Application of LDHs with Photocatalytic Properties in Water Pollution Treatment

doi:10.3969/j.issn.1006-396X.2022.03.006

Abstract

Abstract:

Layered double hydroxides (LDHs),also known as hydrotalcite,can be widely employed in water pollution treatment because of their special layered structures,high physicochemical stability,and electronic properties.The application of LDH composites as catalysts for photocatalysis has received increasing attention.Therefore,the preparation and modification of LDH photocatalysts were reviewed,and the removal effect of pollutants from wastewater exerted by different LDHs was emphatically introduced.In addition, the mechanism and research status of LDH photocatalysts were briefly described.Finally,the development trend of LDH photocatalysts was prospected to provide a reference for the subsequent application of LDHs in water pollution treatment.

Key words: LDHs, Photocatalysis, Water pollution treatment, Degradation of pollutants, Modification of LDHs

摘要：

双金属复合氢氧化物（LDHs，又叫水滑石）因具有层状结构、稳定的物化性质和电子特性等优点，可以大范围地应用在污水处理中。目前，水滑石作为光催化剂及其复合材料在污水处理上的应用受到越来越多的关注。综述了水滑石光催化剂的制备及其改性，着重介绍了不同类型水滑石对水中不同污染物的去除效果，并简要阐述了水滑石光催化剂的作用机理和研究现状。最后，展望了水滑石光催化剂的发展趋势，以期为后续水滑石在污水处理上的应用提供借鉴。

关键词: 水滑石, 光催化, 水污染治理, 降解污染物, 水滑石改性

CLC Number:

TQ110.9

Dongqi Zhao, Guizhou Gu, Zheng Li. Application of LDHs with Photocatalytic Properties in Water Pollution Treatment[J]. Journal of Petrochemical Universities, 2022, 35(3): 36-42.

赵东启, 顾贵洲, 李政. 水滑石类光催化剂在污水处理中的应用[J]. 石油化工高等学校学报, 2022, 35(3): 36-42.

