with the temperature decreased, and the miro-morphology of fracture was changed form the dimple pattern to rive pattern
2018, 38 (02): 66-70. DOI: 10.3969/j.issn.1672-6952.2018.02.014
Fault Dependency Detection Method Based on Random Occurrence of Fault Signal
Wang Guoliang, Yi Chenglong
Abstract483)      PDF (3143KB)(282)      

This paper focuses on the fault detection of a class of discrete-time systems with random faults and proposes a fault-dependent approach. Firstly, a mathematical model is constructed to describe the above problems, and the characteristics of fault signals are transformed into matrices containing uncertainties. By constructing a fault detection filter as a residual generator, the fault detection and isolation (FDI) problem is transformed into a Hfiltering problem. Based on the established model, the  Hperformance is analyzed by adopting a fault-dependent method. The parameter-dependent Lyapunov function is selected for processing. On this basis, the existence condition of the fault detection filter is given in the form of linear matrix inequalities. Finally, an example is used to verify the effectiveness and practicability of the theoretical results.

2018, 38 (02): 71-79. DOI: 10.3969/j.issn.1672-6952.2018.02.015
Research on the Integrity Detection of Aluminum Foil Sealing Based on Infrared Imaging Technology
Zhao Shilong, Li Weijun, Shi Chengjiang
Abstract1021)      PDF (5658KB)(265)      
A method for detecting the integrity of aluminum foil seals with high detection accuracy and high detection efficiency is proposed.First of all,in order to obtain the infrared image of the sealing part aluminum foil,the method has adopted the infrared imaging technology.Then,the infrared image is preprocessed and the feature is extracted by circular symmetric Gabor wavelet.Lastly,KNN is used to identify and classify the acquired imaging.Experiments show that the circular symmetric Gabor wavelet used by this sealing detection method has higher recognition rate and faster algorithm than the traditional Gabor transform algorithm, and provides technical assurance for the automatic screening and rejection of defective sealing products in the subsequent aluminum foil sealing production line.
2018, 38 (02): 80-84. DOI: 10.3969/j.issn.1672-6952.2018.02.016
Research on Path Planning of Welding Robot Based on GA-PSO Algorithm
You Tian, Zhang Wei, Ge Linlin
Abstract638)      PDF (2661KB)(222)      
Welding robots have a wide range of applications in manufacturing industries. There are usually many welded joints in the welding task, and a reasonable welding path passes through these welded joints has a significant impact on the welding efficiency. Traditional manual path planning techniques can handle a small number of welded joints effectively, but when the number of welded joints is large, it is difficult to obtain the optimal path. The traditional manual path planning method is also time consuming and inefficient, and cannot guarantee optimality. Genetic algorithmparticle swarm optimization (GA-PSO) is based on the advantages of genetic algorithm (GA) and particle swarm optimization (PSO) to solve the welding robot path planning problem. The simulation results indicate that the algorithm has strong searching ability and practicality and is suitable for welding robot path planning.
2018, 38 (02): 85-89. DOI: 10.3969/j.issn.1672-6952.2018.02.017
Complexity Analysis of Lotka-Volterra Differential Algebraic Model with Competitive Population
Niu Hong,Wang Yidan,Wang He
Abstract539)      PDF (1417KB)(389)      
The Lotka-Volterra predator-prey biological model is mainly studied in this paper by introducing the new population which has no ability to prey the other population to form a simple competition between predator and prey when the number of predators is excessive. Based on above condition, differential algebraic biological model is established according to the conservation. Then, the stability of biological model is discussed when the parameters change in a certain range by applying the stability analysis method and the related criteria of differential algebraic system. Finally, the model is the simulated numerically by considering the results of the analysis and using the Matlab software, and the simulation results show that the system has a limit cycle when the parameters vary a certain value, which proved that the complex nonlinear phenomena exist in the differential algebraic biological model.
2018, 38 (02): 90-93. DOI: 10.3969/j.issn.1672-6952.2018.02.018
Investigation on Practice about the Construction and Service of Open Ereas in Liaoning Province
Chen Qinghe, Zhang Minghui, Wang Zhipeng
Abstract560)      PDF (2043KB)(199)      
According to the background of views on further strengthening of the urban planning and construction promulgated by the state council, the new open area of the status quo was explored at home and abroad in recent years. And four typical residential areas in A city were taken as examples, combined with investigation in A city, and the pros and cons of the open area were preliminary analyzed. And by using the simulation software to simulate plot open, a variety of factors under the condition of MATLAB mathematical model was established. And before and after the impacts on the surrounding area in the open were quantitatively compared. According to the results, and puts forward the following suggestions: Building the open district should adhere to the peoplecentered principle, should from the laws and regulations, regulatory system, social environment and other aspects to obtain, reasonable planning and construction of the community. The results can provide reference for the construction and management of open community in A city of liaoning province.
