Research Progress of V2O5 Cathode Material for Sodium⁃Ion Batteries

doi:10.3969/j.issn.1006-396X.2022.06.005

Abstract

Abstract:

Sodium?ion batteries (SIBs) have the advantages of rich resources and low cost and supply risk.Therefore,they are regarded as a new generation of electrochemical energy storage devices with great potential.At present,vanadium pentoxide (V₂O₅) has gradually become a research hotspot of cathode materials for SIBs because of its high working voltage and theoretical capacity. However,the disadvantages of V₂O₅ cathode material,including low ion diffusion coefficient,low conductivity,and structural instability caused by repeated ion intercalation/deintercalation,have limited its application in SIBs.This paper analyzed the crystal structure and sodium storage mechanism of V₂O₅ and summarized the research progress of V₂O₅ cathode material in SIBs through modification methods such as morphology control,crystal structure modification,chemical pre?insertion,and composition with other materials.Finally,the paper prospected the development trend of V₂O₅ electrode material.

Key words: V₂O₅, Morphology control, Crystal structure, Chemical pre?insertion, Conductive material

摘要：

钠离子电池(SIBs)具有资源丰富、成本低廉及供应风险低等优势，被认为是极具潜力的下一代电化学储能器件。目前，五氧化二钒(V₂O₅)正极材料因具有高工作电压及高理论容量等优点，逐渐成为SIBs正极材料的研究热点。然而，V₂O₅正极材料的低离子扩散系数、低电导率及反复的离子嵌入/脱嵌所致的结构不稳定等缺点，限制了其在SIBs中的应用。分析了V₂O₅正极材料的晶体结构和储钠机制，并通过形貌控制、晶体结构修饰、化学预插入以及与其他材料复合等改性方法，综述了V₂O₅正极材料在SIBs中的研究进展，最后对V₂O₅正极材料的发展趋势进行了展望。

关键词: V₂O₅, 形貌控制, 晶体结构, 化学预插入, 导电材料

CLC Number:

TQ150

Ya Zhou, Runna Shi, Xiaoshi Lang, Chuangang Yao, Kedi Cai. Research Progress of V₂O₅ Cathode Material for Sodium⁃Ion Batteries[J]. Journal of Petrochemical Universities, 2022, 35(6): 38-47.

周娅, 时润娜, 郎笑石, 姚传刚, 蔡克迪. 钠离子电池正极材料V₂O₅研究进展[J]. 石油化工高等学校学报, 2022, 35(6): 38-47.

Figures/Tables 8

Fig.1 Crystalline structure of orthorhombic V2O5

Fig.2 Discharge/charge profiles,exsitu XRD patterns and the structural changes of the V2O5 electrode during discharging and charging processes

Fig.3 Physical characterization diagram of V2O5 single?crystalline nanowires

Fig.4 Crystalline structure of single layered orthorhombic V2O5 and bilayered V2O5·nH2O(water molecules not shown)

Fig.5 Structural characterization of ε′?V2O5

Fig.6 Schematic illustration of the fabrication process of the Y x V2O5(x=0,0.02,0.06) samples

Fig.7 Analysis of (001) crystal plane of polyaniline/V2O5 composite

Fig.8 A schematic illustration of procedure for the preparation of three dimensional TiO2?V2O5?C nanostructure and their application as anode materials for Na batteries

