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Synthesis of Poly(Butylene Itaconate)
Wang Chuanxing,Xu Qinhong,et al
Abstract
(
741
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386
)
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Poly(Butylene Itaconate) (PBI) was synthesized with itaconic acid (IA) and 1,4-butylene glycol (BOD) by direct esterificationpolycondensation (No.1 method) and stepwise feeding process (No.2 method), respectively. The reaction process of two methods was investigated by determining the acid value, the intrinsic viscosity, the relative molecular mass and its distribution. The results showed that the acid value of synthetic PBI by No.1 method was higher than 40 mg(KOH)/g, the intrinsic viscosity was 8.232 1 mL/g, the molecular weight was 2 889, and the molecular weight dispersion coefficient was 1.614. As for No.2 method of synthetic PBI, the acid value was lower than 39.61 mg(KOH)/g, the intrinsic viscosity was 6.697 3 mL/g, the molecular weight was 2 559, and the molecular weight dispersion coefficient was 1.568. The structure of polyester was confirmed by means of Fourier Transform InfraRed (FT-IR). By comprehensive comparison, stepwise feeding process was the better way to synthesize PBI.
2017, 30 (2): 7-11.
DOI:
10.3969/j.issn.1006-396X.2017.02.002
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Synthesis and Properties of the Unsaturated Polyester
Polyurethane with Lateral Base Double Bonds
Wang Chuanxing, Liu Junkai, Xu Qinhong, Gao Chuanhui, Wu Yumin, Hou Baorong
Abstract
(
684
)
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(2375KB)(
981
)
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With itaconic acid (IA) and 1,4
butanediol (BDO) as the raw materials, the resultant hydroxyl
terminated aliphatic unsaturated polyesters (PBI) were prepared. The unsaturated polyurethane was prepared with PBI as the soft segment and toluene diisocynate (T
DI) as the hard segment. The effect of its reaction conditions on the mechanical properties of the unsaturated polyurethane was also investigated. It was found that the film products with the optimum properties were obtained under the material mass ratio o
f TDI and PBI 1
∶
1.5, the reaction temperature 80
℃
, optimum reaction time 2 h, with dibutyltin dilaurate in an amount of 1% as the catalyst. Combining with benzoyl peroxide in an amount of 1%,as an initiator, the film of the unsaturated polyurethane was smooth, transparent and level. The hardness was 6H, and the adhesion property was A
grade.
2016, 29 (2): 6-12.
DOI:
10.3969/j.issn.1006-396X.2016.02.002
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Fast Algorithm for Computing Analysis Window of Real Discrete Gabor Transforms Based on DCT
XU Qin, TAO Liang
Abstract
(
228
)
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(227KB)(
190
)
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A fast algorithm for computing analysis window of real discrete Gabor transforms based on DCT in order to realize real discrete Gabor transforms efficiently was introduced. The original biorthogonal condition expression of computing analysis window functions was predigested by using the orthogonality of discrete cosine functions, and then divided the original equations set into a set of independent subsystems. Thus this algorithm can save a considerable computation. Some numerical experiments were given to demonstrate the efficiency and advantages of the proposed algorithm. It decreases the computational time compared to the original algorithm.
2008, 21 (4): 87-90.