By confecting simulation corrosion solution of pressuring air cooler system of Maoming Petrification and using CMB-1510B portable instantaneous corrosion rate meter, the experimental inhibition efficiency of organic corrosion inhibitor of Na2Sx and its compound was evaluated.The results show that Na2Sx and its compound are excellent corrosion inhibitor for the corrosion system of reactor effluent air coolers. After compounding with BTA, Na2Sx have attained excellent inhibition effect at little dosage. Moreover, BTA could form protective film on metal surface which prevented depolarizing substances to transfer toward metal surface, and reduced corrosion rate of metal.