Synthesis of Cyclic Carbonate from Carbon Dioxide Catalyzed by Different Morphologies CeO2

doi:10.12422/j.issn.1006-396X.2023.05.005

Abstract

Abstract:

Different morphology CeO₂ was used as a catalyst to catalyse the synthesis of trimethylene carbonate from CO₂ and 1,3?propanediol.The structure and composition of cerium oxides were characterized by SEM, TEM, XPS and XRD. The results showed that the yield of trimethylene carbonate was up to 72.5% at 130 ℃ for 4 h when using the rod?shaped cerium oxide as catalyst and 2?cyanopyridine as dehydrating agent. R?CeO₂ has a higher number of defect sites and an suitable specific surface area, The average particle size is small and it has moderate number of Lewis acidic sites. Based on this, the substrate range was expanded, and the experimental results showed that both five?membered cyclic carbonates and six?membered cyclic carbonates could be obtained in good yields.

Key words: Carbon dioxide, Cyclic carbonate, Cerium dioxide, 2?Cyanopyridine, Catalyst

摘要：

以不同形貌CeO₂为催化剂，催化CO₂和1，3?丙二醇合成三亚甲基碳酸酯。通过SEM、TEM、XPS和XRD对不同形貌CeO₂的结构和组成进行了表征。结果表明，当以棒状CeO₂为催化剂、2?氰基吡啶为脱水剂，在反应温度为130 ℃、反应时间为4 h时，三亚甲基碳酸酯的收率为72.5%；R?CeO₂具有较多的缺陷位点数量和适宜的比表面积，平均粒径小且具有中等数量的路易斯酸性位点。在此基础上对底物范围进行了拓展，实验结果显示五元环状碳酸酯和六元环状碳酸酯均能得到较好的收率。

关键词: CO₂, 环状碳酸酯, CeO₂, 2?氰基吡啶, 催化剂

CLC Number:

TQ235

Xiaoyu CHEN, Chunrong WANG, Jing SUN, Jingyun WANG, Yang CHEN, Mingdong ZHOU. Synthesis of Cyclic Carbonate from Carbon Dioxide Catalyzed by Different Morphologies CeO₂[J]. Journal of Petrochemical Universities, 2023, 36(5): 38-44.

陈晓雨, 王春蓉, 孙京, 王景芸, 陈阳, 周明东. 不同形貌CeO₂催化CO₂合成环状碳酸酯的研究[J]. 石油化工高等学校学报, 2023, 36(5): 38-44.

Figures/Tables 11

Fig.1 XRD patterms of commercial CeO2, R?CeO2, C?CeO2 and P?CeO2

Fig.2 SEM，TEM and HRTEM images of R?CeO2, C?CeO2 and P?CeO2

Fig.3 XRD patterms of CuO/R?CeO2 and AgI/R?CeO2

Fig.4 SEM, HRTEM and TEM images of CuO/R?CeO2 and AgI/R?CeO2

Table 1 Specific surface area and yield of CeO2 with different morphologies

催化剂	比表面积/（m²·g^-1）	产率/%
市售CeO₂	125.50	28.7
R⁃CeO₂	119.90	72.5
C⁃CeO₂	59.25	27.6
P⁃CeO₂	129.10	66.5

Fig.5 Raman spectra of R?CeO2, C?CeO2, P?CeO2

Fig.6 XPS spectra of R?CeO2, C?CeO2, P?CeO2

Table 2 Geometrical parameters and yields of R?CeO2and composite CeO2

催化剂	比表面积/（m²·g^-1）	平均粒径/nm	产率/%
R⁃CeO₂	119.90	10.9	72.5
CuO/R⁃CeO₂	86.29	11.5	50.6
AgI/R⁃CeO₂	79.96	12.2	17.4

Fig.7 XPS spectra of CuO/R?CeO2 and AgI/R?CeO2

Fig.8 Experimental results of substrate expansion

Fig.9 Recovery and utilization results of R?CeO2

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Synthesis of Cyclic Carbonate from Carbon Dioxide Catalyzed by Different Morphologies CeO₂

不同形貌CeO₂催化CO₂合成环状碳酸酯的研究

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Figures/Tables 11

References 24

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