Figures/Tables 2

References 45

1	Tuček J，Kemp K C，Kim K S，et al.Iron⁃oxide⁃supported nanocarbon in lithium⁃ion batteries，medical，catalytic，and environmental applications［J］.ACS Nano，2014，8（8）：7571⁃7612.
2	Dong C C，Ji J H，Shen B，et al.Enhancement of H₂O₂decomposition by the co⁃catalytic effect of WS₂ on the fenton reaction for the synchronous reduction of Cr（VI） and remediation of phenol［J］.Environment Science & Technology，2018，52（19）：11297⁃11308.
3	Duan X G，Sun H Q，Shao Z P，et al.Nonradical reactions in environmental remediation processes：Uncertainty and challenges［J］.Applied Catalysis B：Environmental，2018，224：973⁃982.
4	于喜洋，顾贵洲，李政.水滑石材料处理工业废水的研究进展［J］.石油化工高等学校学报，2021，34（6）：16⁃21.
	Yu X Y，Gu G Z，Li Z.Research progress of industrial wastewater treatment by hydrotalcite［J］.Journal of Petrochemical Universities，2021，34（6）：16⁃21.
5	Lin D，Zhou S.Synthesis and characterization of a novel Mg⁃Al hydrotalcite⁃loaded kaolin clay and its adsorption properties for phosphate in aqueous solution［J］.Journal of Alloys and Compounds，2015，637：188⁃196.
6	周俊义.镍铁水滑石的制备及析氧性能研究［D］.青岛：青岛科技大学，2019.
7	der Ven L D，Gemert M，van Batenburg L F，et al.On the action of hydrotalcite⁃likeclay materials as stabilizers in polyvinylchloride ［J］.Applied Clay Science，2000，17（1⁃2）：25⁃34.
8	张宁，李先铭，张红霞，等.不同层板离子及插层类水滑石对PVC热稳定性的影响［J］.中国塑料，2020，34（2）：74⁃78.
	Zhang N，Li X M，Zhong H X，et al.Effect of intercalated hydrotalcite⁃like compounds with different interlayer ions on thermal stability of PVC［J］.China Plastics，2020，34（2）：74⁃78.
9	Lu H，Zhu Z，Zhang H，et al.Fenton like catalysis and oxidation/ adsorption performances of acetaminophen and arsenic pollutants in water on a multi⁃metal Cu⁃Zn⁃Fe⁃LDH［J］.Acs Applied Materials & Interfaces，2016，8（38）：25343⁃25352.
10	肖康，王新星，吴小飞，等.水滑石层间阴离子为还原剂原位负载贵金属纳米颗粒［J］.化学通报，2018，81（4）：47⁃53.
	Xiao K，Wang X X，Wu X F，et al.Reductive loading of noble metal nanoparticles on layered doube hydroxide with interlayer anion as reductant［J］.Chemistry，2018，81（4）：332⁃338.
11	张鋆益，邹勇昌，陈俊，等.层间阴离子对镁⁃铝水滑石吸附HCl与PVC热稳定性的影响［J］.塑料工业，2019，42（12）：116⁃121.
	Zhang J Y，Zhou Y C，Chen J，et al.Effect of interlayer anions on the absorption by Mg⁃Al hydrotalcite and the thermal stability of PVC［J］.China Plastics Industry，2019，42（12）：116⁃121.
12	Zhang Y，Du D，Li X，et al.Electrostatic self⁃assembly of sandwich⁃like CoAl⁃LDH/ polypyrrole/ graphene nanocomposites with enhanced capacitive performance［J］.Acs Applied Materail Interfaces，2017，9（37）：31699⁃13709.
13	赵策，曾虹燕，王亚举，等.Mg⁃Al水滑石“记忆效应”及其对Cr（VI）阴离子吸附性能研究［J］.无机材料学报，2011，26（8）：874⁃880.
	Zhao C，Zhen H Y，Wang Y J，et al.“Memory effect” of Mg⁃Al hydrotalcites and its chromium（VI） absorption property［J］.Journal of Inorganic Metarials［J］.2011，26（8）：874⁃880.
14	高昆，汪朝晖，汪效祖.水热法制Zn⁃Mg⁃Al花状水滑石［J］.精细化工，2013，30（2）：126⁃143.
	Gao K，Wang C H，Wang X Z.Hydrothermal synthsis and characterization of Zn⁃Mg⁃Al hydrotalcite［J］.Fine Chemicals，2013，30（2）：126⁃143.
15	刘媛，蒋晓帆，姚培.镁铝水滑石结构记忆性及其应用研究［J］.广东化工，2011，38（1）：80⁃82.
	Liu Y，Jiang X F，Yao P.Memory effect and its application of Mg⁃Al hydrotalcite［J］.Guangdong Chemical Industry，2011，38（1）：80⁃82.
16	胡盛，付英英，汪桐，等.反应时间对镁铝水滑石结构的影响［J］.非金属矿，2019，42（1）：46⁃49.
	Hu S，Fu Y Y，Wang T，et al.Effect of reaction time on the structure of Mg⁃Al Hydrotalcite［J］.Non⁃metallic Mines，2019，42（1）：46⁃49.
17	滑亚婷，杜春贵，姚潇翎，等.水滑石阻燃剂的离子改性研究概况与发展前景［J］.化学通报，2018，82（4）：316⁃322.
	Hua Y T，Du C G，Yao X L，et al.Progress in ion⁃ modified hydrotalcite flame retardants［J］.Chemistry，2018，82（4）：316⁃322.
18	Chen Y，Li J，Zhai B Y，et al.Enhanced photocatalytic degradation of RhB by two⁃dimensional composite photocatalyst［J］.Colloids & Surfaces A Physicochemical & Engineering Aspects，2019，568：429⁃435.
19	Marianna I，Antonio D M，Antonio V，et al.Synthesis，characterization，and sorption capacity of layered double hydroxides and their complexes with polymerin［J］.Journal of Agricultural and Food Chemistry，2010，58（9）：5523⁃5530.
20	Rehab M，Samah A M，Fatma M，et，al.Comparative study of single and multiple pollutants system using Ti–Fe chitosan LDH adsorbent with high performance in wastewater treatment［J］.Journal of Chemical and Engineering Data，2017，62（11）：3703⁃3722.
21	张骄佼，田森林，周键.镁铝水滑石的合成与应用研究进展［J］.材料导报，2013，27（4）：144⁃148.
	Zhan J J，Tian S L，Zhou J.Study on synthesis and application of Mg⁃Al Hydrotalcite［J］.Materials Reports A：Review，2013，27（4）：144⁃148.
22	Zhou F，Zhao X M，Andrew V B，et al.Coprecipitation synthesis of NixMn_1- x（OH）₂ mixed hydroxides［J］.Chemistry of Materials，2010，22（3）：1015⁃1021.