2018, 38 (02): 94-98. DOI: 10.3969/j.issn.1672-6952.2018.02.019
Abstract242)      PDF (1089KB)(175)      
2018, 38 (03): 0-.
Progress in Research on Glass Forming Ability of Metallic Glasses
Wu Nianchu,Wang Yong
Abstract545)      PDF (2433KB)(253)      
Metallic glasses were potentially industrial materials due to their excellent properties, such as high specific strength and high corrosion resistance. However, glass-forming ability (GFA) limited their applications greatly. Some key theories and parameters associated with GFA of metallic glasses were reviewed, expecting present new insights and developing bulk metallic glasses.
2018, 38 (03): 1-06. DOI: 10.3969/j.issn.1672-6952.2018.03.001
Electrochemical Behavior of Water Soluble Nitrogen Containing Calixarene
Yang Haiquan,Chen Ping
Abstract513)      PDF (4406KB)(158)      
The calix[4] arene Mannich base was synthesized and characterized by nuclear magnetic resonance. The electrochemical behavior of compound a 1(An acidic salt of the calix[4] arene Mannich base (dimethylamine))and compound b 1(An acidic salt of calix[4] arene Mannich base (diethylamine))was studied by cyclic voltammetry, single potential step time current method, time keeping method and conventional pulse polarography (voltammetry) with CH 3COOH—CH 3COONa as buffer solution. The result shows that there is an irreversible oxidation peak in a scan potential of -0.5 V to 1.5 V. The oxidation peak potentials are 0.92 V and 0.89 V respectively. The peak current and peak potential of the oxidation peak are linear with the scanning rate. The formation of oxidation peak is controlled by diffusion. The activation energy of the reaction is 11.62 kJ/mol and 13.35 kJ/mol respectively.
2018, 38 (03): 7-12. DOI: 10.3969/j.issn.1672-6952.2018.03.002
Catalytic Acetylation of Anisole with Ce- β/MCM-41
Liu Han,Li Huipeng,Zhao Hua,Jiao Lei
Abstract657)      PDF (2171KB)(176)      
With CTAB as template, the β/MCM-41 micro-mesoporous composite molecular sieve has been synthesized by self-assembly of the zeolite structure fragments and the structural units obtained by alkali-treated β zeolite, and the effects of the alkali solution concentration, CTAB dosage in the synthesis process of β/MCM-41 was investigated. The β/MCM-41 composite molecular sieve with well long-range order can be synthesized under the optimum conditions: The solution concentration of NaOH is 1.5 mol/L and the mass fraction of CTAB is 10%. Then the Ce- β/MCM-41 composite molecular sieve doped skeleton with rare earth metal Ce was synthesized and the effect of Ce doping amount (Ce/ β=0.03, 0.08) on Ce- β/MCM-41 was investigated. The result shows that the 0.03-Ce- β/MCM-41 had a well long-range order. The effect of acetylation reaction conditions on the yield of p-MOAP was investigated by using 0.03-Ce- β/MCM-41 as a catalyst in a fixed bed. The single-factor experiments showes that the 4.0 h p-MOAP yield is 58.6% under the conditions: The velocity of the reactants flow is 65 mL/h, the LHSV is 6.5 h -1, reaction temperature is 140 ℃ and n(AN)/n(AA)=6.0.
2018, 38 (03): 13-18. DOI: 10.3969/j.issn.1672-6952.2018.03.003
Development of a Type of Polymeric Mannich Bases
Zhang Shouqing,Huang Wei,Li Fei,Cong Yufeng,Zhang Xiaolin
Abstract719)      PDF (2250KB)(240)      
A new type Mannich base was developed by the reaction of binary copolymer AM/C 9 synthesized from C 9 petroleum fractions with acrylamide as raw materials. The effects of reaction time, reaction temperature, pH of solution and ratio of aldehyde were studied. The apparent viscosity of Mannich was characterized by IR spectroscopy and its structure is characterized. Finally, the performance of the product is analyzed. The results show that the optimum reaction conditions were as follows: The reaction time is 4 h, the reaction temperature is 70 ℃, the pH is 9 and the ratio of dimethylamine to formaldehyde was 1.5. The result of infrared spectrum characterization shows that the product has been synthesized. Synthetic Mannich base has higher viscosity, temperature and salt tolerance compared with traditional HPAM.
2018, 38 (03): 19-22. DOI: 10.3969/j.issn.1672-6952.2018.03.004
Study on without Natural Gas Start-up Alternatives for Daxie Petrochemical Distillate Project
Wang Shiwen,He Shengru,Zhou Yi,Li Wei
Abstract744)      PDF (5847KB)(288)      
The natural gas project supported by CNOOC Ningbo Daxie Petrochemical Co., Ltd. distillate comprehensive utilization project was not synchronized with the start of the project due to external reasons, and there was a risk of lagging behind the start of the project. Starting with the difficulties faced by the start-up process, this study uses propane purchased from outside, self-produced liquefied gas, DCC-produced propane as an alternative medium for natural gas and raw materials for hydrogen production, and adds vehicle propane as the carburetor and LPG tank area to the hydrogen supply process. In the reforming and wax oil hydrogenation installations, 2×5 t/h and 5 t/h liquid hydrocarbon carburetors were added separately to achieve the start of natural gasfree operation, and optimization suggestions were made for the design of the fuel gas pipeline network for refineries.
2018, 38 (03): 23-28. DOI: 10.3969/j.issn.1672-6952.2018.03.005
Progress in Photoinduced Atom Transfer Radical Polymerization
Cui Haiqing,Cui Ye,Liu Furui,Lei Liangcai,Li Haiying
Abstract1128)      PDF (1824KB)(289)      
Photoinduced ATRP is a controlled radical polymerization in the presence of UV/visible light and can be used to synthesize functional polymer materials which can control the molecular structure. The polymerization kinetics was studied by changing illumination time, intensity and frequency of the light source. The amount of transition metal catalyst in photo-induced ATRP polymerization is reduced to less than 100 μg/g, which makes industrial application of controlled free radical technology possible. In this paper, the research progress of direct/indirect light-induced atom transfer radical polymerization (ATRP) is reviewed from the aspects of light source, catalyst, ligand and initiator.
2018, 38 (03): 29-34. DOI: 10.3969/j.issn.1672-6952.2018.03.006
Research Progress in the Nature of Adsorption and Diffusion on Molecular Sieve
Xia Jiajia,Zhou Ming,Li Tiansong,Wang Xiaoning,Liu Shu,Cui Chang
Abstract693)      PDF (2159KB)(683)      
The paper introduces the structure and composition of zeolite molecular sieves, and it elaborates the property of zeolite molecular sieves. In this paper, the performance of the adsorption and diffusion of substances in zeolite molecular sieves is reviewed, and the paper lists the main methods of measuring the performance of molecular sieve's adsorption and diffusion coefficients. It also introduces the adsorption and diffusion of different types of molecular sieves. In the present study, each method of measuring the adsorption performance of zeolite molecular sieves has certain applicable conditions. Due to the difference of measurement mechanism, boundary conditions and assumptions, the diffusion coefficients obtained by different methods are also different. Therefore, the appropriate measurement method will be selected according to the actual experimental situation. As different molecular sieves have different substrates suitable for adsorption, it has different application values.
2018, 38 (03): 35-39. DOI: 10.3969/j.issn.1672-6952.2018.03.007
Synthesis of MEH-PPV under Mild Conditions and the Control of Relative Molecular Mass Control
Shang Yang,An Huiyong,Tang Chaoyong,Ding Xiaoguang,Guo Shilin,Yu Fang
Abstract698)      PDF (2221KB)(258)      
The MEH-PPV electroluminescent materials were synthesized by the dehalogenation condensation method using potassium t-butoxide as the catalyst and tetrahydrofuran as the solvent. The effects of reaction temperature, reaction time, catalyst, solvent and other conditions were studied in details. The synthesis of MEH-PPV requires no heating and the yield is good when THF as the solvent in room temperature. And no gelation appeared during the reaction. The relative molecular mass of MEH-PPV could be controlled well by adding p-methoxyphenol in the reaction system.
2018, 38 (03): 40-43. DOI: 10.3969/j.issn.1672-6952.2018.03.008
Optimization and Economic Evaluation of Buried Hot Oil Pipeline's Thermal Insulation Layer
Yang Ling,Ma Guiyang,Luo Xiaohu,Wang Linjiao,Li Wei
Abstract574)      PDF (9988KB)(242)      
The objective optimization function was set by the summary of the insulation materials' annual sharing cost and the annual heat losing cost after insulation and the calculating model of buried hot oil pipelines' insulation economical thickness was given. The model included the burying depth's influences on around pipelines ambient temperature, the heat transfer coefficient of the outer wall insulation, and the overall heat transfer coefficient. With the help of C# programming language, a computer program was developed to optimize the thickness of insulation layer of buried hot oil pipeline with EXCEL to work out economic evaluation procedures, combining with examples of calculation. The results showed that: The determination of buried hot oil pipeline insulation thickness would have some impact on the economic benefits of the project, and it should take the double requirements into account determining the thickness on both technology and economy. That could provide a theoretical reference to the hot oil transportation construction's optimizing design.
