Recent Advances in the Catalytic Application of Sulfonic Acid Functionalized Ionic Liquids

doi:10.3969/j.issn.1672-6952.2016.03.001

Journal of Liaoning Petrochemical University ›› 2016, Vol. 36 ›› Issue (3): 1-7.DOI: 10.3969/j.issn.1672-6952.2016.03.001

Recent Advances in the Catalytic Application of Sulfonic Acid Functionalized Ionic Liquids

Guo Ya’nan, Guo Fangjie, Chen Ping

College of chemistry and material Science Engineering，Liaoning Shihua University，Fushun Liaoning 113001, China

Received:2016-04-18 Revised:2016-05-10 Online:2016-06-25 Published:2016-07-01

磺酸功能化离子液体用于催化反应的最新进展

郭亚楠,郭芳杰,陈平

(辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001)

通讯作者: 陈平(1963-),女,博士,教授,从事有机绿色催化研究;E-mail:1447292926@qq.com。
作者简介:郭亚楠(1991-),女,硕士研究生,从事离子液体合成及其催化性能的研究;E-mail:1045286719@qq.com。
基金资助:
国家自然科学基金项目(21071073);辽宁省自然科学基金项目(2015020196)

Abstract

Abstract:

Sulfonic acid functionalized ionic liquid is a type of Bronsted acid (B acid) ionic liquid with one or more sulfonic group (—SO₃H) introduced into the organic cation or the anion. This type of ionic liquid shows strong acidity，high polarity and intense activity. In this paper, the synthesis of sulfonic acid functionalized ionic liquid is reviewed, and the application in many kinds of organic catalytic reactions is also described in details. Moreover, the perspectives of sulfonic acid functionalized ionic liquid has been discussed.

Key words:

Sulfonic acid functionalized ionic liquid, Catalysis, Acylation, Esterification, Applicationmso-ascii-font-family: Calibri, mso-ascii-theme-font: minor-latin, mso-fareast-font-family: 宋体, mso-fareast-theme-font: minor-fareast, mso-hansi-font-family: Calibri, mso-hansi-theme-font: minor-latin">

摘要： 磺酸功能化离子液体是指在有机阳离子中引入一个或多个磺酸基(—SO₃H),或者阴离子为磺酸的Brönsted(B酸)型离子液体,其酸性强、极性大、活性高。简要介绍了磺酸功能化离子液体的合成方法,详细阐述了在多种有机催化反应中的应用,展望了磺酸功能化离子液体的发展前景。

关键词: 磺酸功能化离子液体, 催化, 酰化, 酯化, 应用

Guo Ya’nan, Guo Fangjie, Chen Ping.

Recent Advances in the Catalytic Application of Sulfonic Acid Functionalized Ionic Liquids[J]. Journal of Liaoning Petrochemical University, 2016, 36(3): 1-7.

郭亚楠,郭芳杰,陈平. 磺酸功能化离子液体用于催化反应的最新进展[J]. 辽宁石油化工大学学报, 2016, 36(3): 1-7.

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Recent Advances in the Catalytic Application of Sulfonic Acid Functionalized Ionic Liquids

磺酸功能化离子液体用于催化反应的最新进展

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