References 53

1	Wang Q H， Xu J T， Zhang W C， et al. Research progress on vanadium⁃based cathode materials for sodium ion batteries［J］. Journal of Materials Chemistry A， 2018， 6（19）： 8815⁃8838.
2	Liu Z， Yu Q， Zhao Y L， et al. Silicon oxides：A promising family of anode materials for lithium⁃ion batteries［J］. Chemical Society Review， 2019， 48（1）： 285⁃309.
3	Yan B， Zhong S K， Liu X J， et al. Growth of large⁃area petal⁃like V₂O₅ thin nanosheets for superior lithium storage［J］. Journal of Alloys and Compounds， 2021， 875： 159899.
4	Goikolea E， Palomares V， Wang S J， et al. Na⁃ion batteries⁃approaching old and new challenges［J］. Advanced Energy Materials， 2020， 10（44）： 2002055.
5	Ghimbeu C M，Gorka J，Simone V，et al.Insights on the Na⁺ ion storage mechanism in hard carbon：Discrimination between the porosity，surface functional groups and defects［J］.Nano Energy，2018，44：327⁃35.
6	Chen M Z， Liu Q N， Hu Z， et al. Designing advanced vanadium⁃based materials to achieve electrochemically active Multielectron reactions in sodium/potassium⁃ion batteries［J］. Advanced Energy Materials， 2020， 10（42）： 2002244.
7	Wang X H， Li Q， Wang H Y. Anatase TiO₂ as a Na⁺⁃storage anode active material for dual⁃ion batteries［J］. ACS Applied Materials Interfaces， 2019， 11（33）： 30453⁃30459.
8	Zhang W Y， Jin H X， Chen G W， et al. Sandwich⁃like N⁃doped carbon nanotube@Nb₂C MXene composite for high performance alkali ion batteries［J］. Ceramics International， 2021， 47（14）：20610⁃20616.
9	Tomboc G M， Wang Y T， Wang H， et al. Sn⁃based metal oxides and sulfides anode materials for Na ion battery［J］. Energy Storage Materials， 2021， 39： 21⁃44.
10	Qin M S， Ren W H， Jiang R X， et al. Highly crystallized prussian blue with enhanced kinetics for highly efficient sodium storage［J］. ACS Applied Materials Interfaces， 2021， 13： 3999⁃4007.
11	Guo W B， She Z Y， Xue H T， et al. Density functional theory study on the Ti₃CN and Ti₃CNT₂ （T = O， S and F） as high capacity anode material for Na ion batteries［J］. Applied Surface Science， 2020， 529： 147180.
12	卢虹宇，赵景新，彭琪贺，等.正极材料五氧化二钒常规改性的研究进展［J］.化学世界， 2020， 61（3）：153⁃164.
	Lu H Y，Zhao J X，Peng Q H，et al.Progress in conventional modification of vanadium pentoxideas cathode material［J］. Chemical World，2020，61（3）：153⁃164.
13	West K， Christiansen Z B， Jacobsen T， et al. Sodium insertion in vanadium oxides［J］. Solid State Ionics， 1988， 28⁃30： 1128⁃1131.
14	Lu J S， Nguyen M N， Liu W R， et al. Electrochemical properties of novel FeV₂O₄ as an anode for Na⁃ion batteries［J］. Scientific Reports， 2018， 8： 8839.
15	Tan H， Yu X Z， Huang K， et al. Large⁃scale carambola⁃like V₂O₅nanoflowers arrays on microporous reed carbon as improved electrochemical performances lithium⁃ion batteries cathode［J］. Journal of Energy Chemistry， 2020， 51： 388⁃395.
16	Geng H B， Cheng M， Wang B， et al. Electronic structure regulation of layered vanadium oxide via interlayer doping strategy toward superior high⁃rate and low⁃temperature zinc⁃ion batteries［J］.Advanced Function Materials，2019，30（6）：1907684.
17	Chernova N A， Roppolo M， Dillon A C， et al. Layered vanadium and molybdenum oxides： Batteries and electrochromics［J］. Journal of Materials Chemistry， 2009， 19（17）： 2526⁃2552.
18	Ghulam A， Lee J H， Si H O， et al. Investigation of the Na intercalation mechanism into nano⁃sized V₂O₅/C composite cathode material for Na⁃ion batteries［J］. ACS Applied Materials & Interfaces， 2016， 8（9）： 6032⁃6039.
19	Li W Y， Ji J C， Yao J H， et al. Sodium ion storage performance and mechanism in orthorhombic V₂O₅single⁃crystalline nanowires［J］. Science China Materials， 2021， 64： 557⁃570.