2018, 38 (03): 44-50. DOI: 10.3969/j.issn.1672-6952.2018.03.009
Study on the Optimization of Storage and Transportation Logistics System for Transfer Oil Terminal
Wang Xiao,Li Qiandong,Sun Guorui,Liu Dejun,Zheng Ping
Abstract647)      PDF (2681KB)(348)      
Optimizing the storage and transportation logistics system focus on the optimization of the oil supply chain. It is necessary to take into account the cost of each link in the process of oil logistics, and to formulate the optimization scheme according to the actual needs of the enterprise itself. Based on the related theories of oil storage and logistics, combined with practical production situation of a transfer oil terminal, the existing storage and transportation facilities, such as tanks, cranes and loading systems, are optimized and integrated, and mathematical models are established to optimize the distribution and transportation problems so as to reduce operating costs and bring more economic benefits for the enterprises.
2018, 38 (03): 51-56. DOI: 10.3969/j.issn.1672-6952.2018.03.010
Method and Practical Analysis of Oil and Gas Long Distance Pipeline Leak Detection
Tong Chang,Wang Weiqiang,Chen Boyu
Abstract774)      PDF (1101KB)(437)      
With the rapid development of national economy in our country, the demand of oil and gas, as a representative of the major energy, continued to increase, and the security risks of long distance oil and gas pipelines also caused people's attention. Especially, the pipeline leakage deflagration happened from time to time in recent years, which caused not only great economic losses of the people's lives and property, also caused the ecological environment pollution and destruction. Therefore the leak detection of intelligent and efficient positioning method was applied to oil and it was critical for gas pipelines in a timely manner to prevent secondary disasters. The main cause of pipeline leak was analyzed, several kinds of leak detection methods used on the pipeline at present were summarized, and the method of negative pressure wave and flow balance method was dopt in crude oil pipeline leak detection experiments. The experimental results showed that the method could monitor oil pipeline leak in real time, especially small slow leakage, meanwhile could accurately locate the leak point.
2018, 38 (03): 57-61. DOI: 10.3969/j.issn.1672-6952.2018.03.011
Mixed ModeⅠ-Ⅱ Crack Side-Branching and Kinking when K =K
Zheng Xingyu,Xie Yujun
Abstract529)      PDF (2273KB)(181)      
The mixed mode Ⅰ-Ⅱ crack propagation behaviors when K =K were studied based on the geometrical modeling for stress singularity boundary multi-direction cracking, the energy release rate and the energy-based driving force of crack side-branching and kinking had been established, and the critical initiation angle or the critical stress intensity factor had also been calculated. The prediction of critical crack kinking angle by the present theory had a good agreement with 2024-T3, and the deviation was estimated to be 8.9% when compared with En3B and Al.
2018, 38 (03): 62-66. DOI: 10.3969/j.issn.1672-6952.2018.03.012
Application of Digraph Weight Elimination and the Treatment of Connection Based on AutoCAD
Lan Xiaomin,Wang Quan,Wang Shengzhi
Abstract599)      PDF (2774KB)(164)      
This paper analyzes the problem of lines duplication, overlap and discontinuity in the application of AutoCAD. And it also proposes a method of automatic elimination of duplication, overlap and discontinuity by using the VisualLISP language embedded in AutoCAD system. After the processing, the engineering drawings can avoid linear problems which do not conformity to the requirements of the national standard, and can also avoid the complex work of manually modifying on the complicated lines. The processing of repetition elimination in sheet cutting diagram is possible to extend the life of the laser cutting head and the cutting accuracy of the spare part. After the computer graphics repeating the eliminate processing, it can effectively improve the recognition rate of computer graphics automatic scoring system.
2018, 38 (03): 67-72. DOI: 10.3969/j.issn.1672-6952.2018.03.013
Fiber of Coalescence Separation Process Flow Field Numerical Simulation Research
Ling Guohua,Huang Liaoyun,Liu Sen
Abstract571)      PDF (10306KB)(165)      
A numerical study was conducted for the research of the fiber coalescence separation flow field.The results show that the pressure field of the fiber coalescence separator shows a slowly decreasing distribution from front to back. The pressure decreases with the increase of thickness. The coalescence pressure drop increases linearly with the increase of flow velocity and thickness. With the increase of porosity, the velocity distribution of the fiber coalescence separator is symmetrical. When the fluid flows into the fiber layer, The maximum velocity occurs in the fiber gap. The distribution of velocity in the fiber gap presents a “M” shape.
