Abstract: Calix ［4］ arene was synthesized by dealkylation reaction using ptertbutylcalix ［4］ arene and phenol as raw material in the presence of anhydrous AlCl3. Then 5,11,17,23four sulfo phenyl)azo calix ［4］ arene was synthesized by coupling reaction using calix ［4］ arene and pamino benzene sulfonic acid as raw materials. In the presence of tinhydrochloric acid, 5,11,17,23four sulfo phenyl)azo calix ［4］ arene was reduced to 5,11,17,23four aminocalix ［4］ arene hydrochloride. The synthesized compounds were characterized by thermal analysis, infrared spectrum analysis and UV spectra of the synthesized compounds. By using the method of synthesis of calix ［4］ arene ammonium hydrochloride yield is high, cost is greatly reduced.

Key words: Calixarene,    , Watersoluble,    , Synthesis,    , Azo,    , Reduction,   , Calixarene amine hydrochloride

摘要： 以对叔丁基杯[4]芳烃为原料,在无水三氯化铝存在下,与苯酚发生脱烷基化反应合成了杯[4]芳烃。 再以杯[4]芳烃与对氨基苯磺酸为原料,通过偶合反应合成了5,11,17,23灢四[(对磺基苯基)偶氮]灢杯[4]芳烃,再利 用锡灢盐酸还原得到5,11,17,23灢四氨基灢杯[4]芳烃盐酸盐。合成的化合物通过热分析、红外光谱和紫外光谱等对合成的各化合物分析。利用该方法合成杯[4]芳烃铵的盐酸盐收率高,成本大大降低。

关键词: 杯芳烃 , 水溶性 , 合成 , 偶氮 , 还原 , 杯芳烃铵盐酸盐