23	Xu Z P，Qing G.Hydrothermal synthesis of layered double hydroxides （LDHs） from mixed MgO and Al₂O₃：LDH formation mechanism［J］.Chemistry of Materials，2005，17（5）：1055⁃1062.
24	Liang D J，Yue W B，Sun G B，et al.Direct synthesis of unilamellar MgAl⁃LDH nanosheets and stacking in aqueous solution［J］.Langmuir，2015，31（45）：12464⁃12471.
25	张永辉，陈雪冰，张静.可见光催化剂氧化铋的改性研究进展［J］.辽宁石油化工大学学报，2021，41（6）：1⁃8.
	Zhang Y H，Chen X B，Zhang J.Research progress on modification of bismuth oxide as visible light photocatalyst［J］.Journal of Liaoning Petrochemical University，2021，41（6）：1⁃8.
26	Zhang Y H，Tang Z R，Fu X Z，et al.TiO₂⁃graphene nanocomposites for gas⁃phase photocatalytic pegradation of volatile aromatic pollutant：Is TiO₂⁃graphene truly different from other TiO₂⁃carbon composite materials？［J］.ACS Nano，2010，4（12）：7303⁃7314.
27	Tian J Y，David B C，Claudio Q，et al.Lead perovskite and competitive Formation of 6H and 3C perovskite structure with mixed A cations［J］.ACS Applied Energy Materials，2019，2（8）：5427–5437.
28	倪哲明，薛继龙.含Cu水滑石的结构与光催化性能［J］.高等学校化学学报，2013，34（3）：503⁃508.
	Ni Z M，Xue J L.Synthesis of CuMgAl layered double hydroxides for efficient photocatalysis of rhodamine B［J］.Chemical Journal of Chinese Universities，2013，34（3）：503⁃508.
29	Xiong X Y，Zhao Y F，Shi R，et al.Selective photocatalytic CO₂ reduction over Zn⁃based layered double hydroxides containing tri or tetravalent metals［J］.Science Bulletin，2020，65（12）：987⁃994.
30	符艺.稀土金属离子掺杂水滑石的制备及其光催化性能研究［D］.北京：北京化工大学，2016.
31	Wei M，Shi Z Y，David G E，et al.Study on the intercalation and interlayer oxidation transformation of L⁃cysteine in a confined region of layered double hydroxides［J］.Journal of Materials Chemistry，2006，16（21）：2102⁃2109．
32	González M A，Pavlovic I，Delgalo R，et al.Removal of Cu^{2 +}Pb^{2 +} and Cd^{2 +}by layered double hydroxidehumate hybrid.Sorbate and sorbent comparative studies［J］.Chemical Engineering Journal，2014，254：605⁃611．
33	Zhao Y F，Chen P Y，Zhang B S，et al.Highly dispersed TiO₆ units in a layered double hydroxide for water splitting［J］.Chemistry⁃A European Journal，2012，18（38）：11949⁃11958.
34	Yao L H，Wei D，Ni Y M，et al.Surface localization of CdZnS quantum dots onto 2D g⁃C₃N₄ultrathin microribbons：Highly efficient visible light⁃induced H₂⁃generation［J］.Nano Energy，2016，26：248⁃256.
35	Xu Y，Liu T J，Zhang Y，et al.Advances in technologies for pharmaceuticals and personal care products removal［J］.Journal of Materials Chemistry A，2017，5（24）：12001⁃12014.
36	杜仙格.多元类水滑石材料的制备及催化PMS去除水中难降解有机污染物的研究［D］.太原：太原理工大学，2020.
37	Wang Z，Jia W，Jiang M L，et al.Microwave⁃assisted synthesis of layer⁃by⁃layer ultra⁃large and thin NiAl⁃LDH/RGO nanocomposites and their excellent performance as electrodes［J］.Science China Materials，2015，58（12）：944⁃952.
38	邢嘉钰，李丽，张国权，等.锰钴水滑石/石墨烯电极的制备及催化性能［J］.中国环境科学，2020，40（11）：167⁃175.
	Xing J Y，Li L，Zhang G Q，et al.The preparation and catalytic performance of MnCo layered double hydroxides/reduced graphene oxide electrode［J］.China Environmental Science，2020，40（11）：4804⁃4812.
39	方若超，吴代赦，杨昱，等.H₂O₂协同强化CuCoAl⁃LDHs/GO复合材料光催化效能［J］.环境工程学报，2021，15（9）：2913⁃2921.
	Fang R C，Wu D M，Yang L，et al.Photocatalytic performance of CuCoAl⁃LDHs/GO composites synergistically enhanced by H₂O₂［J］.Chinese Journal of Environmental Engineering，2021，15（9）：2913⁃2921.
40	Sun J C，Zhang Y B，Cheng J，et al.Synthesis of Ag/AgCl/Zn⁃Cr LDHs composite with enhanced visible⁃light photocatalytic performance［J］.Journal of Molecular Catalysis A Chemical，2014，382（4）：146⁃153.
41	石双欣，卫静.光催化技术处理染料废水研究进展［J］.绿色科技，2021，23（2）：63⁃65.
	Shi S X，Wei J.Research progress in photocatalytic treatment of dye wastewater［J］.Green Technology，2021，23（2）：63⁃65.
42	Yuan X，Li W，Yuan X，et al.Enhancement photocatalytic degradation of rhodamine B on nanoPt intercalated Zn⁃Ti layered double hydroxides［J］.Applied Surface Science，2014，293：345⁃351.
43	Da G P，Liu S Q，Liang Y，et al.Fabrication of a nano⁃sized Ag₂CO₃/reduced graphene oxide photocatalyst with enhanced visible⁃light photocatalytic activity and stability［J］.RSC Advances，2014，4（65）：34226⁃34231.
44	Ao Y H，Wang P F，Wang C，et al.Enhanced photocatalytic properties of the 3D flower⁃like Mg⁃Al layered double hydroxides decorated with Ag₂CO₃under visible light illumination［J］.Materials Research Bulletin，2016，80：23⁃29.
45	Wang Y Y，Jing Y Q，Li W X，et al.Silicate silver/flower⁃like magnalium hydroxide composites for enhanced visible light photodegradation activities［J］.RSC Advances，2018，8（41）：23442⁃23450.