20	Rui X H， Tang Y， Malyi O I， et al. Ambient dissolution⁃recrystallization towards large⁃scale preparation of V₂O₅ nanobelts for high⁃energy battery applications［J］. Nano Energy， 2016， 22： 583⁃593.
21	Su D W， Dou X， Wang G X.Hierarchical orthorhombic V₂O₅ hollow nanospheres as high performance cathode materials for sodium⁃ion batteries［J］. Journal of Materials Chemistry A， 2014， 2（29）： 11185⁃11194.
22	Zhao Z J， Li D L， Wang C Z， et al. Hierarchical V₂O₅ microspheres： A pseudocapacitive cathode material for enhanced sodium ion storage［J］. Journal of Alloys and Compounds， 2022， 895： 162617.
23	Wang L， Wang Y C， Cao A M， et al. Electrochemically anodized V₂O₅ as an efficient sodium cathode［J］. Energy Fuels， 2021， 35（9）： 8358⁃8364.
24	Kulish V V， Manzhos S. Comparison of Li， Na， Mg and Al⁃ion insertion in vanadium pentoxides and vanadium dioxides［J］. RSC Advances， 2017， 7（30）： 18643⁃18649.
25	Córdobaa R， Kuhna A， Pérez J C F， et al. Sodium insertion in high pressure β⁃V₂O₅： A new high capacity cathode material for sodium ion batteries［J］. Journal of Power Sources， 2019， 422： 42⁃48.
26	Baddour H R， Renard M S， Emery N， et al. The richness of V₂O₅ polymorphs as superior cathode materials for sodium insertion［J］. Electrochimica Acta， 2018， 270： 129⁃137.
27	Renard M S， Baddour H R， Ramos J P. Kinetic insight into the electrochemical sodium insertion⁃extraction mechanism of the puckered γ′⁃V₂O₅ polymorph［J］. Electrochimica Acta， 2019， 322： 134670.
28	Baddour H R， Renard M S， Ramos J P. Enhanced electrochemical properties of ball⁃milled γ′⁃V₂O₅ as cathode material for Na⁃ion batteries： A structural and kinetic investigation［J］. Journal of Power Sources， 2021， 482： 229017.
29	Moretti A， Passerini S. Bilayered nanostructured V₂O₅·nH₂O for metal batteries［J］. Advanced Energy Materials， 2016， 6（23）： 1600868.
30	Tepavcevic S， Xiong H， Stamenkovic V R， et al. Nanostructured bilayered vanadium oxide electrodes for rechargeable sodium⁃ion batteries［J］. ACS Nano， 2012， 6（1）： 530⁃538.
31	Su D W， Wang G X. Single⁃crystalline bilayered V₂O₅ nanobelts for high⁃capacity sodium⁃ion batteries［J］. ACS Nano， 2013， 7（12）： 11218⁃11226.
32	Wei Q L， Liu J， Feng W， et al. Hydrated vanadium pentoxide with superior sodium storage capacity［J］. Journal of Materials Chemistry A， 2015， 3（15）： 8070⁃8075.
33	Wang H， Bi X X， Bai Y， et al. Open⁃structured V₂O₅·nH₂O nanoflakes as highly reversible cathode material for monovalent and multivalent intercalation batteries［J］. Advanced Energy Materials， 2017， 7（14）： 1602720.
34	Moretti A， Secchiaroli M， Buchholz D， et al. Exploring the low voltage behavior of V₂O₅ aerogel as intercalation host for sodium ion battery［J］. Journal of the Electrochemical Society， 2015， 162（14）： 2723⁃2728.
35	Moretti A， Maroni F， Osada I， et al. V₂O₅ aerogel as a versatile cathode material for lithium and sodium batteries［J］. ChemElectroChem， 2015， 2（4）：529⁃537.
36	Li Y W， Liu C Z， Xie Z P， et al. Superior sodium storage performance of additive⁃free V₂O₅ thin film electrode［J］. Journal of Materials Chemistry A， 2017， 5（32）： 16590⁃16594.
37	Li S Y， Li X F， Li Y W， et al. Superior sodium storage of vanadium pentoxide cathode with controllable interlamellar spacing［J］. Electrochimica Acta， 2017， 244： 77⁃85.
38	Tolhurst T M， Leedahl B， Andrews J L， et al. Electronic structure of ε′⁃V₂O₅： An expanded band gap in a double⁃layered polymorph with increased interlayer separation［J］. Journal of Materials Chemistry A， 2017， 5（45）： 23694⁃23703.
39	Hadjean R B， Renard M S， Emery N， et al. The richness of V₂O₅ polymorphs as superior cathode materials for sodium insertion［J］. Electrochimica Acta， 2018， 270： 129⁃137.
