For air⁃water⁃air⁃water⁃water⁃anion exchange resin system, the effects of solid loading, particle size, separator and different guide tube forms on mass transfer coefficients were studied in an airlift cyclone reactor (HALR) with a volume of 130 L (inner diameter 290 mm and height 2 000 mm) and an apparent gas velocity of 0~0.84 cm/s. The results showed that the volumetric mass transfer coefficients of the three phases system were larger than the two phases. As the particle size increased, the volumetric mass transfer coefficients decreased. The volumetric mass transfer coefficients with the solid separator was a little bigger than the none of separator.The volumetric mass transfer coefficient of the finned draft tube was the largest when the superficial gas velocity was small.

The slurry bed hydrogenation was studied using vacuum residue from CNOOC Huizhou Refining & Chemical as raw material. The effects of reaction temperature, hydrogen partial pressure, catalyst mass fraction and airspeed on the conversion rate and the yield of each product were investigated in slurry bed hydrocracking reactor of independent research and development. The results showed that under the optimal reaction conditions of reaction temperature 460 ℃, hydrogen partial pressure 14 MPa, hydrogen oil volume ratio 1 000∶1, catalyst mass fraction 300 μg/g and space velocity 1.0 h ^-1, the residue conversion rate was 90.50%, The coke rate was 5.01%. At the same time, the reaction mechanism and the coking mechanism of the hydrogenation reaction of the suspended sediment were analyzed, which provided theoretical guidance and technical support for the industrialization of the hydrocracking technology.

The nanometer autonomous vehicle assembly MoNiP hydrogenation catalysts were prepared by homogeneous precipitation using thiourea as precipitant matrix and citric acid as complexing agen. The catalysts were characterized by BET, NH3TPD, FTIR spectra of CO adsorbed and XPS. The results of BET and FTIR spectra of CO showed that when the content of thiourea was 40%, catalytic performance of the catalyst was best. The homogeneous precipitation catalyst achieved the desulfurization rate of 95.3% which was higher than the reference catalyst by 1.7%.

A new diesel pour point depressant (PPD) was synthesized using αmethacrylic acid ester, maleic anhydride, and styrene as raw materials.The results showed that the optimum reaction conditions were as follows: the mass fraction of azodiisobutyronitrile (AIBN) was 0.8%, the mole ratio of αmethacrylic acid ester, maleic anhydride and styrene was 6∶1∶1, the reaction temperature was 80 ℃, and the reaction time was 8 h. Meanwhile, the effect of depressants was best when its mass fraction was 0.1%. At the same time, A, B, and C surface active agent were added into PPD according to the different proportion, respectively. It was found diesel pour point was decreased by 17 ℃ when PPD and B surfactant was compounded with mass ratio of 4∶1.

5(acridin9yl)pentanoic acid was prepared using Nphenylaniline and adipic acid as raw materials by cyclization reaction. Lewis acid and Bronsted acid were chosen as catalysts under the condition of solventfree. The effect of sort of catalysts, reaction time, reaction temperature, the amount of catalysts and the mole ratio of reactants on the yields of final products were investigated. The results showed that the yeild of 5(acridin9yl) pentanoic acid can reach 82.6% under the following experimental conditions:HF with high catalytic activity, the reaction time 6 h, the reaction temperature 60 ℃, 3 times molar ratio of the amount of catalyst to substrate, molar ratio of Nphenylaniline to adipic 1∶3. NMR, MS and elemental analysis were used to characterize the product of 5(acridin9yl) pentanoic acid. The temperature of reaction with HF catalyst was low. The product can be easily seperated and purified with high purity. 

The nanotube array with big specific surfacearea and aperture was prepared by the anodic oxidation. Bmodified MoNiP hydrotreating catalyst with pore diameter of 72.3 nm and specific surface area of 156 m2/g was prepared by the impregnation method，and characterized by mercury intrusion method and XRD. The activity of the novel catalyst was evaluated in a fixed bed reactor using diesel oil of Gudao island as the raw material. The results showed that the desulfurization rates of the products reached 96.6% under the optimum hydrogenation condition as follows: temperature 360 ℃，pressure 7 MPa，volume ratio of hydrogen to oil 600∶1 and space velocity 1.5 h-1．

Cycle stock and inferior catalytic cracking diesel oil with volume ratio 2∶1 were used as crude oil, which was refined by a new type of nano selfassembly catalyst. Orthogonal test was designed to investigate the influence of temperature, space velocity and pressure on HDS,HDN and HDAr. The most significant influence factor on HDS，HDN and HDAr was obtained. Through the representation of BET, it is concluded that multilayer dispersion of nanoparticles on the surface of the catalyst FA1204 was uniformwith average pore diameter 7.7 nm, pore volume 0.26 cm3/g, and specific surface area 132.7 m2/g2 respectively. The results proved that the anti coking performance of FA1204 was better than industrial catalyst F2. The liveness and resistance ability of carbonization of catalyst FA1204 in harsh conditions were compared with industrial catalyst F2 and nano selfassembly catalyst FA2012. The results showed that HDS,HDN,HDAr of the catalyst FA1204 was superior to industial catalyst, the percent conversion of HDS,HDN and HDAr of FA1204 were 66%,34% and 74% respectively, and the percent conversion of HDS,HDN and HDAr of F2 were 40%,24% and 25%,respectively. Therefore, the resistance of coking properties of catalyst FA1204 was superior to catalyst F2. In addition, catalyst FA1204 has a processing capacity of HDAr. 

Adopting secondary nano selfassembly method to prepare macroporous catalyst（0106，1227）with small stacking density and high metal loading， the distribution of pore volume centralized from 30 nm to 100 nm，which accounts for 11%,28%. The first activity of two kinds of nano selfassembly catalyst（0106，1227） was investigated with Zhenhai FCC diesel oil as feed at reaction temperatures of 360 ℃，reaction pressure of 7 MPa，hydrogenoil volume ratio of 600，volume space velocity oh 1.5 h-1 in a fixed bed micro reactor of 10 mL，and with reference agent as a contrast. The experimental results show that the two kinds of nano selfassembly catalyst （0106，1227）has higher activity of hydrodesulfurization，hydrodenitrificationand aromatics saturation than the reference catalyst.The sulfur mass fraction of FCC diesel [ＫＧ*４]oil[ＫＧ*４] feedstock [ＫＧ*４]could [ＫＧ*４]be [ＫＧ*４]reduced from 12 400 μg/g to 483，283 μg/g which the highest desulfurization rate of 96.10% and 9771%;the nitrogen mass fraction of FCC diesel oil feedstock could be reduced from 1 507 μg/g to 35.7，14 μg/g which the highest denitrification rate of 9763% and 9900%; the highest aromatics saturation rate of 67.99% and 68.88%,while only to 537，64.6 μg/g and 9457%，95.54%，6565% over the reference catalyst.

With the method of hydrofluoric acidalkylation(the UOP method), realkylene(C ₁₆C ₁₉) was reacted. By this reaction, the relevant process data was obtained, the alkylation pilot technology was developed, and the underlying industrialized data was provided. When the reaction temperature is 50 ℃, the reaction pressure is 0.88 MPa, reaction time is 20 min, the amount of substance ratio for benzene and heavy hydride olefinic is 8∶1 and the volume ratio for HF and hydrocarbon is 2∶1, the conversion rate can be the best for 10.4%.