[1]	Jiaman WANG, Jing XIONG, Jinge SHI, Yuechang WEI, Kailing HUO. An Overview of Carbon Dioxide Catalyzed by Titanium Dioxide Catalyst [J]. Journal of Petrochemical Universities, 2024, 37(4): 1-11.
[2]	Wenke YANG, Lianxue LU, Peng LI, Jian ZHANG, Shaozheng HU. Synthesis, Modification and Application of Photocatalytic Material Graphite Phase Carbon Nitride [J]. Journal of Petrochemical Universities, 2024, 37(1): 43-51.
[3]	Yao NING, Man LIU, Suyan LIU. Preparation and Photodegradation Performances of Porous Carbon BVO/Zn@ZPC [J]. Journal of Petrochemical Universities, 2023, 36(6): 36-47.
[4]	Xuerong Xu, Xiang Peng. Research Progress in Preparation and Application of Layered Double Hydroxides Electrocatalysts [J]. Journal of Petrochemical Universities, 2022, 35(5): 1-11.
[5]	Jiahui Chen, Honglin Li, Zikun Yang, Hongxian Luo, Jinsheng Zhang, Lihua Li. Preparation of GO⁃Modified Cerium⁃Based Nano⁃Composite Photocatalyst and a Comparative Study on Photocatalytic Properties [J]. Journal of Petrochemical Universities, 2022, 35(1): 63-67.
[6]	Jifa Liu, Xuebing Chen, Fangfang Wang, Jing Zhang, Changdong Chen. Controllable Synthesis and Photocatalytic Properties of Hexagonal/Monoclinic WO₃ Phase Junction [J]. Journal of Petrochemical Universities, 2021, 34(6): 22-26.
[7]	Zhou Yue’e, Chen Xuebing, Zhang Jing. Research Progress on the Regulation of Photogenerated Charge Separation by Built⁃In Electric Field [J]. Journal of Petrochemical Universities, 2021, 34(3): 1-6.
[8]	Cui Meiyu， Li Fei. Progress in Amination of Alkenes via Visible Light⁃Photoredox Catalysis [J]. Journal of Petrochemical Universities, 2021, 34(3): 31-37.
[9]	Li Peng, Lü Zhenbo, Yu Fang. Visible Light Induced C-C Bond Cleavage and Amination Reaction of Cyclobutanols [J]. Journal of Petrochemical Universities, 2020, 33(4): 1-5.
[10]	Yan Song, Wang Yan, Wang Chang’ou,et al. Titanium Surface Phase Control and Its Photocatalytic ActivityStudied by UV Raman Spectroscopy [J]. Journal of Petrochemical Universities, 2014, 27(2): 6-9.
[11]	LI Xiuping,DONG Hang,LI Chujia,et al. Preparation of HighPurityand White CeO₂ by ComplexPrecipitation  Method and Its Photocatalytic Activit [J]. Journal of Petrochemical Universities, 2013, 26(5): 15-18.
[12]	LI Song-tian，YAN Yong-sheng，WU Chun-du*，HUO Peng-wei，CHU Jin-yu. Preparation and Performances of TiO₂ /Potassium Titanate Photocatalyst [J]. Journal of Petrochemical Universities, 2007, 20(4): 28-32.