40	Ji J C， Li Y W， Zhang Z L， et al. PEG intercalated vanadium pentoxide xerogel for enhanced sodium storage［J］. Materials Letters， 2020， 270： 127752.
41	Clites M， Pomerantseva E. Bilayered vanadium oxides by chemical pre⁃intercalation of alkali and alkali⁃earth ions as battery electrodes［J］. Energy Storage Materials， 2018， 11： 30⁃37.
42	Cai Y S， Zhou J， Fang G Z， et al. Na_0.282V₂O₅： A high⁃performance cathode material for rechargeable lithium batteries and sodium batteries［J］. Journal of Power Sources， 2016， 328： 241⁃249.
43	Pan H， Zhang G B， Liao X B， et al. Sodium ion stabilized vanadium oxide nanowire cathode for high⁃performance zinc⁃ion batteries［J］. Advanced Energy Materials， 2018， 8（10）： 1702463.
44	Parmar R， Matsubara E Y， Gunnella R， et al. Electro⁃insertion of Mn²⁺ ions into V₂O₅·nH₂O on MWCNTs coated carbon felt for binder⁃free Na⁺ ion battery electrodes［J］. Sustainable Energy & Fuels， 2020， 4（8）： 3951⁃3962.
45	Liu C Z， Yao J H， Zou Z G， et al. Boosting the cycling stability of hydrated vanadium pentoxide by Y³⁺ pillaring for sodium⁃ion batteries［J］. Materials Today Energy， 2019， 11： 218⁃227.
46	Dong J， Jiang Y L， Wei Q L， et al. Strongly coupled pyridine⁃V₂O₅·nH₂O nanowires with intercalation pseudocapacitance and stabilized layer for high energy sodium ion capacitors［J］. Small， 2019， 15（22）： 1900379.
47	Wang Z Q， Tang X Y， Yuan S， et al. Engineering vanadium pentoxide cathode for the zero⁃strain cation storage via a scalable intercalation⁃polymerization approach［J］. Advanced Energy Materials， 2021， 31（22）： 2100164.
48	Zhao M S， Wang J， He X H， et al. Graphene modified vanadium oxide composite materials used in aqueous Na⁃ion batteries［J］. Energy & Fuels， 2021， 35（24）： 20394⁃20399.
49	Tian S， Cai T H， Wang D D， et al. A superior cathode of sodium⁃ion battery： A V₂O₅ nanosheets anchored on carbon nanofibers［J］. IOP Conference Series： Earth and Environmental Science， 2021， 692： 022042.
50	Etman A S， Sun J L， Younesi R. V₂O₅·nH₂O nanosheets and multi⁃walled carbon nanotube composite as a negative electrode for sodium⁃ion batteries［J］. Journal of Energy Chemistry， 2019， 30： 145⁃151.
51	Shang C Q， Hua L， Lin Q， et al. Integration of NaV₆O₁₅·nH₂O nanowires and rGO as cathode materials for efficient sodium storages［J］. Applied Surface Science， 2019， 494： 458⁃464.
52	Feng J J， Xiong Z M， Zhao L， et al. One⁃pot hydrothermal synthesis of NaxV₂O₅·nH₂O/KB nanocomposite as a sodium⁃ion battery cathode for improved reversible capacity and rate performance［J］. Journal of Power Sources， 2018， 396： 230⁃237.
53	Liu F S， Sun X X， Liu Y T， et al. TiO₂ nanorods confined in porous V₂O₅ nanobelts and interconnected carbon channels for sodium ion batteries［J］. Applied Surface Science， 2019， 473： 873⁃884.

[1]	Lei Guan, Xian Chen, Bowen Fan, Yaxu Chen, Pengpeng Yin, Ying Wang. Hydrothermal Synthesis, Crystal Structure and Fluorescence Property of a Tb Coordination Complex [J]. Journal of Petrochemical Universities, 2023, 36(3): 60-65.
[2]	Qian Liuying, Li Dongxue, Li Fengyan, Wang Peng, Zhao Tianbo. The Morphology Control Research of Paraffin/Melamine Resin Phase Transition Microcapsules [J]. Journal of Petrochemical Universities, 2016, 29(3): 7-11.
[3]	Wan Hai,Zhang Ruojie,Qin Yucai,et al. Morphology Control and Aromatization of ZSM5/KL Composite Zeolite [J]. Journal of Petrochemical Universities, 2015, 28(1): 1-6.

Research Progress of V₂O₅ Cathode Material for Sodium⁃Ion Batteries

钠离子电池正极材料V₂O₅研究进展

HTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 53

Related Articles 3

Recommended Articles

Metrics