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Preparation and Performance Study of PPC/PBAT Composite Materials
Ke YANG, Guangxiang ZHANG, Yuanyuan HAN, Guiyan ZHAO
Abstract9)   HTML1)    PDF (2072KB)(1)      

Blending poly(propylene carbonate) (PPC) with poly(adipate?butylene terephthalate) (PBAT) was involved in the preparation of PPC/PBAT composites. However, the limited compatibility between the two materials hinders the potential performance enhancement of PPC/PBAT composites. To improve the compatibility between PPC and PBAT, maleic anhydride (MA) as a polar monomer and 2,5-dimethyl-2,5-bis(tert-butyl peroxy) hexane (DHBP) as an initiator were chosen for grafting onto PBAT to produce copolymer grafted Maleic anhydride (PBAT-g-MA).The interplay between PPC and PBAT-g-MA, as well as its impact on the properties of the blend, was thoroughly examined. The elongation at break of the blend was found to gradually increase with higher mass fraction of PBAT-g-MA. The elongation at break of PPC/PBAT-g-MA blends increased from 21.2% to 68.1%(60 and 40 are the quality scores of PPC and PBAT-g-MA, respectively). Studies have shown that when the PBAT-g-MA content is lower than that of PPC, PBAT-g-MA functions as a uniformly dispersed phase within the PPC matrix. The anhydride group present in the material can effectively react with the end groups of PPC, thereby significantly enhancing compatibility between both phases and promoting stress transfer at interface layers to improve the mechanical properties of blends.

2024, 37 (5): 73-80. DOI: 10.12422/j.issn.1006-396X.2024.05.009
Synthesis, Modification and Application of Photocatalytic Material Graphite Phase Carbon Nitride
Wenke YANG, Lianxue LU, Peng LI, Jian ZHANG, Shaozheng HU
Abstract783)   HTML29)    PDF (1744KB)(485)      

Graphite phase carbon nitride(g?C3N4), as an environmentally benign semiconductor material, has good application prospects in photocatalysis. However, the disadvantages of pure g?C3N4 such as small specific surface area and difficult separation of photogenerated carriers will limit its photocatalytic performance, which will restrict its large?scale application.From the synthetic methods and modification strategies, the research progress of g?C3N4 photocatalysts by researchers in recent years is reviewed, and the development of g?C3N4 photocatalysts in the fields of degradation of pollutants in water treatment, H2 and H2O2 production is summarised, and it can be found that the performance of the modified g?C3N4 photocatalysts has been greatly improved.Finally,the development direction of g?C3N4 photocatalyst is prospected.

2024, 37 (1): 43-51. DOI: 10.12422/j.issn.1006-396X.2024.01.006