2018, 38 (03): 73-78. DOI: 10.3969/j.issn.1672-6952.2018.03.014
Analysis of the Flow Rule of Rubber Melts in the Expansion Dryer
Wu Xianwei,Deng Zilong,Guo Yuquan,Luo Lin
Abstract632)      PDF (4890KB)(150)      
The expansion dryer was the critical equipment for the finishing unit of rubber plant. It could take off 90% moisture in the rubber melt. The flow behavior of rubber melts in the channel of the expansion dryer was analyzed by FLUENT. Observing the nephogram of the distribution of rubber melts speeds and stress nephogram, the flow rule of rubber melts in the expansion dryer was analyzed. The following research directions were indicated.
2018, 38 (03): 79-83. DOI: 10.3969/j.issn.1672-6952.2018.03.015
Prediction of Mini Zone Bathtub Shape Fire Accidents
Zhang Yuanyuan, Liu Xiaopei, Shi Meijing
Abstract472)      PDF (2405KB)(183)      
Because there is a large error defect of predicting the severe fluctuating fire data by traditional grey forecasting model, the article expends the original data sequence of grey prediction model using Taylor formula and expends Lagrange type remainder, which modified the traditional grey forecasting model and improved the traditional grey prediction algorithm. The article used Matlab software to program, and used the traditional gray prediction algorithm and improved gray prediction algorithm,respectively.Then the article selected three sets of data to predict aiming at the mini zone bathtub shape fire accident. As the results show that: modified grey forecasting model prediction curve gives satisfactory accuracy comparing to the characteristic of bathtub curve, which has a high consistency with the original data.And the poor quality, large error and low accuracy is improved. Compared with the traditional grey prediction model, the error of the improved grey prediction model has reduced 86.59%, 55.32%, and 55.70%, respectively. The prediction results of the improved grey prediction model can meet the requirements in three aspects: accuracy, relative error and correlation.
2018, 38 (03): 84-88. DOI: 10.3969/j.issn.1672-6952.2018.03.016
Fault Test and Diagnosis of Rolling Bearing Based on  Acoustic Emission Waveform Streaming Signals
Chen Xiaolong,Zhou Junpeng,Zhang Ying,Fan Ruixiao
Abstract581)      PDF (3547KB)(271)      
Acoustic emission waveform streaming testing technology was adopted to collect acoustic emission waveform streaming signals of rolling bearings under normal conditions and in the case of the failure of outer race, inner race and roller. The relations between frequency characteristics and the signals of acoustic emission waveform streaming were analyzed. Envelope spectrum analysis was adopted to acquire the peak frequency of acoustic emission waveform streaming signals, comparing with the theoretical value of the inherent characteristic frequency of the rolling bearings, under the condition of different faults. The experimental data show that envelope analysis can be carried out for the study of acoustic emission waveform streaming signals of rolling bearing with different kinds of faults and the early diagnosis of rolling bearings with different faults can be realized.
2018, 38 (03): 89-92. DOI: 10.3969/j.issn.1672-6952.2018.03.017
Cross-Talk Free Image Encryption and Watermarking by  Digital Holography and Random Composition
Qi Jun, Liu Changhong, Zhang Wei
Abstract635)      PDF (6897KB)(125)      
In previous image watermarking methods, an encoded host image and a watermark image are usually directly added.Therefore, the two images have cross-talk in the decryption step.In order to eliminate this effect,a new method based on digital holography interferometry is proposed,in which all the image pixels of the two sets of holograms resulted from two hidden images are rearranged and integrated into one set of composite holograms with a random scattering matrix (RSM).In decryption the use of this matrix can ensure the exact retrieval of each hologram,and then the perfect reconstruction of each image without cross-talk noise can be achieved.In the decryption process, the use of RSM can ensure the accurate recovery of each holographic image, so as to achieve a perfect reconstruction of no crosstalk noise in each image. The computer simulation is performed using phase-shift interference and double random phase encoding techniques to verify the feasibility of the method , its robustness to occlusion and additional noise.this method is suitable for 2D and 3D images, and the additional RSM can also provide a higher level of security as a key.
2018, 38 (03): 93-98. DOI: 10.3969/j.issn.1672-6952.2018.03.018
Abstract159)      PDF (1077KB)(160)      
2018, 38 (04): 0-.