Synthesis of Cyclohexyl Propionate Catalyzed by Iodine

Journal of Liaoning Petrochemical University ›› 2005, Vol. 25 ›› Issue (2): 39-41.

Previous Articles Next Articles

Synthesis of Cyclohexyl Propionate Catalyzed by Iodine

School of Petrocheminal Technology , Liaoning University of Petroleum & Chemical Technology ,
Fushun Liaoning 113001 , P .R .China

Received:2004-10-29 Published:2005-06-20 Online:2017-04-18

碘催化合成丙酸环己酯

刘春生, 张晓丽, 何　淼, 周海霞, 罗根祥

辽宁石油化工大学石油化工学院, 辽宁抚顺113001

作者简介:刘春生(1970 -), 男, 安徽安庆市, 实验师。

Abstract

Abstract:

The acylation of cyclohexanol with propionic anhydride was studied by using iodine catalyst .The effects of different factors such as reaction time , the mole ratio of cyclohexanol to propionic anhydride , the mass of catalyst on the yield of cyclohexyl propionate were investigated.The results show that the best of reaction conditions are as following :0.1 mole cyclohexanol , the mole ratio of cyclohexanol to pro pionicanhydride is 1.1∶1 and the mass of catalyst is 0 .08 g ram .After reacting 40 minutes under refluxing , the yield of cyclohexyl propionate reaches 92 .2 %.The product is colorless and transparent .The purity of product is 98.7 %.The reaction was repeated five times.It is shown that the catalyst exhibit a good catalytic activity .The advtanges of the reaction are mild conditions, shorter reaction time and easy manipulation .The product was characterized by refractive index and IR.

Key words: Cyclohexyl propionate , Synthesis , Iodine , Catalysis, Acylation

摘要： 　以碘为催化剂, 对环己醇与丙酸酐之间的酰化反应进行了研究, 考察了反应时间、酐醇摩尔比、催化剂质量对丙酸环己酯收率的影响。实验结果表明, 当环己醇的物质的量为0 .1 mol, 酐醇摩尔比为1.1∶1 时, 催化剂质量为0.08 g , 回流反应40min 后, 丙酸环己酯收率可达到92 .2 %, 且所得产品无色透明, 纯度为98 .7 %。重复实验5 次表明催化剂具有良好的催化活性。合成反应条件温和, 反应时间较短, 操作简便。同时对产品的折光率和红外光谱进行了表征。

关键词: 　丙酸环己酯, 　合成, 　单质碘, 　催化, 　酰化

LIU Chun -sheng,ZHANG Xiao -li,et al. Synthesis of Cyclohexyl Propionate Catalyzed by Iodine[J]. Journal of Liaoning Petrochemical University, 2005, 25(2): 39-41.

刘春生, 张晓丽, 何　淼, 等. 碘催化合成丙酸环己酯[J]. 辽宁石油化工大学学报, 2005, 25(2): 39-41.

[1]	Hua WANG, Xin WANG, He WANG, Mingdong ZHOU, Lei LI. Ruthenium (Ⅱ)⁃Catalyzed Coupling Reaction of 1⁃Phenyl⁃2⁃Pyrazolin⁃5⁃One with Ethylene Carbonate [J]. Journal of Liaoning Petrochemical University, 2023, 43(6): 11-16.
[2]	Ru Jia, Lihua Li, Xiaojie Gong. Study on Catalytic Reduction of p⁃Nitrophenol by Modified UiO⁃66 [J]. Journal of Liaoning Petrochemical University, 2023, 43(4): 14-18.
[3]	Xiangyu Ren, Baokuan Chen, Jing Sun, Yanfeng Bi. Double Polyoxometalates⁃Based Metal⁃Organic Framework with Photocatalytic Degradation Properties [J]. Journal of Liaoning Petrochemical University, 2023, 43(4): 51-58.
[4]	Shuaikang Chang, Chuang Liu, Kunchen Li, Bo Li, Fangfang Wang, Caiyun Lu, Changdong Chen. Preparation of TiO₂ Mesocrystals by Topochemical Conversion and Their Performance [J]. Journal of Liaoning Petrochemical University, 2023, 43(1): 27-31.
[5]	Chun Kang, Huiqiang Ma, Shuang Li. Fe⁃Doped g⁃C₃N₄ Photocatalytic Activation of Persulfate for Degradation of Azo Dyes [J]. Journal of Liaoning Petrochemical University, 2022, 42(5): 13-17.
[6]	Changdong Chen, Zhe Li, Ke Li, Jinying Cong, Yuhang Yang, Fangfang Wang. Topological Transition Synthesis and Properties of TiO₂ Homogeneous Materials [J]. Journal of Liaoning Petrochemical University, 2022, 42(3): 37-41.
[7]	Shuang Xi, Rui Wang. Synthesis of Indole Analogues Based on 1,3⁃Cyclohexanedione Building Blocks [J]. Journal of Liaoning Petrochemical University, 2022, 42(2): 23-29.
[8]	Xian Chen, Chang Liu, Ying Wang, Lei Guan, Pengpeng Yin, Xuejia Xiong, Hongzhe Jin. Syntheses, Structures and Fluorescent Properties of Two Co/Ni Complexes with Nitrogen⁃Donor Ligands [J]. Journal of Liaoning Petrochemical University, 2021, 41(6): 15-19.
[9]	Chang Liu, Jing Sun, Mingdong Zhou. Visible⁃Light Promoted Direct Acylation Reaction of Pyridine N⁃Oxides [J]. Journal of Liaoning Petrochemical University, 2021, 41(6): 20-24.
[10]	Jie Li, Kexin Fang, Lizhu Yao. Preparation and Photocatalytic Degradation Rhodamine B Properties of CNTs/Bi₁₂O₁₇Cl₂ Photocatalyst [J]. Journal of Liaoning Petrochemical University, 2021, 41(6): 42-47.
[11]	Yuke Liu, Fei Yan, Jing Sun, Mingdong Zhou. Copper⁃Catalyzed Synthesis of a Long Alkyl Branched Fatty Alcohol [J]. Journal of Liaoning Petrochemical University, 2021, 41(4): 17-21.
[12]	Huaichuan Shi, Lei Shi. Preparation and Photocatalytic Properties of Nanocarbon Particles/Carbon Nitride [J]. Journal of Liaoning Petrochemical University, 2021, 41(4): 41-45.
[13]	Yongkai Pan, Yunrong Chen. Advances in Asymmetric Catalytic Synthesis of Chiral Oxazolines [J]. Journal of Liaoning Petrochemical University, 2021, 41(4): 9-16.
[14]	Fan Yijun， Liu Zhibo， Yu Fang. Synthesis of Intermediate of Natural Product of CytochalasinPericoannosins C-F [J]. Journal of Liaoning Petrochemical University, 2021, 41(3): 23-27.
[15]	Wang Xiaodi， Li Lihua， Zhang Jinsheng， Wu Xian， Ma Cheng. Preparation of MnFe₂O₄/TiO₂and Its Fenton⁃Like Photocatalytic Properties [J]. Journal of Liaoning Petrochemical University, 2021, 41(2): 32-36.

Synthesis of Cyclohexyl Propionate Catalyzed by Iodine

碘催化合成丙酸环己酯

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics